Infrared quantum cutting conversion luminescence of Tb(0.7)Yb(3):FOV

doi:10.1088/1674-1056/20/2/027801

中国物理B ›› 2011, Vol. 20 ›› Issue (2): 27801-027801.doi: 10.1088/1674-1056/20/2/027801

Infrared quantum cutting conversion luminescence of Tb(0.7)Yb(3):FOV

康洞国¹, 陈晓波², 李崧², 周静², 温磊³, 于春雷³, 胡丽丽³

(1)Beijing Institute of Applied Physics and Computational Mathematics, Beijing 100088, China; (2)Nuclear Science & Technology College and Analytical Testing Center, Applied Optics Beijing Area Major Laboratory, Beijing Normal University, Beijing 100875, China; (3)Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China

收稿日期:2010-06-03 修回日期:2010-08-01 出版日期:2011-02-15 发布日期:2011-02-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 10674019).

Infrared quantum cutting conversion luminescence of Tb(0.7)Yb(3):FOV

Chen Xiao-Bo(陈晓波)^a)^†,Kang Dong-Guo(康洞国)^b),Li Song(李崧)^a), Wen Lei(温磊)^c),Yu Chun-Lei(于春雷)^c),Hu Li-Li(胡丽丽)^c),and Zhou Jing(周静)^a)

^a Nuclear Science & Technology College and Analytical Testing Center, Applied Optics Beijing Area Major Laboratory, Beijing Normal University, Beijing 100875, China; ^b Beijing Institute of Applied Physics and Computational Mathematics, Beijing 100088, China; ^c Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China

Received:2010-06-03 Revised:2010-08-01 Online:2011-02-15 Published:2011-02-15
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 10674019).

摘要/Abstract

摘要： The infrared quantum cutting of oxyfluoride nanophase vitroceramics Tb(0.7)Yb(3):FOV has been studied in the present paper. The actual quantum cutting efficiency formula calculated from integral fluorescence intensity is extended to the case of Tb(0.7)Yb(3):FOV. The visible and the infrared fluorescence spectra and their integral fluorescence intensities are measured from static fluorescence experiment. Lifetime curve is measured from dynamic fluorescence experiment. It is found that the total actual quantum cutting efficiency η of the excited ⁵D₄ level is about 93.7%, and that of excited (⁵D₃, ⁵G₆) levels is 93.5%. It is also found that the total theoretical quantum cutting efficiency upper limit η_x%Yb of the 485.5 nm excited <⁵D₄ level is about 121.7%, and that of 378.5 nm excited (⁵D₃, ⁵G₆) levels is 137.2%.

关键词: infrared quantum cutting, solar cell, oxyfluoride nanophase vitroceramics Tb(0.7)Yb(3):FOV

Abstract: The infrared quantum cutting of oxyfluoride nanophase vitroceramics Tb(0.7)Yb(3):FOV has been studied in the present paper. The actual quantum cutting efficiency formula calculated from integral fluorescence intensity is extended to the case of Tb(0.7)Yb(3):FOV. The visible and the infrared fluorescence spectra and their integral fluorescence intensities are measured from static fluorescence experiment. Lifetime curve is measured from dynamic fluorescence experiment. It is found that the total actual quantum cutting efficiency $\eta $ of the excited $^{5}$D$_{4}$ level is about 93.7%, and that of excited ($^{5}$D$_{3}$, $^{5}$G$_{6})$ levels is 93.5%. It is also found that the total theoretical quantum cutting efficiency upper limit $\eta _{x\%\rm Yb} $ of the 485.5 nm excited $^{5}$D$_{4}$ level is about 121.7%, and that of 378.5 nm excited ($^{5}$D$_{3}$, $^{5}$G$_{6})$ levels is 137.2%.

Key words: infrared quantum cutting, solar cell, oxyfluoride nanophase vitroceramics Tb(0.7)Yb(3):FOV

中图分类号: (Photoluminescence, properties and materials)

78.55.-m

78.30.-j (Infrared and Raman spectra)

陈晓波, 康洞国, 李崧, 温磊, 于春雷, 胡丽丽, 周静. Infrared quantum cutting conversion luminescence of Tb(0.7)Yb(3):FOV[J]. 中国物理B, 2011, 20(2): 27801-027801.

Chen Xiao-Bo(陈晓波), Kang Dong-Guo(康洞国), Li Song(李崧), Wen Lei(温磊), Yu Chun-Lei(于春雷), Hu Li-Li(胡丽丽), and Zhou Jing(周静) . Infrared quantum cutting conversion luminescence of Tb(0.7)Yb(3):FOV[J]. Chin. Phys. B, 2011, 20(2): 27801-027801.

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Infrared quantum cutting conversion luminescence of Tb(0.7)Yb(3):FOV

Infrared quantum cutting conversion luminescence of Tb(0.7)Yb(3):FOV

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