Synthesis, structure and physical properties of ternary Ce-based compound Ce3VAs5

doi:10.1088/1674-1056/ae1ded

中国物理B ›› 2026, Vol. 35 ›› Issue (5): 57111-057111.doi: 10.1088/1674-1056/ae1ded

Synthesis, structure and physical properties of ternary Ce-based compound Ce₃VAs₅

B S Min(闵保森)^1,2, L C Fu(傅立承)^1,3, X M Chen(陈晓铭)^1,4, L C Shi(史鲁川)^1,2, H Y Zheng(郑皓宇)^1,4, J Zhang(张俊)¹, J Song(宋静)¹, Z Deng(邓正)¹, J F Zhao(赵建发)¹, L Duan(段磊)⁴, C J Xiao(肖长江)⁴, J L Zhu(朱金龙)^3,5, X C Wang(望贤成)^1,2,†, and C Q Jin(靳常青)^1,2,‡

1 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2 School of Physics, University of Chinese Academy of Sciences, Beijing 100190, China;
3 Department of Physics, Southern University of Science and Technology, Shenzhen 518055, China;
4 School of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450007, China;
5 Quantum Science Center of Guangdong-Hong Kong-Macao Greater Bay Area (Guangdong), Shenzhen 518045, China

收稿日期:2025-09-12 修回日期:2025-11-05 接受日期:2025-11-01 发布日期:2026-05-11
通讯作者: X C Wang, C Q Jin E-mail:wangxiancheng@iphy.ac.cn;Jin@iphy.ac.cn
基金资助:
This work was supported by the National Key Research and Development Program of China (Grant Nos. 2024YFA1408000 and 2023YFA1406001) and the National Natural Science Foundation of China (Grant No. 12474097).

Synthesis, structure and physical properties of ternary Ce-based compound Ce₃VAs₅

1 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2 School of Physics, University of Chinese Academy of Sciences, Beijing 100190, China;
3 Department of Physics, Southern University of Science and Technology, Shenzhen 518055, China;
4 School of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450007, China;
5 Quantum Science Center of Guangdong-Hong Kong-Macao Greater Bay Area (Guangdong), Shenzhen 518045, China

Received:2025-09-12 Revised:2025-11-05 Accepted:2025-11-01 Published:2026-05-11
Contact: X C Wang, C Q Jin E-mail:wangxiancheng@iphy.ac.cn;Jin@iphy.ac.cn
Supported by:
This work was supported by the National Key Research and Development Program of China (Grant Nos. 2024YFA1408000 and 2023YFA1406001) and the National Natural Science Foundation of China (Grant No. 12474097).

摘要/Abstract

摘要： A new Ce-based compound Ce$_{3}$VAs$_{5}$ has been synthesized at high-pressure and high-temperature conditions. The physical properties were investigated through the crystal structure, magnetism, electrical transport, and specific heat measurements. The compound crystallizes in a hexagonal Hf$_{5}$Sn$_{3}$Cu-anti-type structure with the space group of $P6_{3}$mcm, which consists of face-sharing octahedral VAs$_{6}$ chains and zig-zag like Ce-chains along the $c$ axis. It undergoes a ferromagnetic-like ordering at $T_{\rm N} = 14$ K due to the Ce-lattice, and exhibits heavy fermion behavior with a Sommerfeld coefficient of $\gamma \sim 128$ mJ/(Ce-mol$\cdot$K$^{2}$). The Kondo temperature $T_{\rm K}$ is determined to be $\sim 19 $ K. The deviation of paramagnetic susceptibility from Curie-Weiss law is related to the crystal electric field (CEF) effects, and the abnormal drop in the resistivity is attributed to the synergistic interaction between CEF effect and Kondo scattering. Due to its quasi one-dimensional structure, Ce$_{3}$VAs$_{5}$ provides a good opportunity to study the anisotropy relative to Kondo effect in the future.

关键词: heavy fermion, Kondo effect, Ce-based compound, antiferromagnetism

Abstract: A new Ce-based compound Ce$_{3}$VAs$_{5}$ has been synthesized at high-pressure and high-temperature conditions. The physical properties were investigated through the crystal structure, magnetism, electrical transport, and specific heat measurements. The compound crystallizes in a hexagonal Hf$_{5}$Sn$_{3}$Cu-anti-type structure with the space group of $P6_{3}$mcm, which consists of face-sharing octahedral VAs$_{6}$ chains and zig-zag like Ce-chains along the $c$ axis. It undergoes a ferromagnetic-like ordering at $T_{\rm N} = 14$ K due to the Ce-lattice, and exhibits heavy fermion behavior with a Sommerfeld coefficient of $\gamma \sim 128$ mJ/(Ce-mol$\cdot$K$^{2}$). The Kondo temperature $T_{\rm K}$ is determined to be $\sim 19 $ K. The deviation of paramagnetic susceptibility from Curie-Weiss law is related to the crystal electric field (CEF) effects, and the abnormal drop in the resistivity is attributed to the synergistic interaction between CEF effect and Kondo scattering. Due to its quasi one-dimensional structure, Ce$_{3}$VAs$_{5}$ provides a good opportunity to study the anisotropy relative to Kondo effect in the future.

Key words: heavy fermion, Kondo effect, Ce-based compound, antiferromagnetism

中图分类号: (Strongly correlated electron systems; heavy fermions)

71.27.+a

72.15.Qm (Scattering mechanisms and Kondo effect) 76.50.+g (Ferromagnetic, antiferromagnetic, and ferrimagnetic resonances; spin-wave resonance)

B S Min(闵保森), L C Fu(傅立承), X M Chen(陈晓铭), L C Shi(史鲁川), H Y Zheng(郑皓宇), J Zhang(张俊), J Song(宋静), Z Deng(邓正), J F Zhao(赵建发), L Duan(段磊), C J Xiao(肖长江), J L Zhu(朱金龙), X C Wang(望贤成), and C Q Jin(靳常青). Synthesis, structure and physical properties of ternary Ce-based compound Ce₃VAs₅[J]. 中国物理B, 2026, 35(5): 57111-057111.

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Synthesis, structure and physical properties of ternary Ce-based compound Ce₃VAs₅

Synthesis, structure and physical properties of ternary Ce-based compound Ce₃VAs₅

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