中国物理B ›› 1995, Vol. 4 ›› Issue (12): 912-916.doi: 10.1088/1004-423X/4/12/005

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NEUTRON-POWDER-DIFFRACTION STUDY OF ErFe11.35Nb0.65 AND ErFe11.35Nb0.65Ny

胡伯平1, 王开鹰1, 王亦忠1, 孙向东2, 严启伟2, 张泮霖2   

  1. (1)San Huan Research Laboratory, Academia Sinica, Beijing 100080, China; (2)State Key Laboratory of Magnetism, Institute of Physics, Academia Sinica, Beijing 100080, China
  • 收稿日期:1995-04-12 出版日期:1995-12-20 发布日期:1995-12-20

NEUTRON-POWDER-DIFFRACTION STUDY OF ErFe11.35Nb0.65 AND ErFe11.35Nb0.65Ny

SUN XIANG-DONG (孙向东)a, Yan Qi-wei (严启伟)a, Zhang Pan-lin (张泮霖)a, Hu Bo-ping (胡伯平)b, Wang Kai-ying (王开鹰)b, Wang Yi-zhong (王亦忠)b   

  1. a State Key Laboratory of Magnetism, Institute of Physics, Academia Sinica, Beijing 100080, China; b San Huan Research Laboratory, Academia Sinica, Beijing 100080, China
  • Received:1995-04-12 Online:1995-12-20 Published:1995-12-20

摘要: ErFe11.35Nb0.65 AND ErFe11.35Nb0.65Ny have been synthesized and neutron-powder-diffraction experiments at room temperature performed. The ErFe11.35Nb0.65Ny nitride, obtained by gas-solid reaction, retains the ThMn12-type structure of its parent compound. The Nb atoms occupy 8i sites and the nitrogen atoms are located at 2b sites. The atomic magnetic moments of the Er ions are antiparallel to those of the Fe atoms. Upon nitrogenation, the lattice cell expands mainly along the a-axis and the atomic magnetic moments of Fe are enhanced.

Abstract: ErFe11.35Nb0.65 AND ErFe11.35Nb0.65Ny have been synthesized and neutron-powder-diffraction experiments at room temperature performed. The ErFe11.35Nb0.65Ny nitride, obtained by gas-solid reaction, retains the ThMn12-type structure of its parent compound. The Nb atoms occupy 8i sites and the nitrogen atoms are located at 2b sites. The atomic magnetic moments of the Er ions are antiparallel to those of the Fe atoms. Upon nitrogenation, the lattice cell expands mainly along the a-axis and the atomic magnetic moments of Fe are enhanced.

中图分类号:  (Methods of materials synthesis and materials processing)

  • 81.20.-n
61.05.fm (Neutron diffraction) 75.30.Cr (Saturation moments and magnetic susceptibilities) 61.66.Dk (Alloys )