Mg-doped layered oxide cathode for Na-ion batteries

doi:10.1088/1674-1056/ac523b

中国物理B ›› 2022, Vol. 31 ›› Issue (6): 68201-068201.doi: 10.1088/1674-1056/ac523b

Mg-doped layered oxide cathode for Na-ion batteries

Yuejun Ding(丁月君)^1,2, Feixiang Ding(丁飞翔)¹, Xiaohui Rong(容晓晖)^1,†, Yaxiang Lu(陆雅翔)¹, and Yong-Sheng Hu(胡勇胜)^1,2,‡

1 Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2 Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences, Beijing 100190, China

收稿日期:2021-11-26 修回日期:2021-12-01 接受日期:2022-02-07 出版日期:2022-05-17 发布日期:2022-05-19
通讯作者: Xiaohui Rong, Yong-Sheng Hu E-mail:rong@iphy.ac.cn;yshu@iphy.ac.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 51725206, 52122214, and 52072403), the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA21070500), Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant No. 2020006), and Beijing Municipal Natural Science Foundation, China (Grant No. 2212022).

Mg-doped layered oxide cathode for Na-ion batteries

Yuejun Ding(丁月君)^1,2, Feixiang Ding(丁飞翔)¹, Xiaohui Rong(容晓晖)^1,†, Yaxiang Lu(陆雅翔)¹, and Yong-Sheng Hu(胡勇胜)^1,2,‡

1 Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2 Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences, Beijing 100190, China

Received:2021-11-26 Revised:2021-12-01 Accepted:2022-02-07 Online:2022-05-17 Published:2022-05-19
Contact: Xiaohui Rong, Yong-Sheng Hu E-mail:rong@iphy.ac.cn;yshu@iphy.ac.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 51725206, 52122214, and 52072403), the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA21070500), Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant No. 2020006), and Beijing Municipal Natural Science Foundation, China (Grant No. 2212022).

摘要/Abstract

摘要： Na-ion batteries (NIBs) are regarding as the optimum complement for Li-ion batteries along with the rapid development of stationary energy storage systems. In order to meet the commercial demands of cathodes for NIBs, O3-type Cu containing layered oxide Na_0.90Cu_0.22Fe_0.30Mn_0.48O₂ with good comprehensive performance and low-cost element components is very promising for the practical use. However, only part of the Cu³⁺/Cu²⁺ redox couple participated in the redox reaction, thus impairing the specific capacity of the cathode materials. Herein, Mg²⁺-doped O3-Na_0.90Mg_0.08Cu_0.22Fe_0.30Mn_0.40O₂ layered oxide without Mn³⁺ was synthesized successfully, which exhibited improved reversible specific capacity of 118 mAh/g in the voltage range of 2.4-4.0 V at 0.2 C, corresponding to the intercalation/deintercalation of 0.47 Na⁺ (0.1 more than that of Na_0.90Cu_0.22Fe_0.30Mn_0.48O₂). This work demonstrates an important strategy to obtain advanced layered oxide cathodes for NIBs.

关键词: copper redox, layered oxide, cathode, Na-ion batteries, energy storage

Abstract: Na-ion batteries (NIBs) are regarding as the optimum complement for Li-ion batteries along with the rapid development of stationary energy storage systems. In order to meet the commercial demands of cathodes for NIBs, O3-type Cu containing layered oxide Na_0.90Cu_0.22Fe_0.30Mn_0.48O₂ with good comprehensive performance and low-cost element components is very promising for the practical use. However, only part of the Cu³⁺/Cu²⁺ redox couple participated in the redox reaction, thus impairing the specific capacity of the cathode materials. Herein, Mg²⁺-doped O3-Na_0.90Mg_0.08Cu_0.22Fe_0.30Mn_0.40O₂ layered oxide without Mn³⁺ was synthesized successfully, which exhibited improved reversible specific capacity of 118 mAh/g in the voltage range of 2.4-4.0 V at 0.2 C, corresponding to the intercalation/deintercalation of 0.47 Na⁺ (0.1 more than that of Na_0.90Cu_0.22Fe_0.30Mn_0.48O₂). This work demonstrates an important strategy to obtain advanced layered oxide cathodes for NIBs.

Key words: copper redox, layered oxide, cathode, Na-ion batteries, energy storage

中图分类号: (Applied electrochemistry)

82.47.-a

82.45.Fk (Electrodes) 84.60.-h (Direct energy conversion and storage)

Yuejun Ding(丁月君), Feixiang Ding(丁飞翔), Xiaohui Rong(容晓晖), Yaxiang Lu(陆雅翔), and Yong-Sheng Hu(胡勇胜). Mg-doped layered oxide cathode for Na-ion batteries[J]. 中国物理B, 2022, 31(6): 68201-068201.

Yuejun Ding(丁月君), Feixiang Ding(丁飞翔), Xiaohui Rong(容晓晖), Yaxiang Lu(陆雅翔), and Yong-Sheng Hu(胡勇胜). Mg-doped layered oxide cathode for Na-ion batteries[J]. Chin. Phys. B, 2022, 31(6): 68201-068201.

参考文献

[1] Liu Q, Hu Z, Li W, Zou C, Jin H, Wang S, Chou S and Dou S X 2021 Energ. Environ. Sci. 14 158
[2] Zhou Q, Li Y, Tang F, Li K, Rong X, Lu Y, Chen L and Hu Y S 2021 Chin. Phys. Lett. 38 076501
[3] Fatima H, Zhong Y, Wu H and Shao Z 2021 Mater. Rep. Energy 1 100022
[4] Yang C, Xin S, Mai L and You Y 2020 Adv. Energy Mater. 11 2000974
[5] Zhao C, Lu Y, Chen L and Hu Y S 2019 InfoMat 2 126
[6] Li C, Geng F, Hu B and Hu B 2020 Mater. Today Energy 17 100474
[7] Guo H, Sun K, Lu Y, Wang H, Ma X, Li Z, Hu Y S and Chen D 2019 Chin. Phys. B 28 068203
[8] Palaniyandy N 2020 Curr. Opin. Electroche. 21 319
[9] Liu H, Deng W, Gao X, Chen J, Yin S, Yang L, Zou G, Hou H and Ji X 2020 Nano Sel. 1 200
[10] Ren M, Fang H, Wang C, Li H and Li F 2020 Energ. Fuel 34 13412
[11] Ding F, Meng Q, Yu P, Wang H, Niu Y, Li Y, Yang Y, Rong X, Liu X, Lu Y, Chen L and Hu Y S 2021 Adv. Funct. Mater. 31 2101475
[12] Hu Y S and Li Y 2021 ACS Energy Lett. 6 4115
[13] Xu S Y, Wu X Y, Li Y M, Hu Y S and Chen L Q 2014 Chin. Phys. B 23 118202
[14] Gao X, Chen J, Liu H, Yin S, Tian Y, Cao X, Zou G, Hou H, Wei W, Chen L and Ji X 2021 Chem. Eng. J. 406 126830
[15] Yang L, Luo S H, Wang Y, Zhan Y, Wang Q, Zhang Y, Liu X, Mu W and Teng F 2021 Chem. Eng. J. 404 126578
[16] Chen S, Han E, Xu H, Zhu L, Liu B, Zhang G and Lu M 2017 Ionics 23 3057
[17] Wang P F, Xiao Y, Piao N, Wang Q C, Ji X, Jin T, Guo Y J, Liu S, Deng T, Cui C, Chen L, Guo Y G, Yang X Q and Wang C 2020 Nano Energy 69 104474
[18] Yan Z, Tang L, Huang Y, Hua W, Wang Y, Liu R, Gu Q, Indris S, Chou S L, Huang Y, Wu M and Dou S X 2019 Angew Chem. Int. Ed. Engl. 58 1412
[19] Ramasamy H V, Kaliyappan K, Thangavel R, Aravindan V, Kang K, Kim D U, Park Y, Sun X and Lee Y S 2017 J. Mater. Chem. A 5 8408
[20] Xu S, Wu J, Hu E, Li Q, Zhang J, Wang Y, Stavitski E, Jiang L, Rong X, Yu X, Yang W, Yang X Q, Chen L and Hu Y S 2018 J. Mater. Chem. A 6 20795
[21] Fu F, Liu P and Wang H 2019 Mater. Lett. 253 124
[22] Luo R, Zhang N, Wang J, Qu W, Li L, Wu F and Chen R 2021 Electrochim. Acta 368 137614
[23] Zhang X, Qiu F, Jiang K, He P, Han M, Guo S and Zhou H 2020 Chem. Commun. 56 6293
[24] Deng J, Luo W B, Lu X, Yao Q, Wang Z, Liu H K, Zhou H and Dou S X 2018 Adv. Energy Mater. 8 1701610
[25] Xiao Y, Zhu Y F, Yao H R, Wang P F, Zhang X D, Li H, Yang X, Gu L, Li Y C, Wang T, Yin Y X, Guo X D, Zhong B H and Guo Y G 2019 Adv. Energy Mater. 9 1803978
[26] Zhao Q, Butt F K, Yang M, Guo Z, Yao X, Zapata M J M, Zhu Y, Ma X and Cao C 2021 Energy Storage Mater. 41 581
[27] Kong W, Gao R, Li Q, Yang W, Yang J, Sun L and Liu X 2019 J. Mater. Chem. A 7 9099
[28] Hu G, Liu Y, Li W, Peng Z, Wu J, Xue Z, Shi Y, Fan J, Sun Q, Cao Y and Du K 2020 Ionics 27 657
[29] Wang Y, Kim S, Lu J, Feng G and Li X 2020 Batteries Supercaps 3 376)
[30] Xu J, Chen J, Zhang K, Li N, Tao L and Wong C P 2020 Nano Energy 78 105142
[31] Dang R, Li Q, Chen M, Hu Z and Xiao X 2018 Phys. Chem. Chem. Phys. 21 314
[32] Kubota K, Fujitani N, Yoda Y, Kuroki K, Tokita Y and Komaba S 2021 J. Mater. Chem. A 9 12830
[33] Jung K N, Choi J Y, Shin H S, Huu H T, Im W B and Lee J W 2020 Solid State Sci. 106 106334
[34] Zhang C, Gao R, Zheng L, Hao Y and Liu X 2018 ACS Appl. Mater. Inter. 10 10819
[35] Zhao C, Wang Q, Yao Z, Wang J, Sánchez-Lengeling B, Ding F, Qi X, Lu Y, Bai X and Li B 2020 Science 370 708
[36] Mu L, Xu S, Li Y, Hu Y S, Li H, Chen L and Huang X 2015 Adv. Mater. 27 6928
[37] Yabuuchi N, Yoshida H and Komaba S 2012 Electrochemistry 80 716
[38] Komaba S, Yabuuchi N, Nakayama T, Ogata A, Ishikawa T and Nakai I 2012 Inorg. Chem. 51 6211
[39] Gu Z Y, Guo J Z, Zhao X X, Wang X T, Xie D, Sun Z H, Zhao C D, Liang H J, Li W H and Wu X L 2021 InfoMat 3 694
[40] Ding F, Zhao C, Zhou D, Meng Q, Xiao D, Zhang Q, Niu Y, Li Y, Rong X, Lu Y, Chen L and Hu Y S 2020 Energy Storage Mater. 30 420

Mg-doped layered oxide cathode for Na-ion batteries

Mg-doped layered oxide cathode for Na-ion batteries

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Jianxiang Gao(高健翔), Kai Sun(孙凯), Hao Guo(郭浩), Zhengyao Li(李正耀), Jianlin Wang(王建林), Xiaobai Ma(马小柏), Xuedong Bai(白雪东), and Dongfeng Chen(陈东风). Designing a P2-type cathode material with Li in both Na and transition metal layers for Na-ion batteries[J]. 中国物理B, 2022, 31(9): 98201-098201.
[2]	Xueyan Hou(侯雪妍), Xiaohui Rong(容晓晖), Yaxiang Lu(陆雅翔), and Yong-Sheng Hu(胡勇胜). Anionic redox reaction mechanism in Na-ion batteries[J]. 中国物理B, 2022, 31(9): 98801-098801.
[3]	Qiong Wu(吴琼), Lei Zhao(赵雷), Xinghao Chen(陈兴豪), and Shifeng Zhao(赵世峰)^†. Efficiently enhanced energy storage performance of Ba₂Bi₄Ti₅O₁₈ film by co-doping Fe³⁺ and Ta⁵⁺ ion with larger radius[J]. 中国物理B, 2022, 31(9): 97701-097701.
[4]	Zi-Heng Wang(王自衡), Yi-Jun Zhang(张益军), Shi-Man Li(李诗曼), Shan Li(李姗), Jing-Jing Zhan(詹晶晶), Yun-Sheng Qian(钱芸生), Feng Shi(石峰), Hong-Chang Cheng(程宏昌), Gang-Cheng Jiao(焦岗成), and Yu-Gang Zeng(曾玉刚). Temporal response of laminated graded-bandgap GaAs-based photocathode with distributed Bragg reflection structure: Model and simulation[J]. 中国物理B, 2022, 31(9): 98505-098505.
[5]	Fengling Chen(陈峰岭), Chaozhi Zeng(曾朝智), Chun Huang(黄淳), Jiannan Lin(林建楠), Yifan Chen(陈一帆), Binbin Dong(董彬彬), Chujun Yin(尹楚君), Siying Tian(田飔莹), Dapeng Sun(孙大鹏), Zhenyu Zhang(张振宇), Hong Li(李泓), and Chaobo Li(李超波). Probing the improved stability for high nickel cathode via dual-element modification in lithium-ion[J]. 中国物理B, 2022, 31(7): 78101-078101.
[6]	Fengling Chen(陈峰岭), Jiannan Lin(林建楠), Yifan Chen(陈一帆), Binbin Dong(董彬彬), Chujun Yin(尹楚君), Siying Tian(田飔莹), Dapeng Sun(孙大鹏), Jing Xie (解婧),Zhenyu Zhang(张振宇), Hong Li(李泓), and Chaobo Li(李超波). Enhancement of electrochemical performance in lithium-ion battery via tantalum oxide coated nickel-rich cathode materials[J]. 中国物理B, 2022, 31(5): 58101-058101.
[7]	Xin Wang(王鑫), Bojun Wang(汪博筠), Jiachao Yang(杨家超), Qiwen Ran(冉淇文), Jian Zou(邹剑), Pengyu Chen(陈鹏宇), Li Li(李莉), Liping Wang(王丽平), and Xiaobin Niu(牛晓滨). In situ formed FeS₂@CoS cathode for long cycling life lithium-ion battery[J]. 中国物理B, 2021, 30(8): 88201-088201.
[8]	Hao Xuan(宣浩), Yong-An Liu(刘永安), Peng-Fei Qiang(强鹏飞), Tong Su(苏桐), Xiang-Hui Yang(杨向辉), Li-Zhi Sheng(盛立志), and Bao-Sheng Zhao(赵宝升). Light-controlled pulsed x-ray tube with photocathode[J]. 中国物理B, 2021, 30(11): 118502-118502.
[9]	闫昭, 潘弘毅, 汪君洋, 陈汝颂, 罗飞, 禹习谦, 李泓. Suppressing transition metal dissolution and deposition in lithium-ion batteries using oxide solid electrolyte coated polymer separator[J]. 中国物理B, 2020, 29(8): 88201-088201.
[10]	李钰琦, 陆雅翔, 陈立泉, 胡勇胜. Failure analysis with a focus on thermal aspect towards developing safer Na-ion batteries[J]. 中国物理B, 2020, 29(4): 48201-048201.
[11]	蒋之森, 李少锋, 许正瑞, Dennis Nordlund, Hendrik Ohldag, Piero Pianetta, Jun-Sik Lee, 林锋, 刘宜晋. Revealing the inhomogeneous surface chemistry on the spherical layered oxide polycrystalline cathode particles[J]. 中国物理B, 2020, 29(2): 26103-026103.
[12]	张泽龙, 王城, 孙强, 夏维东. Fluctuation of arc plasma in arc plasma torch with multiple cathodes[J]. 中国物理B, 2019, 28(9): 95201-095201.
[13]	王怡, 刘柏男, 周格, 聂凯会, 张杰男, 禹习谦, 李泓. Improved electrochemical performance of Li(Ni_0.6Co_0.2Mn_0.2)O₂ at high charging cut-off voltage with Li_1.4Al_0.4Ti_1.6(PO₄)₃ surface coating[J]. 中国物理B, 2019, 28(6): 68202-068202.
[14]	张杰男, 李庆浩, 李泉, 禹习谦, 李泓. Improved electrochemical performances of high voltage LiCoO₂ with tungsten doping[J]. 中国物理B, 2018, 27(8): 88202-088202.
[15]	陈辉亮, 肖卓建, 张楠, 肖仕奇, 夏晓刚, 席薇, 王艳春, 周维亚, 解思深. Free-standing, curled and partially reduced graphene oxide network as sulfur host for high-performance lithium-sulfur batteries[J]. 中国物理B, 2018, 27(6): 68101-068101.