Synthesis mechanism of nanoporous Sn3O4 nanosheets by hydrothermal process without any additives

doi:10.1088/1674-1056/24/6/066202

中国物理B ›› 2015, Vol. 24 ›› Issue (6): 66202-066202.doi: 10.1088/1674-1056/24/6/066202

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

Synthesis mechanism of nanoporous Sn₃O₄ nanosheets by hydrothermal process without any additives

赵俊华^a, 谭瑞琴^b, 杨晔^c, 许炜^c, 李佳^c, 沈文峰^c, 吾国强^a, 朱友良^a, 杨旭峰^a, 宋伟杰^c

a College of Chemical and Material Engineering, Quzhou University, Quzhou 324000, China;
b Faculty of Information Science and Engineering, Ningbo University, Ningbo 315211, China;
c Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

收稿日期:2014-11-24 修回日期:2015-01-08 出版日期:2015-06-05 发布日期:2015-06-05
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 21377063, 51102250, 21203226, and 21205127) and the Personnel Training Foundation of Quzhou University (Grant No. BSYJ201412).

Synthesis mechanism of nanoporous Sn₃O₄ nanosheets by hydrothermal process without any additives

Zhao Jun-Hua (赵俊华)^a, Tan Rui-Qin (谭瑞琴)^b, Yang Ye (杨晔)^c, Xu Wei (许炜)^c, Li Jia (李佳)^c, Shen Wen-Feng (沈文峰)^c, Wu Guo-Qiang (吾国强)^a, Zhu You-Liang (朱友良)^a, Yang Xu-Feng (杨旭峰)^a, Song Wei-Jie (宋伟杰)^c

a College of Chemical and Material Engineering, Quzhou University, Quzhou 324000, China;
b Faculty of Information Science and Engineering, Ningbo University, Ningbo 315211, China;
c Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

Received:2014-11-24 Revised:2015-01-08 Online:2015-06-05 Published:2015-06-05
Contact: Zhao Jun-Hua E-mail:Zhaojh1018@163.com
About author:62.23.Kn; 61.46.Hk; 61.82.Rx
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 21377063, 51102250, 21203226, and 21205127) and the Personnel Training Foundation of Quzhou University (Grant No. BSYJ201412).

摘要/Abstract

摘要：

Nanoporous anorthic-phase Sn₃O₄ nanosheets are successfully fabricated via a hydrothermal process without any additives. With the pH value of the precursor increasing from 2.0 to 11.8, the valence of the precursor changes from mixed valence (the ratio of Sn²⁺ to Sn⁴⁺ is 2.7:1) to pure bivalent, and the product transformed from Sn₃O₄ to SnO mesocrystals. When doping SbCl₃ to the alkaline precursor, the valence of the precursor shows mixed valence with the ratio of Sn²⁺ to Sn⁴⁺ being 2.6:1 and Sn₃O₄ is synthesized after the hydrothermal process. The valence state of Sn species in the precursor is the key factor of the formation of Sn₃O₄. The synthesis mechanism is discussed and proposed. These experimental results expand the knowledge base that can be used to guide technological applications of intermediate tin oxide materials.

关键词: Sn₃O₄ nanosheets, hydrothermal synthesis, valence control, precursor

Abstract:

Key words: Sn₃O₄ nanosheets, hydrothermal synthesis, valence control, precursor

中图分类号: (Nanosheets)

62.23.Kn

61.46.Hk (Nanocrystals) 61.82.Rx (Nanocrystalline materials)

赵俊华, 谭瑞琴, 杨晔, 许炜, 李佳, 沈文峰, 吾国强, 朱友良, 杨旭峰, 宋伟杰. Synthesis mechanism of nanoporous Sn₃O₄ nanosheets by hydrothermal process without any additives[J]. 中国物理B, 2015, 24(6): 66202-066202.

Zhao Jun-Hua (赵俊华), Tan Rui-Qin (谭瑞琴), Yang Ye (杨晔), Xu Wei (许炜), Li Jia (李佳), Shen Wen-Feng (沈文峰), Wu Guo-Qiang (吾国强), Zhu You-Liang (朱友良), Yang Xu-Feng (杨旭峰), Song Wei-Jie (宋伟杰). Synthesis mechanism of nanoporous Sn₃O₄ nanosheets by hydrothermal process without any additives[J]. Chin. Phys. B, 2015, 24(6): 66202-066202.

参考文献 25

[1]	Parkinson G S, Novotny Z, Argentero G, Schmid M, Pavelec J, Kosak R, Blaha P and Diebold U 2013 Nat. Mater. 12 724
[2]	Liu F, Zhu J H, Hou Y L and Gao S 2013 Chin. Phys. B 22 107503
[3]	Cai P, Chen H M and Xie J 2014 Chin. Phys. B 23 117504
[4]	Ahn H, Park H, Joo J C and Kim D J 2013 ECS Solid State Lett. 2 11
[5]	Xue D S, Zhang L Y, Gao C X, Xu X F and Gui A B 2004 Chin. Phys. Lett. 21 733
[6]	Bou A, Torchio Ph, Barakel D, Thierry F, Sangar A, Thoulon P Y and Ricci M 2014 J. Appl. Phys. 116 023105
[7]	Luo B C, Chen C L and Xie L 2011 Acta Phys. Sin. 60 027306 (in Chinese)
[8]	Hu Y, Li J C, Shen M W and Shi X Y 2014 Chin. Phys. B 23 078704
[9]	Zeng J F, Jing L H, Hou Y, Jiao M X, Qiao R R, Jia Q J, Liu C Y, Fang F, Lei H and Gao M Y 2014 Adv. Mater. 26 2694
[10]	Lei J M, Lv L, Liu L and Xu X L 2011 Acta Phys. Sin. 60 017501 (in Chinese)
[11]	Zhao J H, Tan R Q, Shen W F, Yang Y, Guo Y Q, Li J, Zhou Z, Jian J W and Song W J 2012 Mater. Lett. 84 94
[12]	Zhu J, Lei D N, Zhang G H, Li Q H, Lu B G and Wang T H 2013 Nanoscale 5 5499
[13]	Lawson F 1967 Nature 215 955
[14]	Seko A, Togo A, Oba F and Tanaka I 2008 Phys. Rev. Lett. 100 045702
[15]	White T A, Moreno M S and Midgley P A 2010 Z. Kristallogr. 225 56
[16]	Berengue O M, Simon R A, Chiquito A J, Dalmaschio C J, Leite E R, Uerreiro G H A and Guimaraes F E G 2010 J. Appl. Phys. 107 033717
[17]	Xu W, Li M, Chen X B, Zhao J H, Tan R Q, Li R, Li J and Song W J 2014 Mater. Lett. 120 140
[18]	Zhou L, Smyth-Boyle D and O'Brien P 2008 J. Am. Chem. Soc. 130 1309
[19]	Li L and Liu C Y 2010 CrystEngComm 12 2073
[20]	Zhao J H, Tan R Q, Guo Y Q, Lu Y H, Xu W and Song W J 2012 CrystEngComm 14 4575
[21]	Verwey E J W, Haaijman P W, Romeijn F C and Van Oosterhout G W 1950 Philips Res. Rep. 5 173
[22]	Popescu D A, Herrmann J M, Ensuque A and Verduraz F B 2001 Phys. Chem. Chem. Phys. 3 2522
[23]	Habboush D A and Osteryoung R A 1984 Inorg. Chem. 23 1726
[24]	Whitney J E and Davidson N 1949 J. Am. Chem. Soc. 71 3809
[25]	Uchiyama H, Ohgi H and Imai H 2006 Cryst. Growth Des. 6 2186

Synthesis mechanism of nanoporous Sn₃O₄ nanosheets by hydrothermal process without any additives

Synthesis mechanism of nanoporous Sn₃O₄ nanosheets by hydrothermal process without any additives

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 25

相关文章 12

Metrics

本文评价

推荐阅读 0

[1]	Yu Zhan(占宇), Weijie Chen(陈炜杰), Fu Yang(杨甫), and Yaowen Li(李耀文). Stabilization of formamidinium lead iodide perovskite precursor solution for blade-coating efficient carbon electrode perovskite solar cells[J]. 中国物理B, 2021, 30(8): 88803-088803.
[2]	王红宇, 武敏, 王艺璇, 王浩, 黄晓丽, 杨新一. Phosphine-free synthesis of FeTe₂ nanoparticles and self-assembly into tree-like nanoarchitectures[J]. 中国物理B, 2019, 28(10): 106401-106401.
[3]	王勐, 周旸, 段军飞, 谌东中. Azobenzene mesogens mediated preparation of SnS nanocrystals encapsulated with in-situ N-doped carbon and their enhanced electrochemical performance for lithium ion batteries application[J]. 中国物理B, 2016, 25(9): 96102-096102.
[4]	邸秋梅, 孙宇梅, 徐齐光, 韩柳, 薛兵, 孙家跃. Hydrothermal synthesis of Yb³⁺, Tm³⁺ co-doped Gd₆MoO₁₂ and its upconversion properties[J]. 中国物理B, 2015, 24(6): 67801-067801.
[5]	王威, 沈鸿烈, 金佳乐, 李金泽, 马跃. Effect of thermal pretreatment of metal precursor on the properties of Cu₂ZnSnS₄ films[J]. 中国物理B, 2015, 24(5): 56805-056805.
[6]	秦玉香, 刘长雨, 柳杨. Morphology-controlled preparation of tungsten oxide nanostructures for gas-sensing application[J]. , 2015, 24(2): 27304-027304.
[7]	张学娜, 汪蓉, 薛奇. Theoretical insights into the formation of thiolate-protected nanoparticles from gold (III) chloride[J]. , 2014, 23(9): 98201-098201.
[8]	杨征, 郭崇峰, 陈叶青, 李琳, 李婷, 郑仲铉. Hydrothermal synthesis and up-conversion luminescence of Ho³⁺/Yb³⁺ co-doped CaF₂[J]. 中国物理B, 2014, 23(6): 64212-064212.
[9]	王洪艳, 丁发柱, 古宏伟, 张腾, 彭星煜. Precursor evolution and growth mechanism of BTO/YBCO films by TFA-MOD process[J]. 中国物理B, 2014, 23(10): 107402-107402.
[10]	Musarrat Jabeen, Muhammad Azhar Iqbal, R Vasant Kumar,Mansoor Ahmed, Muhammad Tayyeb Javed. Chemical synthesis of zinc oxide nanorods for enhanced hydrogen gas sensing[J]. Chin. Phys. B, 2014, 23(1): 18504-018504.
[11]	胡自玉, 万平玉, 侯志灵, 邵晓红. A density-functional theory investigation on disorption of O₂ on Sn(111) and its comparison with initial oxidation on the X(111) (X=Si, Ge, Sn, Pb) surfaces[J]. Chin. Phys. B, 2012, 21(12): 126803-126803.
[12]	周传仓, 刘发民, 丁芃, 蔡鲁刚, 钟文武, 张嬛. Synthesis, structure and antiferromagnetic behaviour of brannerite MnV₂O₆[J]. 中国物理B, 2010, 19(6): 67503-067503.