Structure, conductivity, and ion emission properties of RbAg4I5 solid electrolyte film prepared by pulsed laser deposition

doi:10.1088/1674-1056/28/6/060705

中国物理B ›› 2019, Vol. 28 ›› Issue (6): 60705-060705.doi: 10.1088/1674-1056/28/6/060705

• SPECIAL TOPIC—Recent advances in thermoelectric materials and devices • 上一篇下一篇

Structure, conductivity, and ion emission properties of RbAg₄I₅ solid electrolyte film prepared by pulsed laser deposition

Jun-Lian Chen(陈军联), Wen-Bin Zuo(左文彬), Xian-Wen Ke(柯贤文), Alexander B Tolstoguzov, Can-Xin Tian(田灿鑫), Neena Devi, Ranjana Jha, Gennady N Panin, De-Jun Fu(付德君)

1 School of Printing and Packaging, Wuhan University, Wuhan 430072, China;
2 Shenzhen Institute of Wuhan University, A302 Research Bldg., No.6 Aoxin 2nd Rd., Nanshan Hitech Zone, Shenzhen 518057, China;
3 Ryazan State Radio Engineering University, Gagarin Str. 59/1, 390005 Ryazan, Russia;
4 School of Physics and Technology, Lingnan Normal University, Zhanjiang 524048, China;
5 Department of Physics, Netaji Subhas Institute of Technology, University of Delhi, Dwarka Sector-3, New Delhi 110078, India;
6 Institute of Microelectronics Technology, Russian Academy of Sciences, Chernogolovka, Moscow 142432, Russia

收稿日期:2019-02-14 修回日期:2019-03-18 出版日期:2019-06-05 发布日期:2019-06-05
通讯作者: De-Jun Fu E-mail:djfu@whu.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 11875210), China Postdoctoral Science Foundation (Grant No. 2018M640724), the International Cooperation Program of Guangdong Provincial Science and Technology Plan Project (Grant No. 2018A050506082), and the Talent Project of Lingnan Normal University, China (Grant No. ZL1931).

Structure, conductivity, and ion emission properties of RbAg₄I₅ solid electrolyte film prepared by pulsed laser deposition

Jun-Lian Chen(陈军联)^1,2, Wen-Bin Zuo(左文彬)², Xian-Wen Ke(柯贤文)¹, Alexander B Tolstoguzov³, Can-Xin Tian(田灿鑫)⁴, Neena Devi^1,5, Ranjana Jha⁵, Gennady N Panin⁶, De-Jun Fu(付德君)²

1 School of Printing and Packaging, Wuhan University, Wuhan 430072, China;
2 Shenzhen Institute of Wuhan University, A302 Research Bldg., No.6 Aoxin 2nd Rd., Nanshan Hitech Zone, Shenzhen 518057, China;
3 Ryazan State Radio Engineering University, Gagarin Str. 59/1, 390005 Ryazan, Russia;
4 School of Physics and Technology, Lingnan Normal University, Zhanjiang 524048, China;
5 Department of Physics, Netaji Subhas Institute of Technology, University of Delhi, Dwarka Sector-3, New Delhi 110078, India;
6 Institute of Microelectronics Technology, Russian Academy of Sciences, Chernogolovka, Moscow 142432, Russia

Received:2019-02-14 Revised:2019-03-18 Online:2019-06-05 Published:2019-06-05
Contact: De-Jun Fu E-mail:djfu@whu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 11875210), China Postdoctoral Science Foundation (Grant No. 2018M640724), the International Cooperation Program of Guangdong Provincial Science and Technology Plan Project (Grant No. 2018A050506082), and the Talent Project of Lingnan Normal University, China (Grant No. ZL1931).

摘要/Abstract

摘要：

We fabricated a silver ion emitter based on the solid state electrolyte film of RbAg₄I₅ prepared by pulsed laser deposition. The RbAg₄I₅ target for PLD process was mechano-chemically synthesized by high-energy ball milling in Ar atmosphere using β-AgI and RbI as raw materials. The ion-conducting properties of RbAg₄I₅ were studied by alternating current (AC) impedance spectroscopy and the ionic conductivity at room temperature was estimated 0.21 S/m. The structure, morphology, and elemental composition of the RbAg₄I₅ film were investigated. The Ag⁺ ion-conducting property of the prepared superioni-conductor film was exploited for ion-beam generation. The temperature and accelerating voltage dependences of the ion current were studied. Few nA current was obtained at the temperature of 196 ℃ and the accelerating voltage of 10 kV.

关键词: RbAg₄I₅, ball milling, solid state electrolyte film, ion-beam source, ionic conductivity

Abstract:

Key words: RbAg₄I₅, ball milling, solid state electrolyte film, ion-beam source, ionic conductivity

中图分类号: (Charged-particle beam sources and detectors)

07.77.Ka

陈军联, 左文彬, 柯贤文, Alexander B Tolstoguzov, 田灿鑫, Neena Devi, Ranjana Jha, Gennady N Panin, 付德君. Structure, conductivity, and ion emission properties of RbAg₄I₅ solid electrolyte film prepared by pulsed laser deposition[J]. 中国物理B, 2019, 28(6): 60705-060705.

Jun-Lian Chen(陈军联), Wen-Bin Zuo(左文彬), Xian-Wen Ke(柯贤文), Alexander B Tolstoguzov, Can-Xin Tian(田灿鑫), Neena Devi, Ranjana Jha, Gennady N Panin, De-Jun Fu(付德君). Structure, conductivity, and ion emission properties of RbAg₄I₅ solid electrolyte film prepared by pulsed laser deposition[J]. Chin. Phys. B, 2019, 28(6): 60705-060705.

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Structure, conductivity, and ion emission properties of RbAg₄I₅ solid electrolyte film prepared by pulsed laser deposition

Structure, conductivity, and ion emission properties of RbAg₄I₅ solid electrolyte film prepared by pulsed laser deposition

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