Table-like shape magnetocaloric effect and large refrigerant capacity in dual-phase HoNi/HoNi2 composite

doi:10.1088/1674-1056/aba9be

中国物理B ›› 2020, Vol. 29 ›› Issue (10): 107502-.doi: 10.1088/1674-1056/aba9be

Dan Guo(郭丹)¹, Yikun Zhang(张义坤)¹^,†(), Yaming Wang(王雅鸣)¹, Jiang Wang(王江)¹, Zhongming Ren(任忠鸣)¹^,‡()

收稿日期:2020-06-12 修回日期:2020-07-11 接受日期:2020-07-28 出版日期:2020-10-05 发布日期:2020-10-05
通讯作者: Yikun Zhang(张义坤), Zhongming Ren(任忠鸣)

Table-like shape magnetocaloric effect and large refrigerant capacity in dual-phase HoNi/HoNi₂ composite

Dan Guo(郭丹), Yikun Zhang(张义坤)†, Yaming Wang(王雅鸣), Jiang Wang(王江), and Zhongming Ren(任忠鸣)‡

¹ State Key Laboratory of Advanced Special Steels & Shanghai Key Laboratory of Advanced Ferrometallurgy & School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China

Received:2020-06-12 Revised:2020-07-11 Accepted:2020-07-28 Online:2020-10-05 Published:2020-10-05
Contact: ^†Corresponding author. E-mail: ykzhang@shu.edu.cn ^‡Corresponding author. E-mail: zmren@shu.edu.cn
About author:
†Corresponding author. E-mail: ykzhang@shu.edu.cn
‡Corresponding author. E-mail: zmren@shu.edu.cn
* Project supported by the National Natural Science Foundation of China (Grant No. 51690162), Science and Technology Committee of Shanghai, China (Grant No. 19ZR1418300), Independent Research and Development Project of State Key Laboratory of Advanced Special Steel, Shanghai Key Laboratory of Advanced Ferrometallurgy, Shanghai University (Grant No. SKLASS 2019-Z003), and the Science and Technology Commission of Shanghai Municipality, China (Grant No. 19DZ2270200).

摘要/Abstract

Abstract:

Nowadays, magnetic cooling (MC) technology by using the magnetocaloric effect (MCE) has attracted extensive research interest for its promising practical applications. A constant large/giant MCE covers wide refrigeration temperatures (denote as table-like shape) is beneficial for obtaining high efficiency performance for MC. In this paper, the HoNi/HoNi₂ composite was successfully synthesized by arc-melting method and proved to be composed of HoNi and HoNi₂ crystalline phases with weight ratios of 52.4 wt.% and 47.6 wt.%, respectively. The maximum magnetic entropy change ($ -{\rm{\Delta }}{S}_{M}^{{\rm{\max }}} $ ) is 18.23 J/(kg⋅K), and the refrigerant capacity values RC₁, RC₂, and RC₃ are 867.9 J/kg, 676.4 J/kg, and 467.8 J/kg with ΔH = 0–70 kOe, respectively. The table-like shape MCE and large refrigerant capacity values make the composite attractive for cryogenic MC using the Ericsson cycle.

Key words: HoNi-HoNi₂ composite, magnetic refrigeration, table-like magnetocaloric effect

中图分类号: (Rare earth metals and alloys)

71.20.Eh

75.30.Sg (Magnetocaloric effect, magnetic cooling) 75.30.Cr (Saturation moments and magnetic susceptibilities)

Dan Guo(郭丹), Yikun Zhang(张义坤), Yaming Wang(王雅鸣), Jiang Wang(王江), Zhongming Ren(任忠鸣). [J]. 中国物理B, 2020, 29(10): 107502-.

Dan Guo(郭丹), Yikun Zhang(张义坤)†, Yaming Wang(王雅鸣), Jiang Wang(王江), and Zhongming Ren(任忠鸣)‡. Table-like shape magnetocaloric effect and large refrigerant capacity in dual-phase HoNi/HoNi₂ composite[J]. Chin. Phys. B, 2020, 29(10): 107502-.

图/表 5

参考文献 35

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Materials	T_M/K	$ -{\rm{\Delta }}{S}_{M}^{\max } $ /J⋅kg⁻¹⋅K⁻¹	RC₁/J⋅kg⁻¹	Ref.
HoNi/HoNi₂	13/16/38.5	14.93	623.5	this work
HoNi	13.5/35.5	16.6	∼691	[26]
ErGa	15/30	21.3	∼658	[17]
0.4(DyNi₂) + 0.6(TbNi₂)	21.5/37	12.9	526	[18]
HoPdIn	6/23	14.6	496	[20]
ErZn₂/ErZn	9/20	19.5	447	[23]
GdCo₂B₂C	17.2	10.34	238.1	[30]
Ho₃Pd₂	9.6	18.6	230	[31]
Gd₂NiSi₃	16	13	233	[32]
Tm₂Cu₂In	39.4	14.4	331	[33]
Ho₂Co₂Ga	38.5	11.7	271	[34]
Dy₁₁Co₄In₉	37	3.53	128.4	[35]

Table-like shape magnetocaloric effect and large refrigerant capacity in dual-phase HoNi/HoNi₂ composite

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