Hydrothermal synthesis and up-conversion luminescence of Ho3+/Yb3+ co-doped CaF2

doi:10.1088/1674-1056/23/6/064212

中国物理B ›› 2014, Vol. 23 ›› Issue (6): 64212-064212.doi: 10.1088/1674-1056/23/6/064212

• ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS • 上一篇下一篇

Hydrothermal synthesis and up-conversion luminescence of Ho³⁺/Yb³⁺ co-doped CaF₂

杨征^a, 郭崇峰^a, 陈叶青^b, 李琳^a, 李婷^a, 郑仲铉^b

a National Key Laboratory of Photoelectric Technology and Functional Materials (Culture Base) in Shaanxi Province, Institute of Photonics & Photon-Technology, Northwest University, Xi'an 710069, China;
b Department of Physics, Pukyong National University, Busan, 608-737, Korea

收稿日期:2013-08-17 修回日期:2013-11-01 出版日期:2014-06-15 发布日期:2014-06-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 11274251), the Natural Science Foundation of Hubei Province, China (Grant No. 2010CDB01607), the Technology Foundation for Selected Overseas Chinese Scholar, Ministry of Personnel of China (excellent), the Foundation of Shaanxi Educational Committee, China (Grant No. 11JK0528), and the Foundation of Key Laboratory of Photoelectric Technology in Shaanxi Province, China (Grant No. 12JS094).

Hydrothermal synthesis and up-conversion luminescence of Ho³⁺/Yb³⁺ co-doped CaF₂

Yang Zheng (杨征)^a, Guo Chong-Feng (郭崇峰)^a, Chen Ye-Qing (陈叶青)^b, Li Lin (李琳)^a, Li Ting (李婷)^a, Jeong Jung-Hyun (郑仲铉)^b

a National Key Laboratory of Photoelectric Technology and Functional Materials (Culture Base) in Shaanxi Province, Institute of Photonics & Photon-Technology, Northwest University, Xi'an 710069, China;
b Department of Physics, Pukyong National University, Busan, 608-737, Korea

Received:2013-08-17 Revised:2013-11-01 Online:2014-06-15 Published:2014-06-15
Contact: Guo Chong-Feng, eong Jung-Hyun E-mail:guocf@nwu.edu.cn;jhjeong@pknu.ac.kr
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 11274251), the Natural Science Foundation of Hubei Province, China (Grant No. 2010CDB01607), the Technology Foundation for Selected Overseas Chinese Scholar, Ministry of Personnel of China (excellent), the Foundation of Shaanxi Educational Committee, China (Grant No. 11JK0528), and the Foundation of Key Laboratory of Photoelectric Technology in Shaanxi Province, China (Grant No. 12JS094).

摘要/Abstract

摘要： CaF₂:Ho³⁺/Yb³⁺ nano-particles with intense green up-conversion (UC) luminescence are successfully synthesized via a facile hydrothermal approach by using NH₄F as the fluoride source and Na₂EDTA as a chelating reagent. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), and UC emission spectra are used to characterize the structures, shapes, and luminescent properties of the samples. The effects from fluoride sources and chelating reagents on the formations of CaF₂ nano-particles are investigated, and the formation process is also deduced. Under the excitation of a 980-nm laser diode, the samples each show a green up-conversion emission centered at 540 nm corresponding to the ⁵S₂/⁵F₄→⁵I₈ transitions of Ho³⁺. Moreover, the UC mechanisms of Ho³⁺/Yb³⁺ co-doped CaF₂ nano-particles are also discussed.

关键词: CaF₂, nano-particles, up-conversion, hydrothermal synthesis

Abstract: CaF₂:Ho³⁺/Yb³⁺ nano-particles with intense green up-conversion (UC) luminescence are successfully synthesized via a facile hydrothermal approach by using NH₄F as the fluoride source and Na₂EDTA as a chelating reagent. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), and UC emission spectra are used to characterize the structures, shapes, and luminescent properties of the samples. The effects from fluoride sources and chelating reagents on the formations of CaF₂ nano-particles are investigated, and the formation process is also deduced. Under the excitation of a 980-nm laser diode, the samples each show a green up-conversion emission centered at 540 nm corresponding to the ⁵S₂/⁵F₄→⁵I₈ transitions of Ho³⁺. Moreover, the UC mechanisms of Ho³⁺/Yb³⁺ co-doped CaF₂ nano-particles are also discussed.

Key words: CaF₂, nano-particles, up-conversion, hydrothermal synthesis

中图分类号: (Infrared transmitting materials)

42.70.Km

78.55.Hx (Other solid inorganic materials)

杨征, 郭崇峰, 陈叶青, 李琳, 李婷, 郑仲铉. Hydrothermal synthesis and up-conversion luminescence of Ho³⁺/Yb³⁺ co-doped CaF₂[J]. 中国物理B, 2014, 23(6): 64212-064212.

Yang Zheng (杨征), Guo Chong-Feng (郭崇峰), Chen Ye-Qing (陈叶青), Li Lin (李琳), Li Ting (李婷), Jeong Jung-Hyun (郑仲铉). Hydrothermal synthesis and up-conversion luminescence of Ho³⁺/Yb³⁺ co-doped CaF₂[J]. Chin. Phys. B, 2014, 23(6): 64212-064212.

参考文献 34

[1]	Wang M, Liu J L, Zhang Y X, Hou W, Wu X L and Xu S K 2009 Mater. Lett. 63 325
[2]	Li C R, Li S F, Dong B, Sun J C, Bo X F and Fan X N 2012 Chin. Phys. B 21 097803
[3]	Huang Y and Lieber C M 2004 Pure Appl. Chem. 76 2051
[4]	Wang L Y, Yan R X, Huo Z Y, Wang L, Zeng J H, Bao J, Wang X, Peng Q and Li Y D 2005 Angew. Chem. Int. Ed. 44 6054
[5]	Jiang T, Qin W P and Zhao D 2012 Mater. Lett. 74 54
[6]	Chen X B, Zhang F C and Chen L 2003 Chin. Phys. 12 1451
[7]	Cao T Y, Yang T S, Gao Y, Yang Y, Hu H and Li F Y 2010 Inorg. Chem. Commun. 13 392
[8]	Wang F, Banerjee D, Liu Y, Chen X and Liu X 2010 Analyst. 135 1839
[9]	Cheng L, Yang K, Zhang S, Shao M W, Lee S T and Liu Z 2010 Nano Res. 3 722
[10]	Wang Y, Qin W P, Di W H, Zhang J S and Cao C Y 2008 Chin. Phys. B 17 3300
[11]	Wang D F, Zhang X D, Liu Y J, Wu C Y, Zhang C S, Wei C C and Zhao Y 2013 Chin. Phys. B 22 027801
[12]	Menyuk N, Dwight K and Pierce J 1972 Appl. Phys. Lett. 21 159
[13]	Ma D K, Yang D P, Jiang J L, Cai P and Huang S M 2010 CrystEng- Comm. 12 1650
[14]	Jacobsohn L G, Kucera C, James T, Sprinkle K, DiMaio J R, Kokuoz B, Yazgan K B, DeVol T A and Ballato J 2010 Materials 3 2053
[15]	Jacob M V, Mazierska J, Ledenyov D and Krupka J 2003 J. Eur. Ceram. Soc. 23 2617
[16]	Wang G F, Peng Q and Li Y D 2009 J. Am. Chem. Soc. 131 14200
[17]	Lee T H and Heo J 2006 Phys. Rev. B 73 144201
[18]	Li L, Guo C F, Chen Y Q, Li T and Jeong J H 2013 Mater. Lett. 95 52
[19]	He E J, Liu N, Zhang M L, Qin Y F, Guan B G, Li Y and Guo M L 2012 Chin. Phys. B 21 073201
[20]	Shannon R 1976 Acta Crystallogr. A 32 751
[21]	Chen J X, Ye S, W X and Qiu J R 2008 Chin. Phys. Lett. 25 2078
[22]	Sun Y J, Chen Y, Tian L J, Yu Y, Kong X G, Zhao J W and Zhang H 2007 Nanotechnology 18 275609
[23]	Li W J, Shi E W and Fukuda T 2003 Cryst. Res. Technol. 38 847
[24]	Wang M, Huang Q L, Hong J M, Chen X T and Xue Z L 2006 Cryst. Growth Des. 6 1972
[25]	Wang M, Huang Q L, Hong J M, Chen X T and Xue Z L 2006 Cryst. Growth Des. 6 2169
[26]	Filankembo A, Giorgio S, Lisiecki I and Pileni M P 2003 J. Phys. Chem. B 107 7492
[27]	Moeller T, Martin D F, Thompson L C, Ferrús R, Feistel G R and Randall W J 1965 Chem. Rev. 65 1
[28]	Jiang D L, Li D, Xie J M, Zhu J J, Chen M, Lü X M and Dang S C 2010 J. Colloid Interface Sci. 350 30
[29]	Li C X, Quan Z W, Yang P P, Yang J, Lian H Z and Lin J 2008 J. Mater. Chem. 18 1353
[30]	Guo C F, Ding X, Seo H J, Ren Z Y and Bai J T 2011 J. Alloys Compd. 509 4871
[31]	Chung J H, Ryu J H, Lee S Y, Kang S H and Shim K B 2013 Ceram. Int. 39 1951
[32]	Li C R, Dong B, Li L and Lei M K 2008 Chin. Phys. B 17 224
[33]	Li X J, Nie Q H, Dai S X, Xu T F, Shen X and Zhang X H 2007 J. Phys. Chem. Solids 68 1566
[34]	Tang M M, Wang X S, Peng D F, Wang W, Sun H Q and Yao X 2012 J. Alloys Compd. 529 49

Hydrothermal synthesis and up-conversion luminescence of Ho³⁺/Yb³⁺ co-doped CaF₂

Hydrothermal synthesis and up-conversion luminescence of Ho³⁺/Yb³⁺ co-doped CaF₂

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 34

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Yuan-Hao Zhao(赵元昊), Meng-Yu Zong(宗梦雨), Jia-Hao Dong(董佳昊), Zhen Zhang(张振), Jing-Jing Liu(刘晶晶), Jie Liu(刘杰), and Liang-Bi Su(苏良碧). Mid-infrared lightly Er³⁺-doped CaF² laser under acousto-optical modulation[J]. 中国物理B, 2023, 32(3): 34203-034203.
[2]	Yuye Wang(王与烨), Gang Nie(聂港), Changhao Hu(胡常灏), Kai Chen(陈锴), Chao Yan(闫超), Bin Wu(吴斌), Junfeng Zhu(朱军峰), Degang Xu(徐德刚), and Jianquan Yao(姚建铨). High-sensitive terahertz detection by parametric up-conversion using nanosecond pulsed laser[J]. 中国物理B, 2022, 31(2): 24204-024204.
[3]	Zheng Ge(葛正), Chen Yang(杨琛), Yin-Hai Li(李银海), Yan Li(李岩), Shi-Kai Liu(刘世凯), Su-Jian Niu(牛素俭), Zhi-Yuan Zhou(周志远), and Bao-Sen Shi(史保森). Up-conversion detection of mid-infrared light carrying orbital angular momentum[J]. 中国物理B, 2022, 31(10): 104210-104210.
[4]	Jie Tian(田杰), Xiao Cao(曹笑), Wudi Wang(王无敌), Jian Liu(刘坚), Jianshu Dong(董建树), Donghua Hu(胡冬华), Qingguo Wang(王庆国), Yanyan Xue(薛艳艳), Xiaodong Xu(徐晓东), and Jun Xu(徐军). Crystal growth, spectral properties and Judd-Ofelt analysis of Pr: CaF₂-YF₃[J]. 中国物理B, 2021, 30(10): 108101-108101.
[5]	刘浩, 元晋鹏, 汪丽蓉, 肖连团, 贾锁堂. Coherent 420 nm laser beam generated by four-wave mixing in Rb vapor with a single continuous-wave laser[J]. 中国物理B, 2020, 29(4): 43203-043203.
[6]	程文静, 梁果, 吴萍, 赵世华, 贾天卿, 孙真荣, 张诗按. Up-conversion luminescence tuning in Er³⁺-doped ceramic glass by femtosecond laser pulse at different laser powers[J]. 中国物理B, 2018, 27(12): 123201-123201.
[7]	韩敬华, 罗莉, 张玉波, 胡锐峰, 冯国英. Conditions for laser-induced plasma to effectively remove nano-particles on silicon surfaces[J]. 中国物理B, 2016, 25(9): 95204-095204.
[8]	张晖, 姚云华, 张诗按, 卢晨晖, 孙真荣. Up-conversion luminescence polarization control in Er³⁺-doped NaYF₄ nanocrystals[J]. 中国物理B, 2016, 25(2): 23201-023201.
[9]	邸秋梅, 孙宇梅, 徐齐光, 韩柳, 薛兵, 孙家跃. Hydrothermal synthesis of Yb³⁺, Tm³⁺ co-doped Gd₆MoO₁₂ and its upconversion properties[J]. 中国物理B, 2015, 24(6): 67801-067801.
[10]	赵俊华, 谭瑞琴, 杨晔, 许炜, 李佳, 沈文峰, 吾国强, 朱友良, 杨旭峰, 宋伟杰. Synthesis mechanism of nanoporous Sn₃O₄ nanosheets by hydrothermal process without any additives[J]. 中国物理B, 2015, 24(6): 66202-066202.
[11]	秦玉香, 刘长雨, 柳杨. Morphology-controlled preparation of tungsten oxide nanostructures for gas-sensing application[J]. , 2015, 24(2): 27304-027304.
[12]	马辰硕, 焦清, 李龙基, 周大成, 杨正文, 宋志国, 邱建备. Up-conversion luminescence properties and energy transfer of Er³⁺/Yb³⁺ co-doped oxyfluoride glass ceramic containing CaF₂ nano-crystals[J]. 中国物理B, 2014, 23(5): 57802-057802.
[13]	胡曰博, 邱建备, 周大成, 宋志国, 杨正文, 王荣飞, 焦清, 周大利. Spectroscopic properties and mechanism of Tm³⁺/Er³⁺/Yb³⁺ co-doped oxyfluorogermanate glass ceramics containing BaF₂ nanocrystals[J]. 中国物理B, 2014, 23(2): 24205-024205.
[14]	Musarrat Jabeen, Muhammad Azhar Iqbal, R Vasant Kumar,Mansoor Ahmed, Muhammad Tayyeb Javed. Chemical synthesis of zinc oxide nanorods for enhanced hydrogen gas sensing[J]. Chin. Phys. B, 2014, 23(1): 18504-018504.
[15]	李成仁, 李淑凤, 董斌, 孙景昌, 卜晓峰, 范旭楠. Intense up-conversion emissions of Yb³⁺/Dy³⁺ co-doped Al₂O₃ nanopowders prepared by non-aqueous sol–gel method[J]. 中国物理B, 2012, 21(9): 97803-097803.