Pressure-induced phase transition of B-type Y2O3

doi:10.1088/1674-1056/26/9/090703

中国物理B ›› 2017, Vol. 26 ›› Issue (9): 90703-090703.doi: 10.1088/1674-1056/26/9/090703

Pressure-induced phase transition of B-type Y₂O₃

Qian Zhang(张倩), Xiang Wu(巫翔), Shan Qin(秦善)

1 Gemological Institute, China University of Geosciences, Wuhan 430074, China;
2 State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China;
3 Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education & School of Earth and Space Sciences, Peking University, Beijing 100871, China

收稿日期:2017-05-03 修回日期:2017-05-15 出版日期:2017-09-05 发布日期:2017-09-05
通讯作者: Qian Zhang E-mail:qianzhang@cug.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. U1232204 and 41502029) and China Postdoctoral Science Foundation (Grant No. 2015M580679).

Pressure-induced phase transition of B-type Y₂O₃

Qian Zhang(张倩)¹, Xiang Wu(巫翔)², Shan Qin(秦善)³

1 Gemological Institute, China University of Geosciences, Wuhan 430074, China;
2 State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China;
3 Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education & School of Earth and Space Sciences, Peking University, Beijing 100871, China

Received:2017-05-03 Revised:2017-05-15 Online:2017-09-05 Published:2017-09-05
Contact: Qian Zhang E-mail:qianzhang@cug.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. U1232204 and 41502029) and China Postdoctoral Science Foundation (Grant No. 2015M580679).

摘要/Abstract

摘要： The synthesized monoclinic (B-type) phase of Y₂O₃ has been investigated by in situ angle-dispersive x-ray diffraction in a diamond anvil cell up to 44 GPa at room temperature. A phase transition occurs from monoclinic (B-type) to hexagonal (A-type) phase at 23.5 GPa and these two phases coexist even at the highest pressure. Parameters of isothermal equation of state are V₀=69.0(1) Å³, K₀=159(3) GPa, K₀'=4 (fixed) for the B-type phase and V₀=67.8(2) Å³, K₀=156(3) GPa, K₀'=4 (fixed) for the A-type phase. The structural anisotropy increases with increasing pressure for both phases.

关键词: Y₂O₃, x-ray diffraction, pressure-induced phase transition, equation of state

Abstract: The synthesized monoclinic (B-type) phase of Y₂O₃ has been investigated by in situ angle-dispersive x-ray diffraction in a diamond anvil cell up to 44 GPa at room temperature. A phase transition occurs from monoclinic (B-type) to hexagonal (A-type) phase at 23.5 GPa and these two phases coexist even at the highest pressure. Parameters of isothermal equation of state are V₀=69.0(1) Å³, K₀=159(3) GPa, K₀'=4 (fixed) for the B-type phase and V₀=67.8(2) Å³, K₀=156(3) GPa, K₀'=4 (fixed) for the A-type phase. The structural anisotropy increases with increasing pressure for both phases.

Key words: Y₂O₃, x-ray diffraction, pressure-induced phase transition, equation of state

中图分类号: (High-pressure apparatus; shock tubes; diamond anvil cells)

07.35.+k

61.05.cp (X-ray diffraction) 91.60.Hg (Phase changes)

张倩, 巫翔, 秦善. Pressure-induced phase transition of B-type Y₂O₃[J]. 中国物理B, 2017, 26(9): 90703-090703.

Qian Zhang(张倩), Xiang Wu(巫翔), Shan Qin(秦善). Pressure-induced phase transition of B-type Y₂O₃[J]. Chin. Phys. B, 2017, 26(9): 90703-090703.

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Pressure-induced phase transition of B-type Y₂O₃

Pressure-induced phase transition of B-type Y₂O₃

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