Hydrogen sulphide detection using near-infrared diode laser and compact dense-pattern multipass cell

doi:10.1088/1674-1056/28/6/063301

中国物理B ›› 2019, Vol. 28 ›› Issue (6): 63301-063301.doi: 10.1088/1674-1056/28/6/063301

• SPECIAL TOPIC—Recent advances in thermoelectric materials and devices • 上一篇下一篇

Hydrogen sulphide detection using near-infrared diode laser and compact dense-pattern multipass cell

Xing Tian(田兴), Yuan Cao(曹渊), Jia-Jin Chen(陈家金), Kun Liu(刘锟), Gui-Shi Wang(王贵师), Xiao-Ming Gao(高晓明)

1 Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China;
2 University of Science and Technology of China, Hefei 230026, China

收稿日期:2019-03-11 修回日期:2019-04-11 出版日期:2019-06-05 发布日期:2019-06-05
通讯作者: Kun Liu E-mail:liukun@aiofm.ac.cn
基金资助:
Project supported by the National Key Research and Development Program of China (Grant Nos. 2016YFC0303900 and 2017YFC0209700).

Hydrogen sulphide detection using near-infrared diode laser and compact dense-pattern multipass cell

Xing Tian(田兴)^1,2, Yuan Cao(曹渊)^1,2, Jia-Jin Chen(陈家金)¹, Kun Liu(刘锟)¹, Gui-Shi Wang(王贵师)¹, Xiao-Ming Gao(高晓明)¹

1 Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China;
2 University of Science and Technology of China, Hefei 230026, China

Received:2019-03-11 Revised:2019-04-11 Online:2019-06-05 Published:2019-06-05
Contact: Kun Liu E-mail:liukun@aiofm.ac.cn
Supported by:
Project supported by the National Key Research and Development Program of China (Grant Nos. 2016YFC0303900 and 2017YFC0209700).

摘要/Abstract

摘要：

Sub-ppmv level detection of hydrogen sulphide (H₂S) using a 1.578-μm distributed feedback tunable diode laser combining with wavelength modulation spectroscopy and second harmonic detection scheme is reported. A home-developed novel compact dense-pattern multipass gas cell with an effective optical path length of 29.37 m is used to improve sensitivity and reduce sample volume. Detection parameters are optimized, including modulation frequency and amplitude. The analysis of Allan variance shows that a minimum detectable concentration 60 ppbv is obtained with a lock-in time constant of 10 ms, and a detection limit of 13 ppbv can be achieved by average in 300 s. The demonstrated H₂S sensor has a strong penitential application in natural gas process for regulating and controlling H₂S concentration.

关键词: hydrogen sulphide, wavelength modulation spectroscopy, second harmonic detection, detection limit

Abstract:

Key words: hydrogen sulphide, wavelength modulation spectroscopy, second harmonic detection, detection limit

中图分类号: (Infrared spectra)

33.20.Ea

42.55.-f (Lasers) 42.62.-b (Laser applications) 42.62.Fi (Laser spectroscopy)

田兴, 曹渊, 陈家金, 刘锟, 王贵师, 高晓明. Hydrogen sulphide detection using near-infrared diode laser and compact dense-pattern multipass cell[J]. 中国物理B, 2019, 28(6): 63301-063301.

Xing Tian(田兴), Yuan Cao(曹渊), Jia-Jin Chen(陈家金), Kun Liu(刘锟), Gui-Shi Wang(王贵师), Xiao-Ming Gao(高晓明). Hydrogen sulphide detection using near-infrared diode laser and compact dense-pattern multipass cell[J]. Chin. Phys. B, 2019, 28(6): 63301-063301.

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Hydrogen sulphide detection using near-infrared diode laser and compact dense-pattern multipass cell

Hydrogen sulphide detection using near-infrared diode laser and compact dense-pattern multipass cell

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