Lithium-ion transport in inorganic solid state electrolyte

doi:10.1088/1674-1056/25/1/018211

中国物理B ›› 2016, Vol. 25 ›› Issue (1): 18211-018211.doi: 10.1088/1674-1056/25/1/018211

所属专题： TOPICAL REVIEW — Fundamental physics research in lithium batteries

• TOPICAL REVIEW—Fundamental physics research in lithium batteries • 上一篇下一篇

Lithium-ion transport in inorganic solid state electrolyte

Jian Gao(高健), Yu-Sheng Zhao(赵予生), Si-Qi Shi(施思齐), Hong Li(李泓)

1. Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2. Materials Genome Institute, Shanghai University, Shanghai 200444, China;
3. Department of Physics and Astronomy and High Pressure Science and Engineering Center, University of Nevada, Las Vegas, Nevada 89154, USA;
4. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China

收稿日期:2015-05-18 修回日期:2015-07-22 出版日期:2016-01-05 发布日期:2016-01-05
通讯作者: Si-Qi Shi, Hong Li E-mail:sqshi@shu.edu.cn;hli@aphy.iphy.ac.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 51372228), the Shanghai Pujiang Program, China (Grant No. 14PJ1403900), and the Shanghai Institute of Materials Genome from the Shanghai Municipal Science and Technology Commission, China (Grant No. 14DZ2261200).

Lithium-ion transport in inorganic solid state electrolyte

Jian Gao(高健)^1,2, Yu-Sheng Zhao(赵予生)³, Si-Qi Shi(施思齐)^4,2, Hong Li(李泓)¹

1. Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2. Materials Genome Institute, Shanghai University, Shanghai 200444, China;
3. Department of Physics and Astronomy and High Pressure Science and Engineering Center, University of Nevada, Las Vegas, Nevada 89154, USA;
4. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China

Received:2015-05-18 Revised:2015-07-22 Online:2016-01-05 Published:2016-01-05
Contact: Si-Qi Shi, Hong Li E-mail:sqshi@shu.edu.cn;hli@aphy.iphy.ac.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 51372228), the Shanghai Pujiang Program, China (Grant No. 14PJ1403900), and the Shanghai Institute of Materials Genome from the Shanghai Municipal Science and Technology Commission, China (Grant No. 14DZ2261200).

摘要/Abstract

摘要：

An overview of ion transport in lithium-ion inorganic solid state electrolytes is presented, aimed at exploring and designing better electrolyte materials. Ionic conductivity is one of the most important indices of the performance of inorganic solid state electrolytes. The general definition of solid state electrolytes is presented in terms of their role in a working cell (to convey ions while isolate electrons), and the history of solid electrolyte development is briefly summarized. Ways of using the available theoretical models and experimental methods to characterize lithium-ion transport in solid state electrolytes are systematically introduced. Then the various factors that affect ionic conductivity are itemized, including mainly structural disorder, composite materials and interface effects between a solid electrolyte and an electrode. Finally, strategies for future material systems, for synthesis and characterization methods, and for theory and calculation are proposed, aiming to help accelerate the design and development of new solid electrolytes.

关键词: lithium-ion batteries, solid state electrolyte, ionic conductivity, ion transport mechanism

Abstract:

Key words: lithium-ion batteries, solid state electrolyte, ionic conductivity, ion transport mechanism

中图分类号: (Lithium-ion batteries)

82.47.Aa

65.40.gk (Electrochemical properties)

高健, 赵予生, 施思齐, 李泓. Lithium-ion transport in inorganic solid state electrolyte[J]. 中国物理B, 2016, 25(1): 18211-018211.

Jian Gao(高健), Yu-Sheng Zhao(赵予生), Si-Qi Shi(施思齐), Hong Li(李泓). Lithium-ion transport in inorganic solid state electrolyte[J]. Chin. Phys. B, 2016, 25(1): 18211-018211.

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Lithium-ion transport in inorganic solid state electrolyte

Lithium-ion transport in inorganic solid state electrolyte

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