High quality sub-monolayer, monolayer, and bilayer graphene on Ru(0001)

doi:10.1088/1674-1056/23/9/098101

中国物理B ›› 2014, Vol. 23 ›› Issue (9): 98101-098101.doi: 10.1088/1674-1056/23/9/098101

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High quality sub-monolayer, monolayer, and bilayer graphene on Ru(0001)

徐文焱^{a b}, 黄立^{a b}, 阙炎德^{a b}, 李恩^{a b}, 张海刚^{a b}, 林晓^{b a}, 王业亮^{a b}, 杜世萱^{a b}, 高鸿钧^{a b}

a Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

收稿日期:2014-04-29 修回日期:2014-05-06 出版日期:2014-09-15 发布日期:2014-09-15
基金资助:
Project supported by the National Basic Research Program of China (Grant Nos. 2013CBA01600 and 2011CB932700) and the National Natural Science Foundation of China (Grant Nos. 61222112 and 11334006).

High quality sub-monolayer, monolayer, and bilayer graphene on Ru(0001)

Xu Wen-Yan (徐文焱)^{a b}, Huang Li (黄立)^{a b}, Que Yan-De (阙炎德)^{a b}, Li En (李恩)^{a b}, Zhang Hai-Gang (张海刚)^{a b}, Lin Xiao (林晓)^{b a}, Wang Ye-Liang (王业亮)^{a b}, Du Shi-Xuan (杜世萱)^{a b}, Gao Hong-Jun (高鸿钧)^{a b}

a Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

Received:2014-04-29 Revised:2014-05-06 Online:2014-09-15 Published:2014-09-15
Contact: Lin Xiao, Wang Ye-Liang, Gao Hong-Jun E-mail:xlin@ucas.ac.cn;ylwang@iphy.ac.cn;hjgao@iphy.ac.cn
Supported by:
Project supported by the National Basic Research Program of China (Grant Nos. 2013CBA01600 and 2011CB932700) and the National Natural Science Foundation of China (Grant Nos. 61222112 and 11334006).

摘要/Abstract

摘要： High quality sub-monolayer, monolayer, and bilayer graphene were grown on Ru(0001). For the sub-monolayer graphene, the size of graphene islands with zigzag edges can be controlled by the dose of ethylene exposure. By increasing the dose of ethylene to 100 Langmuir at a high substrate temperature (800℃), high quality single-crystalline monolayer graphene was synthesized on Ru(0001). High quality bilayer graphene was formed by further increasing the dose of ethylene while reducing the cooling rate to 5℃/min. Raman spectroscopy revealed the vibrational states of graphene, G and 2D peaks appeared only in the bilayer graphene, which demonstrates that it behaves as the intrinsic graphene. Our present work affords methods to produce high quality sub-monolayer, monolayer, and bilayer graphene, both for basic research and applications.

关键词: graphene, Ru(0001), scanning tunneling microscopy

Abstract: High quality sub-monolayer, monolayer, and bilayer graphene were grown on Ru(0001). For the sub-monolayer graphene, the size of graphene islands with zigzag edges can be controlled by the dose of ethylene exposure. By increasing the dose of ethylene to 100 Langmuir at a high substrate temperature (800℃), high quality single-crystalline monolayer graphene was synthesized on Ru(0001). High quality bilayer graphene was formed by further increasing the dose of ethylene while reducing the cooling rate to 5℃/min. Raman spectroscopy revealed the vibrational states of graphene, G and 2D peaks appeared only in the bilayer graphene, which demonstrates that it behaves as the intrinsic graphene. Our present work affords methods to produce high quality sub-monolayer, monolayer, and bilayer graphene, both for basic research and applications.

Key words: graphene, Ru(0001), scanning tunneling microscopy

中图分类号: (Graphene)

81.05.ue

68.65.Pq (Graphene films) 87.64.Dz (Scanning tunneling and atomic force microscopy)

徐文焱, 黄立, 阙炎德, 李恩, 张海刚, 林晓, 王业亮, 杜世萱, 高鸿钧. High quality sub-monolayer, monolayer, and bilayer graphene on Ru(0001)[J]. 中国物理B, 2014, 23(9): 98101-098101.

Xu Wen-Yan (徐文焱), Huang Li (黄立), Que Yan-De (阙炎德), Li En (李恩), Zhang Hai-Gang (张海刚), Lin Xiao (林晓), Wang Ye-Liang (王业亮), Du Shi-Xuan (杜世萱), Gao Hong-Jun (高鸿钧). High quality sub-monolayer, monolayer, and bilayer graphene on Ru(0001)[J]. Chin. Phys. B, 2014, 23(9): 98101-098101.

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High quality sub-monolayer, monolayer, and bilayer graphene on Ru(0001)

High quality sub-monolayer, monolayer, and bilayer graphene on Ru(0001)

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