中国物理B ›› 2022, Vol. 31 ›› Issue (9): 93301-093301.doi: 10.1088/1674-1056/ac633a
Ben Chen(陈犇), Yi-Ni Chen(陈旖旎), Jia-Nuan Pan(潘佳煖), Jian-Ping Yin(印建平), and Hai-Ling Wang(汪海玲)†
Ben Chen(陈犇), Yi-Ni Chen(陈旖旎), Jia-Nuan Pan(潘佳煖), Jian-Ping Yin(印建平), and Hai-Ling Wang(汪海玲)†
摘要: PbF, a valuable candidate for measuring the electron electric dipole moment (eEDM), is of great significance in measuring its spectrum and deriving its molecular constants in experiment. In the present work, the rovibronic spectrum of the B$^{2}{\Sigma }^{+}$-X$_{1}^{\, 2}{\Pi }_{1/2}$ transition of PbF in a wavelength range of 260 nm-285 nm is studied by the laser ablation/laser induced fluorescence method. The molecular parameters of the X$_{1}^{\, 2}{\Pi }_{1/2}$ (${v''}=0)$ and B$^{2}{\Sigma }^{+}$ (${v}'=0, 1$) states are derived from the recorded spectra of the (0, 0) and (1, 0) bands of the B$^{2}{\Sigma }^{+}$-X$_{1}^{\, 2}{\Pi }_{1/2}$ transition. Also, the Franck-Condon factors (FCFs) of the transitions between the B$^{2}{\Sigma }^{+}$ and X$_{1}^{\, 2}{\Pi }_{1/2}$ states are calculated by the RKR/LEVEL method and the Morse potential method, respectively.
中图分类号: (Fine and hyperfine structure)