Photoelectrocatalytic oxidation of methane into methanol and formic acid over ZnO/graphene/polyaniline catalyst

doi:10.1088/1674-1056/28/4/048101

中国物理B ›› 2019, Vol. 28 ›› Issue (4): 48101-048101.doi: 10.1088/1674-1056/28/4/048101

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇下一篇

Photoelectrocatalytic oxidation of methane into methanol and formic acid over ZnO/graphene/polyaniline catalyst

Jia Liu(刘佳), Ying-Hua Zhang(张英华), Zhi-Ming Bai(白智明), Zhi-An Huang(黄志安), Yu-Kun Gao(高玉坤)

School of Civil and Resource Engineering, University of Science and Technology Beijing, Beijing 100083, China

收稿日期:2018-10-16 修回日期:2019-01-10 出版日期:2019-04-05 发布日期:2019-04-05
通讯作者: Zhi-Ming Bai E-mail:baizhiming2008@126.com
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 51602021 and 51474017) and the Fundamental Research Funds for the Central Universities (Grant No. FRF-TP-15-107A1).

Photoelectrocatalytic oxidation of methane into methanol and formic acid over ZnO/graphene/polyaniline catalyst

Jia Liu(刘佳), Ying-Hua Zhang(张英华), Zhi-Ming Bai(白智明), Zhi-An Huang(黄志安), Yu-Kun Gao(高玉坤)

School of Civil and Resource Engineering, University of Science and Technology Beijing, Beijing 100083, China

Received:2018-10-16 Revised:2019-01-10 Online:2019-04-05 Published:2019-04-05
Contact: Zhi-Ming Bai E-mail:baizhiming2008@126.com
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 51602021 and 51474017) and the Fundamental Research Funds for the Central Universities (Grant No. FRF-TP-15-107A1).

摘要/Abstract

摘要：

ZnO/graphene/polyaniline (PANI) composite is synthesized and used for photoelectrocatalytic oxidation of methane under simulated sun light illumination with ambient conditions. The photoelectrochemical (PEC) performance of pure ZnO, ZnO/graphene, ZnO/PANI, and ZnO/graphene/PANI photoanodes is investigated by cyclic voltammetry (CV), chronoamerometry (J-t) and electrochemical impedance spectroscopy (EIS). The yields of methane oxidation products, mainly methanol (CH₃OH) and formic acid (HCOOH), catalysed by the synthesized ZnO/graphene/PANI composite are 2.76 and 3.20 times those of pure ZnO, respectively. The mechanism of the photoelectrocatalytic process converting methane into methanol and formic acid is proposed on the basis of the experimental results. The enhanced photoelectrocatalytic activity of the ZnO/graphene/PANI composite can be attributed to the fact that graphene can efficiently transfer photo-generated electrons from the inner region to the surface reaction to form free radicals due to its superior electrical conductivity as an inter-media layer. Meanwhile, the introduction of PANI promotes solar energy harvesting by extending the visible light absorption and enhances charge separation efficiency due to its conducting polymer characteristics. In addition, the PANI can create a favorable π-conjunction structure together with graphene layers, which can achieve a more effective charge separation. This research demonstrates that the fabricated ZnO/graphene/PANI composite promises to implement the visible-light photoelectrocatalytic methane oxidation.

关键词: methane conversion, photoelectrocatalysis, methanol, formic acid, ZnO NWAs, polyaniline

Abstract:

Key words: methane conversion, photoelectrocatalysis, methanol, formic acid, ZnO NWAs, polyaniline

中图分类号: (II-VI semiconductors)

81.05.Dz

81.05.Fb (Organic semiconductors) 81.05.ue (Graphene) 81.07.-b (Nanoscale materials and structures: fabrication and characterization)

刘佳, 张英华, 白智明, 黄志安, 高玉坤. Photoelectrocatalytic oxidation of methane into methanol and formic acid over ZnO/graphene/polyaniline catalyst[J]. 中国物理B, 2019, 28(4): 48101-048101.

Jia Liu(刘佳), Ying-Hua Zhang(张英华), Zhi-Ming Bai(白智明), Zhi-An Huang(黄志安), Yu-Kun Gao(高玉坤). Photoelectrocatalytic oxidation of methane into methanol and formic acid over ZnO/graphene/polyaniline catalyst[J]. Chin. Phys. B, 2019, 28(4): 48101-048101.

参考文献 61

[1]	Crabtree R H 1995 Chem. Rev. 95 987 doi: 10.1021/cr00036a005
[2]	Cao M K, Gregson K and Marshall S 1998 Atmos. Environ. 32 3293 doi: 10.1016/S1352-2310(98)00105-8
[3]	Ruppel C D 2011 Nat. Educ. Knowl. 3 29
[4]	Howarth R W, Santoro R and Ingraffea A 2011 Climatic Change 106 679 doi: 10.1007/s10584-011-0061-5
[5]	Hammond C, Forde M M, Rahim A, Hasbi M, Thetford A, He Q, Jenkins R L, Dimitratos N, Lopez-Sanchez J A and Dummer N F 2012 Angew. Chem. Int. Ed. 51 5129 doi: 10.1002/anie.201108706
[6]	Zhang Q J, He D H and Zhu Q M 2008 J. Nat. Gas Chem. 17 24 doi: 10.1016/S1003-9953(08)60021-3
[7]	Alvarez-Galvan M C, Mota N, Ojeda M, Rojas S, Navarro R M and Fierro J L G 2011 Catal. Today 171 15 doi: 10.1016/j.cattod.2011.02.028
[8]	Sustersic M G, Córdova O R, Triaca W E and Arvía A J 1980 J. Electrochem. Soc. 127 1242 doi: 10.1149/1.2129863
[9]	Qiao J, Tang S N, Tian Y N, Shuang S M, Dong C and Choi M M F 2009 Sens. Actuators B: Chem. 138 402 doi: 10.1016/j.snb.2009.02.065
[10]	Jafarian M, Mahjani M G, Heli H, Gobal F and Heydarpoor M 2003 Electrochem. Commun. 5 184 doi: 10.1016/S1388-2481(03)00017-1
[11]	Joglekar M, Nguyen V, Pylypenko S, Ngo C, Li Q, O'Reilly M E, Gray T S, Hubbard W A, Gunnoe T B, Herring A M and Trewyn B G 2016 J. Am. Chem. Soc. 138 116 doi: 10.1021/jacs.5b06392
[12]	Dong F, Ou M Y, Jiang Y K, Guo S and Wu Z B 2014 Ind. & Eng. Chem. Res. 53 2318
[13]	Nischk M, Mazierski P, Gazda M and Zaleska A 2014 Appl. Catal. B: Environ. 144 674 doi: 10.1016/j.apcatb.2013.07.041
[14]	Naldoni A, Bianchi C L, Pirola C and Suslick K S 2013 Ultrason. Sonochem. 20 445 doi: 10.1016/j.ultsonch.2012.07.003
[15]	Hameed A, Ismail I M I, Aslam M and Gondal M A 2014 Appl. Catal. A: Gen. 470 327 doi: 10.1016/j.apcata.2013.10.045
[16]	Gondal M A, Hameed A and Suwaiyan A 2003 Appl. Catal. A: Gen. 243 165 doi: 10.1016/S0926-860X(02)00562-8
[17]	Gondal M A, Hameed A, Yamani Z H and Arfaj A 2004 Chem. Phys. Lett. 392 372 doi: 10.1016/j.cplett.2004.05.092
[18]	Chen X X, Li Y P, Pan X Y, Cortie D, Huang X T and Yi Z G 2016 Nat Commun. 7 12273 doi: 10.1038/ncomms12273
[19]	Hu Y, Nagai Y, Rahmawaty D, Wei C H and Anpo M 2008 Catal. Lett. 124 80 doi: 10.1007/s10562-008-9491-8
[20]	Wahl A, Ulmann M, Carroy A, Jermann B, Dolata M, Kedzierzawski P, Chatelain C, Monnier A and Augustynski J 1995 J. Electroanal. Chem. 396 41 doi: 10.1016/0022-0728(95)04023-H
[21]	Georgieva J, Valova E, Armyanov S, Philippidis N, Poulios I and Sotiropoulos S 2012 J. Hazard. Mater. 211-212 30 doi: 10.1016/j.jhazmat.2011.11.069
[22]	Fraga L E, Anderson M A, Beatriz M L P M A, Paschoal F M M, Romão L P and Zanoni M V B 2009 Electrochim. Acta 54 2069 doi: 10.1016/j.electacta.2008.08.060
[23]	Orak I, Kocyigit A and Alindal S 2017 Chin. Phys. B 26 028102 doi: 10.1088/1674-1056/26/2/028102
[24]	Yang T Y, Kong C Y, Ruan H B, Qin G P, Li W J, Liang W W, Meng X D, Zhao Y H, Fang L and Cui Y T 2012 Acta Phys. Sin. 61 168101 (in Chinese)
[25]	Jin Y P, Zhang B, Wang J Z and Shi L Q 2016 Chin. Phys. Lett. 33 058101 doi: 10.1088/0256-307X/33/5/058101
[26]	Yang X Y, Cheng J Y, Li B, Cao W Q, Yuan J, Zhang D Q and Cao M S 2012 Chin. Phys. Lett. 29 108101 doi: 10.1088/0256-307X/29/10/108101
[27]	Wang Y J, Shi R, Lin J and Zhu Y F 2011 Energy & Environ. Sci. 4 2922 doi: y
[28]	Bai X J, Wang L, Zong R L, Lv Y H, Sun Y Q and Zhu Y F 2013 Langmuir Acs J. Surf. & Colloids 29 3097 doi: uir Acs J. Surf.
[29]	Wu Y N, Wu D C, Dong C J, Zhang P P, Ji H X and He L 2011 Acta Phys. Sin. 60 77505 (in Chinese)
[30]	Zhong W W, L F M, Cai L G, Ding P, Liu X Q and Li Y 2011 Acta Phys. Sin. 60 118102 (in Chinese)
[31]	Wu Z H and Duan W Q 2012 Acta Phys. Sin. 61 137502 (in Chinese)
[32]	Chen H M, Chen C K, Chang Y C, Tsai C W, Liu R S, Hu S F, Chang W S and Chen K H 2010 Angew. Chem. 122 6102 doi: 10.1002/ange.201001827
[33]	Wang G, Yang X, Qian F, Zhang J Z and Li Y 2010 Nano Lett. 10 1088 doi: 10.1021/nl100250z
[34]	Shao M F, Ning F Y, Wei M, Evans D G and Xue D 2014 Adv. Funct. Mater. 24 580 doi: 10.1002/adfm.201301889
[35]	Singh N S, Kumar L, Kumar A, Vaisakh S, Singh S D, Sisodiya K, Srivastava S, Kansal M, Rawat S, Singh T A, Tanya and Anita 2017 Mater. Sci. Semicond. Process. 60 29 doi: 10.1016/j.mssp.2016.12.021
[36]	Bai Z M, Yan X Q, Kang Z, Hu Y P, Zhang X H and Zhang Y 2015 Nano Energy 14 392 doi: 10.1016/j.nanoen.2014.09.005
[37]	Xu T G, Zhang L W, Cheng H Y and Zhu Y F 2011 Appl. Catal. B Environ. 101 382 doi: 10.1016/j.apcatb.2010.10.007
[38]	Fu C, He D W, Wang Y S, Fu M, Geng X and Zhuo Z L 2015 Chin. Phys. B 24 87801 doi: 10.1088/1674-1056/24/8/087801
[39]	Zhang L L, Huang D, Hu N T, Yang C, Li M, Wei H, Yang Z, Su Y J and Zhang Y F 2017 J. Power Sources 342 1 doi: 10.1016/j.jpowsour.2016.11.068
[40]	Fan S N, Liu R W, Ma R S, Yu S S, Li M, Zheng W T and Hu S X 2017 Chin. Phys. B 26 048102 doi: 10.1088/1674-1056/26/4/048102
[41]	Nsib M F, Saafi S, Rayes A, Moussa N and Houas A 2016 J. Energy Inst. 89 694 doi: 10.1016/j.joei.2015.05.001
[42]	Anjum M, Oves M, Kumar R and Barakat M A 2017 Int. Biodeterioration & Biodegradation 119 66 doi: Biodeterioration
[43]	Li Z H, Feng S L, Liu S Y, Li X, Wang L and Lu W Q 2015 Nanoscale 7 19178 doi: 10.1039/C5NR06212H
[44]	Weng B, Yang M Q, Zhang N and Xu Y J 2014 J. Mater. Chem. A 2 9380 doi: 10.1039/c4ta01077a
[45]	Jing L, Yang Z Y, Zhao Y F, Zhang Y X, Guo X, Yan Y M and Sun K N 2014 J. Mater. Chem. A 2 1068 doi: 10.1039/C3TA13751A
[46]	Singh J, Bhondekar A P, Singla M L and Sharma A 2013 ACS Appl. Mater. & Interfaces 5 5346 doi: ppl. Mater.
[47]	Gasteiger H A, Markovic N, Jr P N R and Cairns E J 1994 J. Phys. Chem. 9746 326
[48]	Hahn F and Melendres C A 2001 Electrochim. Acta 46 3525 doi: 10.1016/S0013-4686(01)00649-1
[49]	Sustersic M G 1980 J. Electrochem. Soc. 127 1242 doi: 10.1149/1.2129863
[50]	Koppenol W H and Liebman J F 1984 J. Phys. Chem. 88 99 doi: 10.1021/j150645a024
[51]	Chen X X, Huang X T and Yi Z G 2014 Chemistry 20 17590 doi: 10.1002/chem.201404284
[52]	Wood P M 1988 Biochem. J. 253 287 doi: 10.1042/bj2530287
[53]	Xu C W, Cheng L Q, Shen P K and Liu Y L 2007 Electrochem. Commun. 9 997 doi: 10.1016/j.elecom.2006.12.003
[54]	Chen S, Zhu J W and Wang X 2010 J. Phys. Chem. C 114 11829 doi: 10.1021/jp1048474
[55]	Sawangphruk M and Kaewsongpol T 2012 Mater. Lett. 87 142 doi: 10.1016/j.matlet.2012.07.103
[56]	Tang Y H, Wu N, Luo S L, Liu C B, Wang K and Chen L Y 2012 Macromol. Rapid Commun. 33 1780 doi: 10.1002/marc.201200328
[57]	Seh Z W, Kibsgaard J, Dickens C F, Chorkendorff I, Norskov J K and Jaramillo T F 2017 Science 355 eaad4998
[58]	Wang Z Q, Liu Z A, Du G, Asiri A M, Wang L, Li X N, Wang H J, Sun X P, Chen L and Zhang Q J 2018 Chem. Commun. 54 7
[59]	Zhang H B, Yu L, Chen T, Zhou W and Lou X W 2018 Adv. Funct. Mater. 201807086
[60]	Yuliati L and Yoshida H 2008 Chem. Soc. Rev. 37 1592 doi: 10.1039/b710575b
[61]	Taylor C and Noceti R 2000 Catal. Today 55 259 doi: 10.1016/S0920-5861(99)00244-8

Photoelectrocatalytic oxidation of methane into methanol and formic acid over ZnO/graphene/polyaniline catalyst

Photoelectrocatalytic oxidation of methane into methanol and formic acid over ZnO/graphene/polyaniline catalyst

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