Chin. Phys. B ›› 2012, Vol. 21 ›› Issue (12): 124205-124205.doi: 10.1088/1674-1056/21/12/124205

• ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS • 上一篇    下一篇

Infrared emissivities of Mn, Co co-doped ZnO powders

姚银华, 曹全喜   

  1. School of Technical Physics, Xidian University, Xi'an 710071, China
  • 收稿日期:2012-02-25 修回日期:2012-05-31 出版日期:2012-11-01 发布日期:2012-11-01

Infrared emissivities of Mn, Co co-doped ZnO powders

Yao Yin-Hua (姚银华), Cao Quan-Xi (曹全喜)   

  1. School of Technical Physics, Xidian University, Xi'an 710071, China
  • Received:2012-02-25 Revised:2012-05-31 Online:2012-11-01 Published:2012-11-01
  • Contact: Yao Yin-Hua E-mail:yaoyinhua2009@126.com

摘要: Infrared emissivities of Zn0.99-xMn0.01CoxO (x=0.00, 0.01, 0.03, 0.05) powders synthesized at different calcination temperatures by solid-state reaction are investigated. Their phases, morphologies, UV absorption spectra, and infrared emissivities are studied by XRD, SEM, UV spectrophotometer, and IR-2 Dual-Band Infrared Emissometer in a range of 8 μm-14 μm. Doped ZnO is still of wurtzite structure, and no peaks of other phases originating from impurities are detected. The optical band-gap decreases as the Co content and calcination temperature ascend, and of which the smallest optical band-gap is 2.19 eV. The lowest infrared emissivity, 0.754, is observed in Zn0.98Mn0.01Co0.01O with the increase in Co concentration. The infrared emissivity experiences fluctuations with calcination temperature going up, and its minimum value is 0.762 at 1100℃.

关键词: co-doped ZnO, optical band-gap, infrared emissivity, solid-state reaction

Abstract: Infrared emissivities of Zn0.99-xMn0.01CoxO (x=0.00, 0.01, 0.03, 0.05) powders synthesized at different calcination temperatures by solid-state reaction are investigated. Their phases, morphologies, UV absorption spectra, and infrared emissivities are studied by XRD, SEM, UV spectrophotometer, and IR-2 Dual-Band Infrared Emissometer in a range of 8 μm-14 μm. Doped ZnO is still of wurtzite structure, and no peaks of other phases originating from impurities are detected. The optical band-gap decreases as the Co content and calcination temperature ascend, and of which the smallest optical band-gap is 2.19 eV. The lowest infrared emissivity, 0.754, is observed in Zn0.98Mn0.01Co0.01O with the increase in Co concentration. The infrared emissivity experiences fluctuations with calcination temperature going up, and its minimum value is 0.762 at 1100℃.

Key words: co-doped ZnO, optical band-gap, infrared emissivity, solid-state reaction

中图分类号:  (Optical coatings)

  • 42.79.Wc
52.25.Tx (Emission, absorption, and scattering of particles) 71.55.Gs (II-VI semiconductors)