Facile and controllable synthesis of molybdenum disulfide quantum dots for highly sensitive and selective sensing of copper ions

doi:10.1088/1674-1056/27/5/056104

中国物理B ›› 2018, Vol. 27 ›› Issue (5): 56104-056104.doi: 10.1088/1674-1056/27/5/056104

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

Facile and controllable synthesis of molybdenum disulfide quantum dots for highly sensitive and selective sensing of copper ions

Xue Li(李雪), Da-Wei He(何大伟), Yong-Sheng Wang(王永生), Yin Hu(胡音), Xuan Zhao(赵宣), Chen Fu(付晨), Jing-Yan Wu(吴静燕)

Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Beijing 100044, China

收稿日期:2017-12-16 修回日期:2018-02-26 出版日期:2018-05-05 发布日期:2018-05-05
通讯作者: Da-Wei He E-mail:dwhe@bjtu.edu.cn
基金资助:
Project supported by the National Key R&D Program of China (Grant No.2016YFA0202302),the National Natural Science Foundation of China (Grant Nos.61335006,61527817,and 61378073),the Overseas Expertise Introduction Center for Discipline Innovation,111 Center,China,and the National Basic Research Program of China (Grant No.KSJB17030536).

Facile and controllable synthesis of molybdenum disulfide quantum dots for highly sensitive and selective sensing of copper ions

Xue Li(李雪), Da-Wei He(何大伟), Yong-Sheng Wang(王永生), Yin Hu(胡音), Xuan Zhao(赵宣), Chen Fu(付晨), Jing-Yan Wu(吴静燕)

Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Beijing 100044, China

Received:2017-12-16 Revised:2018-02-26 Online:2018-05-05 Published:2018-05-05
Contact: Da-Wei He E-mail:dwhe@bjtu.edu.cn
Supported by:
Project supported by the National Key R&D Program of China (Grant No.2016YFA0202302),the National Natural Science Foundation of China (Grant Nos.61335006,61527817,and 61378073),the Overseas Expertise Introduction Center for Discipline Innovation,111 Center,China,and the National Basic Research Program of China (Grant No.KSJB17030536).

摘要/Abstract

摘要：

Molybdenum disulfide quantum dots (MoS₂ QDs) were synthesized via a hydrothermal method using sodium molybdate and cysteine as molybdenum and sulfur sources, respectively. The optimal hydrothermal time was studied. Furthermore, the as synthesized water-soluble MoS₂ QDs were used as a fluorescence probe for the sensitive and selective detection of copper ions. The fluorescence of the MoS₂ QDs was quenched after the addition of copper ions; the reason may be that the transfer of the excited electron from QDs to copper ions leads to the reduction of the radiative recombination. The fluorescence quenching of MoS₂ QDs is linearly dependent on the copper ions concentration ranging from 0.1 μM to 600 μM, the limit of detection is 0.098 μM, which is much lower than that of existing methods. Moreover, the MoS₂ QDs show highly selectivity towards the detection of copper ions.

关键词: MoS₂ quantum dots, photoluminescence, fluorescent probe

Abstract:

Key words: MoS₂ quantum dots, photoluminescence, fluorescent probe

中图分类号: (Structure of nanocrystals and nanoparticles ("colloidal" quantum dots but not gate-isolated embedded quantum dots))

61.46.Df

78.55.-m (Photoluminescence, properties and materials) 87.85.fk (Biosensors)

李雪, 何大伟, 王永生, 胡音, 赵宣, 付晨, 吴静燕. Facile and controllable synthesis of molybdenum disulfide quantum dots for highly sensitive and selective sensing of copper ions[J]. 中国物理B, 2018, 27(5): 56104-056104.

Xue Li(李雪), Da-Wei He(何大伟), Yong-Sheng Wang(王永生), Yin Hu(胡音), Xuan Zhao(赵宣), Chen Fu(付晨), Jing-Yan Wu(吴静燕). Facile and controllable synthesis of molybdenum disulfide quantum dots for highly sensitive and selective sensing of copper ions[J]. Chin. Phys. B, 2018, 27(5): 56104-056104.

参考文献 43

[10]	Wang J, Zhou X, Ma H and Tao G 2011 Spectrochimica Acta Part A Molecular & Biomolecular Spectroscopy 81 178
[1]	Kumar M, Kumar N, Bhalla V, Sharma P R and Kaur T 2012 Org. Lett. 14 406
[11]	Chen J, Li Y, Lv K, Zhong W, Wang H, Wu Z, Yi P and Jiang J 2016 Sensor. Actuat. B-Chem. 224 298
[2]	Liu X, Gao W, Zhou X and Ma Y 2014 J. Mater. Res. 29 1401
[12]	Wang F, Gu Z, Lei W, Wang W, Xia X and Hao Q 2014 Sensor. Actuat. B-Chem. 190 516
[3]	Zhao J, Deng J, Yi Y, Li H, Zhang Y and Yao S 2014 Talanta 125 372
[13]	Gan Z X, Gui Q F, Shan Y, Pan P F, Zhang N and Zhang L F 2016 J. Appl. Phys. 120 104503
[4]	Jin L H and Han C S 2014 Anal. Chem. 86 7209
[14]	Niu Y, Jiao W, Wang R, Ding G and Huang Y 2016 J. Mater. Chem. A 4 8198
[5]	Li Y M, Zhang X L, Zhu B C, Xue J, Zhu Z and Tan W H 2011 The Analyst 136 1124
[15]	Zhao X, He D W, Wang Y S, Hu Y, Fu C and Li X 2017 Chin. Phys. B 26 066102
[6]	Barati A, Shamsipur M and Abdollahi H 2016 Sensor. Actuat. B-Chem. 230 289
[16]	Yuwen L H, Zhou J J, Zhang Y Q, Zhang Q, Shang J Y, Luo Z M, Weng L X, Teng Z G and Wang L H 2016 Nanoscale 8 2720
[7]	Jin L, Zhang Z, Tang A, Cong L and Shen Y 2016 Biosens. Bioelectron. 79 108
[17]	Zhang S, Jia X F and Wang E 2016 Nanoscale. 8 15152
[8]	Lan G Y, Huang C C and Chang H T 2010 Chem. Comm. 46 1257
[18]	Ren X P, Ma Q, Fan H, Pang L Q, Zhang Y X, Yao Y, Ren X D and Liu S Z 2015 Chem.Commun. 51 15997
[9]	Yao J, Zhang K, Zhu H, Ma F, Sun M, Yu H, Sun J and Wang S 2013 Anal. Chem. 85 6461
[19]	Ren X P, Ren X D, Pang L Q, Zhang Y X, Ma Q, Fan H B and Liu S Z 2016 Int. J. Hydrogen. energ. 41 916
[10]	Wang J, Zhou X, Ma H and Tao G 2011 Spectrochimica Acta Part A Molecular & Biomolecular Spectroscopy 81 178
[20]	Gu W, Yan Y H, Zhang C L, Ding C P, and Xian Y Z 2016 Acs. Appl. Mater. Inter. 8 11272
[11]	Chen J, Li Y, Lv K, Zhong W, Wang H, Wu Z, Yi P and Jiang J 2016 Sensor. Actuat. B-Chem. 224 298
[21]	Hariharan S and Karthikeyan B 2016 Rsc Advances 6 101770
[12]	Wang F, Gu Z, Lei W, Wang W, Xia X and Hao Q 2014 Sensor. Actuat. B-Chem. 190 516
[22]	Lö Z, Mahmood N, Tahir M, Pan L, Zhang X W and Zou J J 2016 Nanoscale 8 18250
[13]	Gan Z X, Gui Q F, Shan Y, Pan P F, Zhang N and Zhang L F 2016 J. Appl. Phys. 120 104503
[23]	Park S J, Sang W P, Qiu D, Kang J H, Song D Y and Kim E K 2017 J. Lumin. 183 62
[14]	Niu Y, Jiao W, Wang R, Ding G and Huang Y 2016 J. Mater. Chem. A 4 8198
[24]	Qiao W, Yan S, Song X, Zhang X, He X, Zhong W and Du Y 2015 Appl. Surf. SCI 359 130
[15]	Zhao X, He D W, Wang Y S, Hu Y, Fu C and Li X 2017 Chin. Phys. B 26 066102
[25]	Gu W, Yan Y, Cao X, Zhang C, Ding C and Xian Y 2016 J. Mater. Chem. B 4 27
[16]	Yuwen L H, Zhou J J, Zhang Y Q, Zhang Q, Shang J Y, Luo Z M, Weng L X, Teng Z G and Wang L H 2016 Nanoscale 8 2720
[26]	Haldar D, Dinda D and Saha S K 2016 J. Mater. Chem. C 4 6321
[17]	Zhang S, Jia X F and Wang E 2016 Nanoscale. 8 15152
[27]	Pei L, Tao S, Shu H and Song X 2015 Solid. State. Commun. 218 25
[18]	Ren X P, Ma Q, Fan H, Pang L Q, Zhang Y X, Yao Y, Ren X D and Liu S Z 2015 Chem.Commun. 51 15997
[28]	Zhou K, Zhang Y, Xia Z and Wei W 2016 Nanotechnology 27 275101
[19]	Ren X P, Ren X D, Pang L Q, Zhang Y X, Ma Q, Fan H B and Liu S Z 2016 Int. J. Hydrogen. energ. 41 916
[29]	Xu S, Li D and Wu P 2015 Adv. Funct. Mater. 25 1127
[20]	Gu W, Yan Y H, Zhang C L, Ding C P, and Xian Y Z 2016 Acs. Appl. Mater. Inter. 8 11272
[30]	Wang N, Wei F, Qi Y H, Li H X, Lu Xin, Zhao G Q and Xu Q 2014 Acs. Appl. Mater. Inter. 6 19888
[21]	Hariharan S and Karthikeyan B 2016 Rsc Advances 6 101770
[31]	Ren X, Pang L, Zhang Y, Ren X, Fan H and Liu S 2015 J. Mater. Chem. A 3 10693
[22]	Lö Z, Mahmood N, Tahir M, Pan L, Zhang X W and Zou J J 2016 Nanoscale 8 18250
[32]	Wang Z, Lin J, Gao J and Wang Q 2016 Mater. Chem. Phys. 178 82
[23]	Park S J, Sang W P, Qiu D, Kang J H, Song D Y and Kim E K 2017 J. Lumin. 183 62
[33]	Xua Y L, Niu X Y, Chen H L, Zhao S G and Chen X G 2017 Chin. Chem. Lett. 28 338
[24]	Qiao W, Yan S, Song X, Zhang X, He X, Zhong W and Du Y 2015 Appl. Surf. SCI 359 130
[34]	Dai W, Dong H, Fugetsu B, Cao Y, Lu H, Ma X and Zhang X 2015 Small 11 4158
[25]	Gu W, Yan Y, Cao X, Zhang C, Ding C and Xian Y 2016 J. Mater. Chem. B 4 27
[35]	Gopalakrishnan D, Damien D, Li B, Gullappalli H, Pillai V, Ajayan P and Shaijumon M 2015 Chem. Commun. 51 6293
[26]	Haldar D, Dinda D and Saha S K 2016 J. Mater. Chem. C 4 6321
[36]	Zhang X, Lai Z, Liu Z, Tan C, Huang Y, Li B, Zhao M, Xie L, Huang W and Zhang H 2015 Angew. Chem., Int. Ed. 54 5425
[27]	Pei L, Tao S, Shu H and Song X 2015 Solid. State. Commun. 218 25
[37]	Štengl V and Henych J 2013 Nanoscale 5 3387
[28]	Zhou K, Zhang Y, Xia Z and Wei W 2016 Nanotechnology 27 275101
[38]	Li B, Chen L, Zou H, Lei J, Luo H and Li N 2014 Nanoscale 6 9831
[29]	Xu S, Li D and Wu P 2015 Adv. Funct. Mater. 25 1127
[39]	Fahimi-Kashani N, Rashti A, Hormozi-Nezhad M R and Mahdavic V 2017 Anal. Methods 9 716
[30]	Wang N, Wei F, Qi Y H, Li H X, Lu Xin, Zhao G Q and Xu Q 2014 Acs. Appl. Mater. Inter. 6 19888
[40]	Li W Z, Li F, Wang X, Tang Y, Yang Y Y, Gao W B and Li R 2017 Appl. Surf. 401 190
[31]	Ren X, Pang L, Zhang Y, Ren X, Fan H and Liu S 2015 J. Mater. Chem. A 3 10693
[41]	Gu W, Yan Y, Zhang C, Ding C and Xian Y 2016 Acs. Appl. Mater. Interfaces 8 11272
[32]	Wang Z, Lin J, Gao J and Wang Q 2016 Mater. Chem. Phys. 178 82
[42]	Wang Y and Ni Y 2014 Anal. Chem. 86 7463
[33]	Xua Y L, Niu X Y, Chen H L, Zhao S G and Chen X G 2017 Chin. Chem. Lett. 28 338
[43]	Wang F, Gu Z, Lei W, Wang W, Xia X and Hao Q 2014 Sensor. Actuat B-Chem. 190 516
[34]	Dai W, Dong H, Fugetsu B, Cao Y, Lu H, Ma X and Zhang X 2015 Small 11 4158
[35]	Gopalakrishnan D, Damien D, Li B, Gullappalli H, Pillai V, Ajayan P and Shaijumon M 2015 Chem. Commun. 51 6293
[36]	Zhang X, Lai Z, Liu Z, Tan C, Huang Y, Li B, Zhao M, Xie L, Huang W and Zhang H 2015 Angew. Chem., Int. Ed. 54 5425
[37]	Štengl V and Henych J 2013 Nanoscale 5 3387
[38]	Li B, Chen L, Zou H, Lei J, Luo H and Li N 2014 Nanoscale 6 9831
[39]	Fahimi-Kashani N, Rashti A, Hormozi-Nezhad M R and Mahdavic V 2017 Anal. Methods 9 716
[40]	Li W Z, Li F, Wang X, Tang Y, Yang Y Y, Gao W B and Li R 2017 Appl. Surf. 401 190
[41]	Gu W, Yan Y, Zhang C, Ding C and Xian Y 2016 Acs. Appl. Mater. Interfaces 8 11272
[42]	Wang Y and Ni Y 2014 Anal. Chem. 86 7463
[43]	Wang F, Gu Z, Lei W, Wang W, Xia X and Hao Q 2014 Sensor. Actuat B-Chem. 190 516

Facile and controllable synthesis of molybdenum disulfide quantum dots for highly sensitive and selective sensing of copper ions

Facile and controllable synthesis of molybdenum disulfide quantum dots for highly sensitive and selective sensing of copper ions

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