Key parameters of two typical intercalation reactions to prepare hybrid inorganic-organic perovskite films

doi:10.1088/1674-1056/27/1/018807

中国物理B ›› 2018, Vol. 27 ›› Issue (1): 18807-018807.doi: 10.1088/1674-1056/27/1/018807

所属专题： SPECIAL TOPIC — New generation solar cells

• SPECIAL TOPIC—Non-equilibrium phenomena in soft matters • 上一篇下一篇

Key parameters of two typical intercalation reactions to prepare hybrid inorganic-organic perovskite films

Biao Shi(石标), Sheng Guo(郭升), Changchun Wei(魏长春), Baozhang Li(李宝璋), Yi Ding(丁毅), Yuelong Li(李跃龙), Qing Wan(万青), Ying Zhao(赵颖), Xiaodan Zhang(张晓丹)

1 Institute of Photoelectronic Thin Film Devices and Technology, Nankai University, Tianjin 300071, China;
2 Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Tianjin 300071, China;
3 Key Laboratory of Optical Information Science and Technology of Ministry of Education, Tianjin 300071, China;
4 Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300072, China;
5 College of Electronic Science and Engineering, Nanjing University, Nanjing 210093, China

收稿日期:2017-10-06 修回日期:2017-11-24 出版日期:2018-01-05 发布日期:2018-01-05
通讯作者: Xiaodan Zhang E-mail:xdzhang@nankai.edu.cn
基金资助:
Project supported by the International Cooperation Project of the Ministry of Science and Technology, China (Grant No. 2014DFE60170), the National Natural Science Foundation of China (Grant Nos. 61474065 and 61674084), Tianjin Research Key Program of Application Foundation and Advanced Technology, China (Grant No. 15JCZDJC31300), Key Project in the Science & Technology Pillar Program of Jiangsu Province, China (Grant No. BE2014147-3), and the 111 Project, China (Grant No. B16027).

Key parameters of two typical intercalation reactions to prepare hybrid inorganic-organic perovskite films

Biao Shi(石标)^1,2,3,4, Sheng Guo(郭升)^1,2,3,4, Changchun Wei(魏长春)^1,2,3,4, Baozhang Li(李宝璋)^1,2,3,4, Yi Ding(丁毅)^1,2,3,4, Yuelong Li(李跃龙)^1,2,3,4, Qing Wan(万青)⁵, Ying Zhao(赵颖)^1,2,3,4, Xiaodan Zhang(张晓丹)^1,2,3,4

1 Institute of Photoelectronic Thin Film Devices and Technology, Nankai University, Tianjin 300071, China;
2 Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Tianjin 300071, China;
3 Key Laboratory of Optical Information Science and Technology of Ministry of Education, Tianjin 300071, China;
4 Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300072, China;
5 College of Electronic Science and Engineering, Nanjing University, Nanjing 210093, China

Received:2017-10-06 Revised:2017-11-24 Online:2018-01-05 Published:2018-01-05
Contact: Xiaodan Zhang E-mail:xdzhang@nankai.edu.cn
Supported by:
Project supported by the International Cooperation Project of the Ministry of Science and Technology, China (Grant No. 2014DFE60170), the National Natural Science Foundation of China (Grant Nos. 61474065 and 61674084), Tianjin Research Key Program of Application Foundation and Advanced Technology, China (Grant No. 15JCZDJC31300), Key Project in the Science & Technology Pillar Program of Jiangsu Province, China (Grant No. BE2014147-3), and the 111 Project, China (Grant No. B16027).

摘要/Abstract

摘要： A star hybrid inorganic-organic perovskite material selected as an outstanding absorbing layer in solar cells benefits from multiple preparation techniques and excellent photoelectric characteristics. Among numerous synthetic processes, uniform, compact, and multi-stack perovskite thin films can be manufactured using vacuum deposition. During sequential vacuum deposition, the penetration ability of the organic molecules cannot be effectively controlled. In addition, the relationship between the thickness of the inorganic seeding layer and the organic molecule concentration for optimized devices using an evaporation-solution method is unclear. In this work, we prepared high-quality perovskite films by effectively controlling the penetration ability and chemical quantity of organic methyl ammonium iodide by monitoring the evaporation pressure and time. Thus, a device efficiency of over 15% was achieved with an all-vacuum prepared perovskite film. For the evaporation-solution method, we reacted different thicknesses of inorganic lead iodine with various concentrations of the organic molecule solution. The inorganic layer thickness and organic molecule concentration showed a linear relationship to achieve an optimum perovskite film, and an empirical formula was obtained. This work noted the key parameters of two intercalation reactions to prepare perovskite films, which paves a way to deliver a device that enables multi-layered structures, such as tandem solar cells.

关键词: perovskite solar cell, sequential vacuum deposition, evaporation-solution method, intercalation reaction

Abstract: A star hybrid inorganic-organic perovskite material selected as an outstanding absorbing layer in solar cells benefits from multiple preparation techniques and excellent photoelectric characteristics. Among numerous synthetic processes, uniform, compact, and multi-stack perovskite thin films can be manufactured using vacuum deposition. During sequential vacuum deposition, the penetration ability of the organic molecules cannot be effectively controlled. In addition, the relationship between the thickness of the inorganic seeding layer and the organic molecule concentration for optimized devices using an evaporation-solution method is unclear. In this work, we prepared high-quality perovskite films by effectively controlling the penetration ability and chemical quantity of organic methyl ammonium iodide by monitoring the evaporation pressure and time. Thus, a device efficiency of over 15% was achieved with an all-vacuum prepared perovskite film. For the evaporation-solution method, we reacted different thicknesses of inorganic lead iodine with various concentrations of the organic molecule solution. The inorganic layer thickness and organic molecule concentration showed a linear relationship to achieve an optimum perovskite film, and an empirical formula was obtained. This work noted the key parameters of two intercalation reactions to prepare perovskite films, which paves a way to deliver a device that enables multi-layered structures, such as tandem solar cells.

Key words: perovskite solar cell, sequential vacuum deposition, evaporation-solution method, intercalation reaction

中图分类号: (Solar cells (photovoltaics))

88.40.H-

88.40.hj (Efficiency and performance of solar cells) 88.40.fh (Advanced materials development) 91.60.Ed (Crystal structure and defects, microstructure)

石标, 郭升, 魏长春, 李宝璋, 丁毅, 李跃龙, 万青, 赵颖, 张晓丹. Key parameters of two typical intercalation reactions to prepare hybrid inorganic-organic perovskite films[J]. 中国物理B, 2018, 27(1): 18807-018807.

Biao Shi(石标), Sheng Guo(郭升), Changchun Wei(魏长春), Baozhang Li(李宝璋), Yi Ding(丁毅), Yuelong Li(李跃龙), Qing Wan(万青), Ying Zhao(赵颖), Xiaodan Zhang(张晓丹). Key parameters of two typical intercalation reactions to prepare hybrid inorganic-organic perovskite films[J]. Chin. Phys. B, 2018, 27(1): 18807-018807.

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Key parameters of two typical intercalation reactions to prepare hybrid inorganic-organic perovskite films

Key parameters of two typical intercalation reactions to prepare hybrid inorganic-organic perovskite films

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