Preparation of silver-coated glass frit and its application in silicon solar cells

doi:10.1088/1674-1056/25/7/078110

中国物理B ›› 2016, Vol. 25 ›› Issue (7): 78110-078110.doi: 10.1088/1674-1056/25/7/078110

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇下一篇

Preparation of silver-coated glass frit and its application in silicon solar cells

Feng Xiang(向锋), Biyuan Li(李碧渊), Yingfen Li(黎应芬), Jian Zhou(周健), Weiping Gan(甘卫平)

School of Material Science and Engineering, Central South University, Changsha 410083, China

收稿日期:2015-12-07 修回日期:2016-03-11 出版日期:2016-07-05 发布日期:2016-07-05
通讯作者: Biyuan Li E-mail:lylby917@163.com

Preparation of silver-coated glass frit and its application in silicon solar cells

Feng Xiang(向锋), Biyuan Li(李碧渊), Yingfen Li(黎应芬), Jian Zhou(周健), Weiping Gan(甘卫平)

School of Material Science and Engineering, Central South University, Changsha 410083, China

Received:2015-12-07 Revised:2016-03-11 Online:2016-07-05 Published:2016-07-05
Contact: Biyuan Li E-mail:lylby917@163.com

摘要/Abstract

摘要： A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone (PVP) before the electroless plating process. Infrared (IR) spectroscopy, field emission scanning electron microscopy (FESEM), and x-ray diffraction (XRD) were used to characterize the PVP modified glass frits and investigate the mechanism of the modification process. It was found that the PVP molecules adsorbed on the glass frit surface and reduced the silver ions to the silver nanoparticles. Through epitaxial growth, these nanoparticles were uniformly deposited onto the surface of the glass frit. Silicon solar cells with this novel silver coating exhibited a photoelectric conversion efficiency increase of 0.33%. Compared with the electroless plating processes, this method provides a simple route to prepare silver-coated glass frits without introducing impurity ions.

关键词: electroless plating, silver nanoparticle, glass frit, solar cell

Abstract: A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone (PVP) before the electroless plating process. Infrared (IR) spectroscopy, field emission scanning electron microscopy (FESEM), and x-ray diffraction (XRD) were used to characterize the PVP modified glass frits and investigate the mechanism of the modification process. It was found that the PVP molecules adsorbed on the glass frit surface and reduced the silver ions to the silver nanoparticles. Through epitaxial growth, these nanoparticles were uniformly deposited onto the surface of the glass frit. Silicon solar cells with this novel silver coating exhibited a photoelectric conversion efficiency increase of 0.33%. Compared with the electroless plating processes, this method provides a simple route to prepare silver-coated glass frits without introducing impurity ions.

Key words: electroless plating, silver nanoparticle, glass frit, solar cell

中图分类号: (Electrodeposition, electroplating)

81.15.Pq

78.56.-a (Photoconduction and photovoltaic effects) 73.40.Cg (Contact resistance, contact potential) 73.50.-h (Electronic transport phenomena in thin films)

向锋, 李碧渊, 黎应芬, 周健, 甘卫平. Preparation of silver-coated glass frit and its application in silicon solar cells[J]. 中国物理B, 2016, 25(7): 78110-078110.

Feng Xiang(向锋), Biyuan Li(李碧渊), Yingfen Li(黎应芬), Jian Zhou(周健), Weiping Gan(甘卫平). Preparation of silver-coated glass frit and its application in silicon solar cells[J]. Chin. Phys. B, 2016, 25(7): 78110-078110.

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Preparation of silver-coated glass frit and its application in silicon solar cells

Preparation of silver-coated glass frit and its application in silicon solar cells

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