中国物理B ›› 2018, Vol. 27 ›› Issue (1): 18804-018804.doi: 10.1088/1674-1056/27/1/018804

所属专题: SPECIAL TOPIC — New generation solar cells

• SPECIAL TOPIC—Non-equilibrium phenomena in soft matters • 上一篇    下一篇

420 nm thick CH3NH3PbI3-xBrx capping layers for efficient TiO2 nanorod array perovskite solar cells

Long Li(李龙), Cheng-Wu Shi(史成武), Xin-Lian Deng(邓新莲), Yan-Qing Wang(王艳青), Guan-Nan Xiao(肖冠南), Ling-Ling Ni(倪玲玲)   

  1. School of Chemistry and Chemical Engineering, Anhui Province Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, Hefei University of Technology, Hefei 230009, China
  • 收稿日期:2017-09-23 修回日期:2017-11-16 出版日期:2018-01-05 发布日期:2018-01-05
  • 通讯作者: Cheng-Wu Shi E-mail:shicw506@foxmail.com,shicw506@hfut.edu.cn
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant Nos. 51472071 and 51272061) and Talent Project of Hefei University of Technology, China (Grant Nos. 75010-037004 and 75010-037003).

420 nm thick CH3NH3PbI3-xBrx capping layers for efficient TiO2 nanorod array perovskite solar cells

Long Li(李龙), Cheng-Wu Shi(史成武), Xin-Lian Deng(邓新莲), Yan-Qing Wang(王艳青), Guan-Nan Xiao(肖冠南), Ling-Ling Ni(倪玲玲)   

  1. School of Chemistry and Chemical Engineering, Anhui Province Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, Hefei University of Technology, Hefei 230009, China
  • Received:2017-09-23 Revised:2017-11-16 Online:2018-01-05 Published:2018-01-05
  • Contact: Cheng-Wu Shi E-mail:shicw506@foxmail.com,shicw506@hfut.edu.cn
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant Nos. 51472071 and 51272061) and Talent Project of Hefei University of Technology, China (Grant Nos. 75010-037004 and 75010-037003).

摘要: The rutile TiO2 nanorod arrays with 240 nm in length, 30 nm in diameter, and 420 μm-2 in areal density were prepared by the hydrothermal method to replace the typical 200-300 nm thick mesoporous TiO2 thin films in perovskite solar cells. The CH3NH3PbI3-xBrx capping layers with different thicknesses were obtained on the TiO2 nanorod arrays using different concentration PbI2· DMSO complex precursor solutions in DMF and the photovoltaic performances of the corresponding solar cells were compared. The perovskite solar cells based on 240 nm long TiO2 nanorod arrays and 420 nm thick CH3NH3PbI3-xBrx capping layers showed the best photoelectric conversion efficiency (PCE) of 15.56% and the average PCE of 14.93±0.63% at the relative humidity of 50%-54% under the illumination of simulated AM 1.5 sunlight (100 mW· cm-2).

关键词: rutile TiO2 nanorod array, CH3NH3PbI3-xBrx, capping layer, perovskite solar cell

Abstract: The rutile TiO2 nanorod arrays with 240 nm in length, 30 nm in diameter, and 420 μm-2 in areal density were prepared by the hydrothermal method to replace the typical 200-300 nm thick mesoporous TiO2 thin films in perovskite solar cells. The CH3NH3PbI3-xBrx capping layers with different thicknesses were obtained on the TiO2 nanorod arrays using different concentration PbI2· DMSO complex precursor solutions in DMF and the photovoltaic performances of the corresponding solar cells were compared. The perovskite solar cells based on 240 nm long TiO2 nanorod arrays and 420 nm thick CH3NH3PbI3-xBrx capping layers showed the best photoelectric conversion efficiency (PCE) of 15.56% and the average PCE of 14.93±0.63% at the relative humidity of 50%-54% under the illumination of simulated AM 1.5 sunlight (100 mW· cm-2).

Key words: rutile TiO2 nanorod array, CH3NH3PbI3-xBrx, capping layer, perovskite solar cell

中图分类号:  (Solar cells (photovoltaics))

  • 88.40.H-
88.40.hj (Efficiency and performance of solar cells) 84.60.Jt (Photoelectric conversion)