Novel closed-cycle reaction mode for totally green production of Cu1.8Se nanoparticles based on laser-generated Se colloidal solution

doi:10.1088/1674-1056/ac6db2

中国物理B ›› 2022, Vol. 31 ›› Issue (7): 78102-078102.doi: 10.1088/1674-1056/ac6db2

所属专题： TOPICAL REVIEW—Laser and plasma assisted synthesis of advanced nanomaterials in liquids

Novel closed-cycle reaction mode for totally green production of Cu_1.8Se nanoparticles based on laser-generated Se colloidal solution

Zhangyu Gu(顾张彧)^1,2,†, Yisong Fan(范一松)^3,†, Yixing Ye(叶一星)^2,†, Yunyu Cai(蔡云雨)^2,‡, Jun Liu(刘俊)², Shouliang Wu(吴守良)², Pengfei Li(李鹏飞)², Junhua Hu(胡俊华)⁴, Changhao Liang(梁长浩)^2,4,5,§, and Yao Ma(马垚)^2,6

1 Henan Institute of Advanced Technology, Zhengzhou University, Zhengzhou 450001, China;
2 Key Laboratory of Materials Physics and Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China;
3 Anhui Institute of Optics and Fine Mechanics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China;
4 School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China;
5 University of Science and Technology of China, Hefei 230026, China;
6 Technology Center, Benecke Changshun Auto Trim(Zhangjiagang) Co., Ltd., No. 8, Changyang Rd., Nansha, Jingang Town, Zhangjiagang 215632, China

收稿日期:2022-03-06 修回日期:2022-04-03 接受日期:2022-05-07 出版日期:2022-06-09 发布日期:2022-07-19
通讯作者: Yunyu Cai, Changhao Liang E-mail:yycai@issp.ac.cn;chliang@issp.ac.cn
基金资助:
Project supported by the Fund from Hefei National Laboratory for Physical Sciences at the Microscale (Grant No. KF2020110), the Natural Science Foundation of Anhui Province, China (Grant No. 1908085ME146), the Key Research and Development Plan of Anhui Province, China (Grant No. 201904a05020049), the Director Fund of Institute of Solid State Physics, Chinese Academy of Sciences (Grant No. 2019DFY01), the National Natural Science Foundation of China (Grant Nos. 52071313 and 51971211), and the Hefei Institutes of Physical Science, Chinese Academy of Sciences Director's Fund (Grant Nos. YZJJZX202018 and YZJJ202102).

Novel closed-cycle reaction mode for totally green production of Cu_1.8Se nanoparticles based on laser-generated Se colloidal solution

1 Henan Institute of Advanced Technology, Zhengzhou University, Zhengzhou 450001, China;
2 Key Laboratory of Materials Physics and Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China;
3 Anhui Institute of Optics and Fine Mechanics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China;
4 School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China;
5 University of Science and Technology of China, Hefei 230026, China;
6 Technology Center, Benecke Changshun Auto Trim(Zhangjiagang) Co., Ltd., No. 8, Changyang Rd., Nansha, Jingang Town, Zhangjiagang 215632, China

Received:2022-03-06 Revised:2022-04-03 Accepted:2022-05-07 Online:2022-06-09 Published:2022-07-19
Contact: Yunyu Cai, Changhao Liang E-mail:yycai@issp.ac.cn;chliang@issp.ac.cn
Supported by:
Project supported by the Fund from Hefei National Laboratory for Physical Sciences at the Microscale (Grant No. KF2020110), the Natural Science Foundation of Anhui Province, China (Grant No. 1908085ME146), the Key Research and Development Plan of Anhui Province, China (Grant No. 201904a05020049), the Director Fund of Institute of Solid State Physics, Chinese Academy of Sciences (Grant No. 2019DFY01), the National Natural Science Foundation of China (Grant Nos. 52071313 and 51971211), and the Hefei Institutes of Physical Science, Chinese Academy of Sciences Director's Fund (Grant Nos. YZJJZX202018 and YZJJ202102).

摘要/Abstract

摘要： Non-stoichiometric copper selenide (Cu_2-xSe, x=0.18～0.25) nanomaterials have attracted extensive attentions due to their excellent thermoelectric, optoelectronic and photocatalytic performances. However, efficient production of Cu_2-xSe nanoparticles (NPs) through a green and convenient way is still hindered by the inevitable non-environmentally friendly operations in common chemical synthesis. Herein, we initially reveal the coexistence of seleninic acid content and elemental selenium (Se) NPs in pulsed laser-generated Se colloidal solution. Consequently, we put forward firstly a closed-cycle reaction mode for totally green production of Cu_1.8Se NPs to exclude traditional requirements of high temperature and toxic precursors by using Se colloidal solution. In such closed-cycle reaction, seleninic acid works as the initiator to oxidize copper sheet to release cuprous ions which can catalyze the disproportion of Se NPs to form SeO₃^2- and Se^2- ions and further produce Cu_2-xSe NPs, and the by-product SeO₃^2- ions promote subsequent formation of cuprous from the excessive Cu sheet. In experiments, the adequate copper (Cu) sheet was simply dipped into such Se colloidal solution at 70 ℃, and then the stream of Cu_1.8Se NPs could be produced until the exhaustion of selenium source. The conversion rate of Se element reaches to more than 75% when the size of Se NPs in weakly acidic colloidal solution is limited between 1 nm and 50 nm. The laser irradiation duration shows negative correlation with the size of Se NPs and unobvious impact to the pH of the solution which both are essential to the high yield of Cu_1.8Se NPs. Before Cu sheet is exhausted, Se colloidal solution can be successively added without influences to the product quality and the Se conversion rate. Such green methodology positively showcases a brand-new and potential strategy for mass production of Cu_2-xSe nanomaterials.

关键词: non-stoichiometric copper selenide, green production, selenium colloidal solution, laser irradiation in liquids

Abstract: Non-stoichiometric copper selenide (Cu_2-xSe, x=0.18～0.25) nanomaterials have attracted extensive attentions due to their excellent thermoelectric, optoelectronic and photocatalytic performances. However, efficient production of Cu_2-xSe nanoparticles (NPs) through a green and convenient way is still hindered by the inevitable non-environmentally friendly operations in common chemical synthesis. Herein, we initially reveal the coexistence of seleninic acid content and elemental selenium (Se) NPs in pulsed laser-generated Se colloidal solution. Consequently, we put forward firstly a closed-cycle reaction mode for totally green production of Cu_1.8Se NPs to exclude traditional requirements of high temperature and toxic precursors by using Se colloidal solution. In such closed-cycle reaction, seleninic acid works as the initiator to oxidize copper sheet to release cuprous ions which can catalyze the disproportion of Se NPs to form SeO₃^2- and Se^2- ions and further produce Cu_2-xSe NPs, and the by-product SeO₃^2- ions promote subsequent formation of cuprous from the excessive Cu sheet. In experiments, the adequate copper (Cu) sheet was simply dipped into such Se colloidal solution at 70 ℃, and then the stream of Cu_1.8Se NPs could be produced until the exhaustion of selenium source. The conversion rate of Se element reaches to more than 75% when the size of Se NPs in weakly acidic colloidal solution is limited between 1 nm and 50 nm. The laser irradiation duration shows negative correlation with the size of Se NPs and unobvious impact to the pH of the solution which both are essential to the high yield of Cu_1.8Se NPs. Before Cu sheet is exhausted, Se colloidal solution can be successively added without influences to the product quality and the Se conversion rate. Such green methodology positively showcases a brand-new and potential strategy for mass production of Cu_2-xSe nanomaterials.

Key words: non-stoichiometric copper selenide, green production, selenium colloidal solution, laser irradiation in liquids

中图分类号: (Nanoscale materials and structures: fabrication and characterization)

81.07.-b

79.20.Eb (Laser ablation) 64.70.pv (Colloids) 73.61.Le (Other inorganic semiconductors)

Zhangyu Gu(顾张彧), Yisong Fan(范一松), Yixing Ye(叶一星), Yunyu Cai(蔡云雨), Jun Liu(刘俊), Shouliang Wu(吴守良), Pengfei Li(李鹏飞), Junhua Hu(胡俊华), Changhao Liang(梁长浩), and Yao Ma(马垚). Novel closed-cycle reaction mode for totally green production of Cu_1.8Se nanoparticles based on laser-generated Se colloidal solution[J]. 中国物理B, 2022, 31(7): 78102-078102.

参考文献

[1] Xu J, Yang Q, Kang W, Huang X, Wu C, Wang L, Luo L, Zhang W and Lee C-S 2015 Part. Part. Syst. Charact. 32 840
[2] Zhang H, Wang C, Peng W, Yang C and Zhong X 2016 Nano Energy 23 60
[3] Wang X, Miao Z, Ma Y, Chen H, Qian H and Zha Z 2017 Nanoscale 9 14512
[4] Wang X, Ma Y, Chen H, Wu X, Qian H, Yang X and Zha Z 2017 Colloid. Surf. B 152 449
[5] Zhang S, Sun C, Zeng J, Sun Q, Wang G, Wang Y, Wu Y, Dou S, Gao M and Li Z 2016 Adv. Mater. 28 8927
[6] Hu J, Song G, Han L, Zou W, Xiao Z, Huang X, Qin Z and Zou R 2014 Nano-Micro. Lett. 6 169
[7] Wang X, Zhong X, Lei H, Geng Y, Zhao Q, Gong F, Yang Z, Dong Z, Liu Z and Cheng L 2019 Chem. Mater. 31 6174
[8] Liu X, Lee C, Law W C, Zhu D, Liu M, Jeon M, Kim J, Prasad P N, Kim C and Swihart M T 2013 Nano. Lett. 13 4333
[9] Xiao X X, Xie W J, Tang X F and Zhang Q J 2011 Chin. Phys. B 20 087201
[10] Wang X, Ma Y, Sheng X, Wang Y and Xu H 2018 Nano. Lett. 18 2217
[11] Xiao G, Ning J, Liu Z, Sui Y, Wang Y, Dong Q, Tian W, Liu B, Zou G and Zou B 2012 Crystengcomm 14 2139
[12] Zhang Y, Hu C, Zheng C, Xi Y and Wan B 2010 J. Phys. Chem. C 114 14849
[13] Wang Y, Zhukovskyi M, Tongying P, Tian Y and Kuno M 2014 J. Phys. Chem. Lett. 5 3608
[14] Chen X, Gu L, Liu L, Chen H, Li J, Liu C and Zhou P 2020 Chin. Phys. B 29 097201
[15] Wang A, Liu Z, Pan J, Li Q, Li G, Huan Q, Du S and Gao H J 2020 Chin. Phys. B 29 078102
[16] Koren B, Friedman O, Maman N, Hayun S, Ezersky V and Golan Y 2022 RSC. Adv. 12 277
[17] Chen J Y, Zhao X Y, Liu L and Xu J P 2019 Chin. Phys. B 28 128101
[18] Hosnedlova B, Kepinska M, Skalickova S, Fernandez C, Ruttkay-Nedecky B, Peng Q, Baron M, Melcova M, Opatrilova R, Zidkova J, Bjorklund G, Sochor J and Kizek R 2018 Int. J. Nanomed. 13 2107
[19] Lie S Q, Wang D M, Gao M X and Huang C Z 2014 Nanoscale 6 10289
[20] Riha S C, Johnson D C and Prieto A L 2011 J. Am. Chem. Soc. 133 1383
[21] Haynes W M, Lide D R and Bruno T J 2016 CRC Handbook of Chemistry and Physics, 97th edn. (CRC Press) pp. 5-75
[22] Amendola V, Amans D, Ishikawa Y, Koshizaki N, Scire S, Compagnini G, Reichenberger S and Barcikowski S 2020 Chemistry 26 9206
[23] Zamiri R, Bahari-Poor H R, Zakaria A, Jorfi R, Zamiri G, Rebelo A and Omar A A 2013 Chin. Phys. Lett. 30 118103
[24] Crivellaro S, Guadagnini A, Arboleda D M, Schinca D and Amendola V 2019 Rev. Sci. Instrum. 90 033902
[25] Labusch M, Cunha A P, Wirtz S F, Reichenberger S, Cleve E, Söffker D and Barcikowski S 2019 Appl. Surf. Sci. 479 887
[26] Cui Y H, Li L L, Zhou N Q, Liu J H, Huang Q, Wang H J, Tian J and Yu H Q 2016 Enzyme Microb. Technol. 95 185
[27] Yan S, Wang H, Zhang Y, Li S and Xiao Z 2009 Mater. Chem. Phys. 114 300
[28] P C, Shah, Kumar M, Pushpa K K and Bajaj P N 2008 Cryst. Growth Des. 8 6
[29] Cai Y, Zhang Y, Ji S, Ye Y, Wu S, Liu J, Chen S and Liang C 2020 J. Colloid. Interface. Sci. 566 284
[30] Cai Y, Ye Y, Li P, Zhou Y, Liu J, Tian Z, Yang Z and Liang C 2019 Appl. Surf. Sci. 473 564
[31] Chen Q, Zhang C, Liu J, Ye Y, Li P and Liang C 2019 Appl. Surf. Sci. 466 1000
[32] Shevchik N J, Cardona M and Tejeda J 1973 Phys. Rev. B 8 2833
[33] Malmsten G, Thorh S H I, Bergmark J E and Karlsson S E 1971 Phys. Scripta 3 96
[34] Gan X Y, Keller E L, Warkentin C L, Crawford S E, Frontiera R R and Millstone J E 2019 Nano. Lett. 19 2384
[35] Yang D, Zhu Q, Chen C, Liu H, Liu Z, Zhao Z, Zhang X, Liu S and Han B 2019 Nat. Commun. 10 677
[36] Brisk M A and Baker A 1975 J. Electron Spectrosc. Relat. Phenom. 7 197
[37] White S L, Smith J G, Behl M and Jain P K 2013 Nat. Commun. 4 2933
[38] Liu Y, Dong Q, Wei H, Ning Y, Sun H, Tian W, Zhang H and Yang B 2011 J. Phys. Chem. C 115 9909

Novel closed-cycle reaction mode for totally green production of Cu_1.8Se nanoparticles based on laser-generated Se colloidal solution

Novel closed-cycle reaction mode for totally green production of Cu_1.8Se nanoparticles based on laser-generated Se colloidal solution

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