Adsorption-modulated dynamical stability of nanobubbles at the solid-liquid interface

doi:10.1088/1674-1056/adbd29

中国物理B ›› 2025, Vol. 34 ›› Issue (6): 64702-064702.doi: 10.1088/1674-1056/adbd29

Adsorption-modulated dynamical stability of nanobubbles at the solid-liquid interface

Guiyuan Huang(黄桂源)¹, Lili Lan(蓝礼礼)¹, Binghai Wen(闻炳海)¹, Li Yang(阳丽)^1,†, and Yong Yang(杨勇)^2,1,‡

1 College of Physical Science and Technology, Guangxi Normal University, Guilin 541004, China;
2 Key Laboratory of Photovoltaic and Energy Conservation Materials, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China

收稿日期:2025-01-10 修回日期:2025-02-10 接受日期:2025-03-06 出版日期:2025-05-16 发布日期:2025-06-12
通讯作者: Li Yang, Yong Yang E-mail:yangli@mailbox.gxnu.edu.cn;yyanglab@issp.ac.cn
基金资助:
Project supported by the Natural Science Foundation of Guangxi Zhuang Autonomous Region, China (Grant No. 2022GXNSFAA035487), the National Natural Science Foundation of China (Grant Nos. 12272100, 11474285, and 12074382), the Graduate Education Innovation Project of Guangxi Zhuang Autonomous Region, China (Grant No. XJCY2022012), the Guangxi Normal University Ideological and Political Demonstration Course Construction Project (Grant Nos. 2022kcsz15 and 2023kcsz29), and the Innovation Project of Graduate Education of Guangxi Zhuang Autonomous Region, China (Grant No. YCBZ2024087).

Adsorption-modulated dynamical stability of nanobubbles at the solid-liquid interface

Guiyuan Huang(黄桂源)¹, Lili Lan(蓝礼礼)¹, Binghai Wen(闻炳海)¹, Li Yang(阳丽)^1,†, and Yong Yang(杨勇)^2,1,‡

1 College of Physical Science and Technology, Guangxi Normal University, Guilin 541004, China;
2 Key Laboratory of Photovoltaic and Energy Conservation Materials, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China

Received:2025-01-10 Revised:2025-02-10 Accepted:2025-03-06 Online:2025-05-16 Published:2025-06-12
Contact: Li Yang, Yong Yang E-mail:yangli@mailbox.gxnu.edu.cn;yyanglab@issp.ac.cn
Supported by:
Project supported by the Natural Science Foundation of Guangxi Zhuang Autonomous Region, China (Grant No. 2022GXNSFAA035487), the National Natural Science Foundation of China (Grant Nos. 12272100, 11474285, and 12074382), the Graduate Education Innovation Project of Guangxi Zhuang Autonomous Region, China (Grant No. XJCY2022012), the Guangxi Normal University Ideological and Political Demonstration Course Construction Project (Grant Nos. 2022kcsz15 and 2023kcsz29), and the Innovation Project of Graduate Education of Guangxi Zhuang Autonomous Region, China (Grant No. YCBZ2024087).

摘要/Abstract

摘要： We study the effects of gas adsorption on the dynamics and stability of nanobubbles at the solid-liquid interface. The phase diagram and dynamic evolution of surface nanobubbles were analyzed under varying equilibrium adsorption constant. Four distinct dynamic behaviors appear in the phase diagram: shrinking to dissolution, expanding to bursting, shrinking to stability, and expanding to stability. Special boundary states are identified in phase diagram, where the continuous growth of nanobubbles can take place even under very weak gas-surface interaction or with very small initial bubble size. Surface adsorption plays a critical role in the stability, lifetime, radius, and contact angle of nanobubbles, thereby demonstrating that pinning is not a prerequisite for stabilization. Furthermore, stable equilibrium nanobubbles exhibit a characteristic range of footprint radius, a limited height, and a small contact angle, consistent with experimental observations.

关键词: nanobubbles, solid-liquid interface, phase diagram, gas adsorption

Abstract: We study the effects of gas adsorption on the dynamics and stability of nanobubbles at the solid-liquid interface. The phase diagram and dynamic evolution of surface nanobubbles were analyzed under varying equilibrium adsorption constant. Four distinct dynamic behaviors appear in the phase diagram: shrinking to dissolution, expanding to bursting, shrinking to stability, and expanding to stability. Special boundary states are identified in phase diagram, where the continuous growth of nanobubbles can take place even under very weak gas-surface interaction or with very small initial bubble size. Surface adsorption plays a critical role in the stability, lifetime, radius, and contact angle of nanobubbles, thereby demonstrating that pinning is not a prerequisite for stabilization. Furthermore, stable equilibrium nanobubbles exhibit a characteristic range of footprint radius, a limited height, and a small contact angle, consistent with experimental observations.

Key words: nanobubbles, solid-liquid interface, phase diagram, gas adsorption

中图分类号: (Bubble dynamics)

47.55.dd

64.60.Ej (Studies/theory of phase transitions of specific substances) 67.80.bf (Liquid-solid interfaces; growth kinetics)

Guiyuan Huang(黄桂源), Lili Lan(蓝礼礼), Binghai Wen(闻炳海), Li Yang(阳丽), and Yong Yang(杨勇). Adsorption-modulated dynamical stability of nanobubbles at the solid-liquid interface[J]. 中国物理B, 2025, 34(6): 64702-064702.

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Adsorption-modulated dynamical stability of nanobubbles at the solid-liquid interface

Adsorption-modulated dynamical stability of nanobubbles at the solid-liquid interface

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