Up-conversion luminescence properties and energy transfer of Er3+/Yb3+ co-doped oxyfluoride glass ceramic containing CaF2 nano-crystals

doi:10.1088/1674-1056/23/5/057802

中国物理B ›› 2014, Vol. 23 ›› Issue (5): 57802-057802.doi: 10.1088/1674-1056/23/5/057802

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Up-conversion luminescence properties and energy transfer of Er³⁺/Yb³⁺ co-doped oxyfluoride glass ceramic containing CaF₂ nano-crystals

马辰硕^a, 焦清^a, 李龙基^a, 周大成^a, 杨正文^{a b}, 宋志国^{a b}, 邱建备^{a b}

a College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China;
b Key Laboratory of Advanced Materials of Yunnan Province, Kunming 650093, China

收稿日期:2013-08-21 修回日期:2013-11-26 出版日期:2014-05-15 发布日期:2014-05-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 61265004, 51272097, and 11204113) and the Nature and Science Fund from Yunnan Province Ministry of Education, China (Grant No. 2011C13211708).

Up-conversion luminescence properties and energy transfer of Er³⁺/Yb³⁺ co-doped oxyfluoride glass ceramic containing CaF₂ nano-crystals

Ma Chen-Shuo (马辰硕)^a, Jiao Qing (焦清)^a, Li Long-Ji (李龙基)^a, Zhou Da-Cheng (周大成)^a, Yang Zheng-Wen (杨正文)^{a b}, Song Zhi-Guo (宋志国)^{a b}, Qiu Jian-Bei (邱建备)^{a b}

a College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China;
b Key Laboratory of Advanced Materials of Yunnan Province, Kunming 650093, China

Received:2013-08-21 Revised:2013-11-26 Online:2014-05-15 Published:2014-05-15
Contact: Qiu Jian-Bei E-mail:qiu@kmust.edu.cn
About author:78.40.-q; 42.70.-a; 78.66.Jg; 78.67.Bf
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 61265004, 51272097, and 11204113) and the Nature and Science Fund from Yunnan Province Ministry of Education, China (Grant No. 2011C13211708).

摘要/Abstract

摘要： The Er³⁺/Yb³⁺ co-doped transparent oxyfluoride glass-ceramics containing CaF₂ nano-crystals were successfully prepared. After heat treatments, transmission electron microscopy (TEM) images showed that CaF₂ nano-crystals of 20-30 nm in diameter precipitated uniformly in the glass matrix. Comparing with the host glass, high efficiency upconversion luminescence of Er³⁺ at 540 nm and 658 nm was observed in the glass ceramics under the excitation of 980 nm. Moreover, the size of the precipitated nano-crystals can be controlled by heat-treatment temperature and time. With the increase of the nano-crystal size, the intensity of the red emission increased more rapidly than that of the green emission. The energy transfer process of Er³⁺ and Yb³⁺ was convinced and the possible mechanism of Er³⁺ up-conversion was discussed.

关键词: nano-crystals, up-conversion luminescence, Er³⁺/Yb³⁺ co-doped glass ceramics

Abstract: The Er³⁺/Yb³⁺ co-doped transparent oxyfluoride glass-ceramics containing CaF₂ nano-crystals were successfully prepared. After heat treatments, transmission electron microscopy (TEM) images showed that CaF₂ nano-crystals of 20-30 nm in diameter precipitated uniformly in the glass matrix. Comparing with the host glass, high efficiency upconversion luminescence of Er³⁺ at 540 nm and 658 nm was observed in the glass ceramics under the excitation of 980 nm. Moreover, the size of the precipitated nano-crystals can be controlled by heat-treatment temperature and time. With the increase of the nano-crystal size, the intensity of the red emission increased more rapidly than that of the green emission. The energy transfer process of Er³⁺ and Yb³⁺ was convinced and the possible mechanism of Er³⁺ up-conversion was discussed.

Key words: nano-crystals, up-conversion luminescence, Er³⁺/Yb³⁺ co-doped glass ceramics

中图分类号: (Absorption and reflection spectra: visible and ultraviolet)

78.40.-q

42.70.-a (Optical materials) 78.66.Jg (Amorphous semiconductors; glasses) 78.67.Bf (Nanocrystals, nanoparticles, and nanoclusters)

马辰硕, 焦清, 李龙基, 周大成, 杨正文, 宋志国, 邱建备. Up-conversion luminescence properties and energy transfer of Er³⁺/Yb³⁺ co-doped oxyfluoride glass ceramic containing CaF₂ nano-crystals[J]. 中国物理B, 2014, 23(5): 57802-057802.

Ma Chen-Shuo (马辰硕), Jiao Qing (焦清), Li Long-Ji (李龙基), Zhou Da-Cheng (周大成), Yang Zheng-Wen (杨正文), Song Zhi-Guo (宋志国), Qiu Jian-Bei (邱建备). Up-conversion luminescence properties and energy transfer of Er³⁺/Yb³⁺ co-doped oxyfluoride glass ceramic containing CaF₂ nano-crystals[J]. Chin. Phys. B, 2014, 23(5): 57802-057802.

参考文献 24

[1]	Qiao X S, Fan X P, Wang J and Wang M Q 2005 J. Non-Cryst. Solids 351 357
[2]	Xu W, Li C R, Cao B S and Dong B 2010 Chin. Phys. B 19 127804
[3]	Li C R, Xu W, Dong B, Li S F, Ding J H, Cheng Y Q and Yin H T 2010 Chin. Phys. B 19 047801
[4]	Dai S X, Yu C L, Zhou G, Wang G N and Hu L L 2006 J. Lumin. 117 39
[5]	Hu Y B, Qiu J B, Zhou D L, Song Z G and Yang Z W 201 J. Wuhan University of Technology Mater. Sci. Ed. 26 393
[6]	Auzel F, Lipinska-Kalita K E and Santa-Cruz P 1996 Opt. Mater. 5 75
[7]	Wang Y H and Ohwaki J 1993 Appl. Phys. Lett. 63 3268
[8]	Lisiecki R, Augustyn E, Ryba-Romanowski W and Zelechower M 2011 Opt. Mater. 33 1630
[9]	Wang D F, Zhang X D, Liu Y J, Wu C Y, Zhang C S, Wei C C and Zhao Y 2013 Chin. Phys. B 22 027801
[10]	Zhao S L, Xu S Q, Jia G H, Deng D G, Huang L H and Wang H P 2011 Mater. Lett. 65 2407
[11]	Ping H, Chen D Q, Yu Y L and Wang Y S 2010 J. Alloys Compd. 490 74
[12]	Ye Y X, Hu X Y, Yan Z Y, Liu E Z, Fan J, Zhang D K, Miao H, Shang Y B and Yang J 2011 Chin. Phys. B 20 087803
[13]	Lou K, Song Z G, Shang J H, Yang Z W and Qiu J B 2011 J. Non-Cryst. Solids 357 2251
[14]	Zhao S L, Xu S Q, Deng D G and Fan X P 2010 J. Rare Earth 28 903
[15]	Hu Z J, Wang Y S, Ma E, Chen D Q and Bao F 2007 Mater. Chem. Phys. 101 234
[16]	Chen D Q, Wang Y S, Ma E, Yu Y L and Liu F 2007 Opt. Mater. 29 1693
[17]	del-Castillo J, Yanes A C, Méndez-Ramos J, Tikhomirov V K and Rodríguez V D 2009 Opt. Mater. 32 104
[18]	Chen D Q, Wang Y S, Zheng K L and Guo T L 2007 Appl. Phys. Lett. 91 251903
[19]	Chen D Q, Wang Y S, Yu Y L and Huang P 2007 Appl. Phys. Lett. 91 051920
[20]	Chen D Q, Yu Y L, Huang P, Wang F Y, Lin H and Wang Y S 2009 Appl. Phys. Lett. 94 041909
[21]	Chen D Q, Yu Y L, Huang P, Lin H, Shan Z F and Wang Y S 2010 Acta Mater. 58 3035
[22]	Chen D Q, Yu Y L, Lin H, Huang P, Wang F Y, Shan Z F and Wang Y S 2009 Opt. Lett. 34 2882
[23]	Lucca A, Jacquemet M, Druon F, Balembois F, Georges P, Camy P, Doualan J L and Moncorge R 2004 Opt. Lett. 29 1879
[24]	Chen D Q, Lei L, Xu J, Yang A P and Wang Y S 2013 Nanotech. 24 085708

Up-conversion luminescence properties and energy transfer of Er³⁺/Yb³⁺ co-doped oxyfluoride glass ceramic containing CaF₂ nano-crystals

Up-conversion luminescence properties and energy transfer of Er³⁺/Yb³⁺ co-doped oxyfluoride glass ceramic containing CaF₂ nano-crystals

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