中国物理B ›› 1998, Vol. 7 ›› Issue (10): 764-772.doi: 10.1088/1004-423X/7/10/008

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LOW-FREQUENCY INTERNAL FRICTION STUDY FOR SrBi2Ta2O9 FERROELECTRIC CERAMICS

王志勇1, 陈廷国1, 朱为民2, 傅剑2, 宴海学2, 李承恩2   

  1. (1)Laboratory of Materials Physics, Shanghai Institute of Metallurgy, Academia Sinica, Shanghai 200050, China; (2)Shanghai Institute of Ceramics, Academia Sinica, Shanghai 200050, China
  • 收稿日期:1998-05-11 修回日期:1998-06-23 出版日期:1998-10-20 发布日期:1998-10-20

LOW-FREQUENCY INTERNAL FRICTION STUDY FOR SrBi2Ta2O9 FERROELECTRIC CERAMICS

Wang Zhi-yong (王志勇)a, Chen Ting-guo (陈廷国)a, Zhu Wei-min (朱为民)b, Fu Jian (傅剑)b, Yan Hai-xue (宴海学)b, Li Cheng-en (李承恩)b   

  1. a Laboratory of Materials Physics, Shanghai Institute of Metallurgy, Academia Sinica, Shanghai 200050, China; b Shanghai Institute of Ceramics, Academia Sinica, Shanghai 200050, China
  • Received:1998-05-11 Revised:1998-06-23 Online:1998-10-20 Published:1998-10-20

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摘要： Low-frequency internal friction (IF) of SrBi2Ta2O9(SBT) ceramics has been measured at temperatures ranging from 293 to 623 K. Two IF peaks, with their locations around 393 K (P1) and 569 K (P2) (f≈1.58 Hz), respectively, are observed. P1 is found to be associated with a relaxation process with activation energy of 0.97 eV and pre-exponential factor of 3.58×10-14 s. Peak shape analyses reveal that P1 can be well described by a broadened Debye peak with the width parameter β from 2.70 to 2.92. The mechanism responsible for P1 is proposed to be relaxation of oxygen vacancies near domain walls(DWs). P2 is considered to arise from viscous motion of DWs since it shows characteristics of static hysteresis type. Comparisons for the IF behavior between SBT and Pb(Zr, Ti)O3(PZT) suggest that in SBT oxygen vacancies are much less localized near DWs than that in PZT. This result provides a possible explanation for the weak DW pinning due to oxygen vacancies in SBT.

Abstract: Low-frequency internal friction (IF) of SrBi2Ta2O9(SBT) ceramics has been measured at temperatures ranging from 293 to 623 K. Two IF peaks, with their locations around 393 K (P1) and 569 K (P2) (f≈1.58 Hz), respectively, are observed. P1 is found to be associated with a relaxation process with activation energy of 0.97 eV and pre-exponential factor of 3.58×10-14 s. Peak shape analyses reveal that P1 can be well described by a broadened Debye peak with the width parameter $\beta$ from 2.70 to 2.92. The mechanism responsible for P1 is proposed to be relaxation of oxygen vacancies near domain walls(DWs). P2 is considered to arise from viscous motion of DWs since it shows characteristics of static hysteresis type. Comparisons for the IF behavior between SBT and Pb(Zr, Ti)O3(PZT) suggest that in SBT oxygen vacancies are much less localized near DWs than that in PZT. This result provides a possible explanation for the weak DW pinning due to oxygen vacancies in SBT.

中图分类号:  (Domain structure; hysteresis)

  • 77.80.Dj
62.40.+i (Anelasticity, internal friction, stress relaxation, and mechanical resonances) 81.40.Jj (Elasticity and anelasticity, stress-strain relations) 61.72.J- (Point defects and defect clusters)