Research progress of Pt and Pt-based cathode electrocatalysts for proton-exchange membrane fuel cells

doi:10.1088/1674-1056/aca081

中国物理B ›› 2022, Vol. 31 ›› Issue (12): 128108-128108.doi: 10.1088/1674-1056/aca081

所属专题： TOPICAL REVIEW — Celebrating 30 Years of Chinese Physics B

Research progress of Pt and Pt-based cathode electrocatalysts for proton-exchange membrane fuel cells

Ni Suo(索妮), Longsheng Cao(曹龙生), Xiaoping Qin(秦晓平), and Zhigang Shao(邵志刚)^†

Fuel-Cell System and Engineering Laboratory, Key Laboratory of Fuel Cells&Hybrid Power Sources, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

收稿日期:2022-04-17 修回日期:2022-09-23 接受日期:2022-11-07 出版日期:2022-11-11 发布日期:2022-11-28
通讯作者: Zhigang Shao E-mail:zhgshao@dicp.ac.cn
基金资助:
Project supported by the National Key Research and Development Program of China (Grant No. 2018YFB1502503) and Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA21090101).

Research progress of Pt and Pt-based cathode electrocatalysts for proton-exchange membrane fuel cells

Ni Suo(索妮), Longsheng Cao(曹龙生), Xiaoping Qin(秦晓平), and Zhigang Shao(邵志刚)^†

Fuel-Cell System and Engineering Laboratory, Key Laboratory of Fuel Cells&Hybrid Power Sources, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Received:2022-04-17 Revised:2022-09-23 Accepted:2022-11-07 Online:2022-11-11 Published:2022-11-28
Contact: Zhigang Shao E-mail:zhgshao@dicp.ac.cn
Supported by:
Project supported by the National Key Research and Development Program of China (Grant No. 2018YFB1502503) and Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA21090101).

摘要/Abstract

摘要： Proton-exchange membrane fuel cells (PEMFCs) have been widely used commercially to solve the energy crisis and environmental pollution. The oxygen reduction reaction (ORR) at the cathode is the rate-determining step in PEMFCs. Platinum (Pt) catalysts are used to accelerate the ORR kinetics. Pt's scarcity, high cost, and instability in an acidic environment at high potentials seriously hinder the commercialization of PEMFCs. Therefore, studies should explore electrocatalysts with high catalytic activity, enhanced stability, and low-Pt loading. This review briefly introduces the research progress on Pt and Pt-based ORR electrocatalysts for PEMFCs, including anticorrosion catalyst supports, Pt, and Pt-based alloy electrocatalysts. Advanced preparation technology and material characterization of Pt-based ORR electrocatalysts are necessary to improve the performance and corresponding reaction mechanisms.

关键词: electrocatalysts, oxygen reduction reaction, activity, stability

Abstract: Proton-exchange membrane fuel cells (PEMFCs) have been widely used commercially to solve the energy crisis and environmental pollution. The oxygen reduction reaction (ORR) at the cathode is the rate-determining step in PEMFCs. Platinum (Pt) catalysts are used to accelerate the ORR kinetics. Pt's scarcity, high cost, and instability in an acidic environment at high potentials seriously hinder the commercialization of PEMFCs. Therefore, studies should explore electrocatalysts with high catalytic activity, enhanced stability, and low-Pt loading. This review briefly introduces the research progress on Pt and Pt-based ORR electrocatalysts for PEMFCs, including anticorrosion catalyst supports, Pt, and Pt-based alloy electrocatalysts. Advanced preparation technology and material characterization of Pt-based ORR electrocatalysts are necessary to improve the performance and corresponding reaction mechanisms.

Key words: electrocatalysts, oxygen reduction reaction, activity, stability

中图分类号: (Carbon/carbon-based materials)

81.05.U-

81.07.-b (Nanoscale materials and structures: fabrication and characterization) 81.07.Bc (Nanocrystalline materials) 82.45.Jn (Surface structure, reactivity and catalysis)

Ni Suo(索妮), Longsheng Cao(曹龙生), Xiaoping Qin(秦晓平), and Zhigang Shao(邵志刚). Research progress of Pt and Pt-based cathode electrocatalysts for proton-exchange membrane fuel cells[J]. 中国物理B, 2022, 31(12): 128108-128108.

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Research progress of Pt and Pt-based cathode electrocatalysts for proton-exchange membrane fuel cells

Research progress of Pt and Pt-based cathode electrocatalysts for proton-exchange membrane fuel cells

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