中国物理B ›› 2022, Vol. 31 ›› Issue (11): 110101-110101.doi: 10.1088/1674-1056/ac7c01

所属专题: SPECIAL TOPIC — Emerging photovoltaic materials and devices

• •    下一篇

A silazane additive for CsPbI2Br perovskite solar cells

Ruiqi Cao(曹瑞琪)1,2,†, Yaochang Yue(乐耀昌)2,3,†, Hong Zhang(张弘)2, Qian Cheng(程倩)2, Boxin Wang(王博欣)2, Shilin Li(李世麟)2,3, Yuan Zhang(张渊)3, Shuhong Li(李书宏)1,‡, and Huiqiong Zhou(周惠琼)2,§   

  1. 1 Beijing Technology&Business University, Department of Chemistry, Beijing 100048, China;
    2 CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, Nanoscience National Center for Nanoscience and Technology, Beijing 100190, China;
    3 HEEGER Beijing Research&Development Center, Beihang University, Beijing 100191, China
  • 收稿日期:2022-02-20 修回日期:2022-05-24 接受日期:2022-06-27 出版日期:2022-10-17 发布日期:2022-10-25
  • 通讯作者: Shuhong Li, Huiqiong Zhou E-mail:lish@th.btbu.edu.cn;zhouhq@nanoctr.cn
  • 基金资助:
    This work was financially supported by the National Key Research and Development Program of China (Grant No. 2017YFA0206600), the National Natural Science Foundation of China (Grant No. 21922505), and the Strategic Priority Research Program of Chinese Academy of Sciences (Grant No. XDB36000000).

A silazane additive for CsPbI2Br perovskite solar cells

Ruiqi Cao(曹瑞琪)1,2,†, Yaochang Yue(乐耀昌)2,3,†, Hong Zhang(张弘)2, Qian Cheng(程倩)2, Boxin Wang(王博欣)2, Shilin Li(李世麟)2,3, Yuan Zhang(张渊)3, Shuhong Li(李书宏)1,‡, and Huiqiong Zhou(周惠琼)2,§   

  1. 1 Beijing Technology&Business University, Department of Chemistry, Beijing 100048, China;
    2 CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, Nanoscience National Center for Nanoscience and Technology, Beijing 100190, China;
    3 HEEGER Beijing Research&Development Center, Beihang University, Beijing 100191, China
  • Received:2022-02-20 Revised:2022-05-24 Accepted:2022-06-27 Online:2022-10-17 Published:2022-10-25
  • Contact: Shuhong Li, Huiqiong Zhou E-mail:lish@th.btbu.edu.cn;zhouhq@nanoctr.cn
  • Supported by:
    This work was financially supported by the National Key Research and Development Program of China (Grant No. 2017YFA0206600), the National Natural Science Foundation of China (Grant No. 21922505), and the Strategic Priority Research Program of Chinese Academy of Sciences (Grant No. XDB36000000).

摘要: Adding additives into peroskite precursor solution has been proven as a simple and efficient strategy to improve the quality of peroskite films. In this work, we demonstrate an effective additive strategy to improve the quality of all-inorganic perovskite films by adding a novel silazane additive heptamethyldisilazane (HDMS). The power conversion efficiency (PCE) of the optimized devices is enhanced from 14.55% to 15.31% with an open-circuit voltage over 1.26 V due to the higher quality perovskite films with lower trap density after the incorporation of HDMS. More interestingly, the HDMS devices exhibit superior humidity and thermal stability compared with the control ones. This work provides a simple and efficient strategy to enhance the device performance and stability of all-inorganic perovskite solar cells, which could facilitate its commercialization.

关键词: silazane, all-inorganic perovskite, heptamethyldisilazane (HDMS), additive, solar cells

Abstract: Adding additives into peroskite precursor solution has been proven as a simple and efficient strategy to improve the quality of peroskite films. In this work, we demonstrate an effective additive strategy to improve the quality of all-inorganic perovskite films by adding a novel silazane additive heptamethyldisilazane (HDMS). The power conversion efficiency (PCE) of the optimized devices is enhanced from 14.55% to 15.31% with an open-circuit voltage over 1.26 V due to the higher quality perovskite films with lower trap density after the incorporation of HDMS. More interestingly, the HDMS devices exhibit superior humidity and thermal stability compared with the control ones. This work provides a simple and efficient strategy to enhance the device performance and stability of all-inorganic perovskite solar cells, which could facilitate its commercialization.

Key words: silazane, all-inorganic perovskite, heptamethyldisilazane (HDMS), additive, solar cells

中图分类号:  (Physics tournaments and contests)

  • 01.50.Rt
14.70.Bh (Photons)