中国物理B ›› 2005, Vol. 14 ›› Issue (10): 2117-2121.doi: 10.1088/1009-1963/14/10/032

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Effect of Cu doping on the magnetic and electrical properties of n=2 Ruddlesden--Popper manganates

司继伟, 曹庆琪, 顾本喜, 都有为   

  1. National Laboratory of Solid State Microstructures and Department of Physics,Nanjing University, Nanjing 210093, China
  • 收稿日期:2005-01-12 修回日期:2005-06-21 出版日期:2005-10-20 发布日期:2005-10-20
  • 基金资助:
    Project supported by the State Key Development Program for Basic Research of China (Grant No 1999064508).

Effect of Cu doping on the magnetic and electrical properties of n=2 Ruddlesden--Popper manganates

Si Ji-Wei (司继伟), Cao Qing-Qi (曹庆琪), Gu Ben-Xi (顾本喜), Du You-Wei (都有为)   

  1. National Laboratory of Solid State Microstructures and Department of Physics,Nanjing University, Nanjing 210093, China
  • Received:2005-01-12 Revised:2005-06-21 Online:2005-10-20 Published:2005-10-20
  • Supported by:
    Project supported by the State Key Development Program for Basic Research of China (Grant No 1999064508).

摘要: A series of polycrystalline Cu-doped $n$=2 Ruddlesden--Popper manganates La$_{1.2}$Sr$_{1.8}$Cu$_{x}$Mn$_{(2-x)}$O$_{7}$ ($x$=0, 0.04, 0.13) were synthesized by the solid state reaction method. The effect of Cu doping on the magnetic and transport properties has been studied. It is found that Cu substitution for Mn greatly affects the magnetic and electrical properties of the parent phase La_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$. With the increase of Cu content, the system undergoes a transition from long-range ferromagnetic order to the spin glass state and further to an antiferromagnetic order. A little of Cu dopant can lead to the samples showing semiconductor or insulator behaviour in the whole observed temperature range while the parent phase has a metal--insulator transition.These samples show colossal magnetoresistance at low temperatures and the value of it decreases with increasing Cu content.

关键词: layered perovskite, magnetic and electrical properties, spin glass

Abstract: A series of polycrystalline Cu-doped $n$=2 Ruddlesden--Popper manganates La$_{1.2}$Sr$_{1.8}$Cu$_{x}$Mn$_{(2-x)}$O$_{7}$ ($x$=0, 0.04, 0.13) were synthesized by the solid state reaction method. The effect of Cu doping on the magnetic and transport properties has been studied. It is found that Cu substitution for Mn greatly affects the magnetic and electrical properties of the parent phase La$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$. With the increase of Cu content, the system undergoes a transition from long-range ferromagnetic order to the spin glass state and further to an antiferromagnetic order. A little of Cu dopant can lead to the samples showing semiconductor or insulator behaviour in the whole observed temperature range while the parent phase has a metal--insulator transition.These samples show colossal magnetoresistance at low temperatures and the value of it decreases with increasing Cu content.

Key words: layered perovskite, magnetic and electrical properties, spin glass

中图分类号:  (Galvanomagnetic and other magnetotransport effects)

  • 72.20.My
75.60.Ej (Magnetization curves, hysteresis, Barkhausen and related effects) 75.30.Kz (Magnetic phase boundaries (including classical and quantum magnetic transitions, metamagnetism, etc.)) 71.30.+h (Metal-insulator transitions and other electronic transitions) 75.47.Gk (Colossal magnetoresistance) 75.47.Lx (Magnetic oxides)