The phase transition, hygroscopicity, and thermal expansion properties of Yb2-xAlxMo3O12

doi:10.1088/1674-1056/21/4/046501

中国物理B ›› 2012, Vol. 21 ›› Issue (4): 46501-046501.doi: 10.1088/1674-1056/21/4/046501

李求杰,袁保合,宋文博,梁二军,袁斌

收稿日期:2011-06-05 修回日期:2011-12-24 出版日期:2012-02-29 发布日期:2012-02-29
通讯作者: 梁二军,ejliang@zzu.edu.cn E-mail:ejliang@zzu.edu.cn

The phase transition, hygroscopicity, and thermal expansion properties of Yb_2-xAl_xMo₃O₁₂

Li Qiu-Jie(李求杰), Yuan Bao-He(袁保合), Song Wen-Bo(宋文博), Liang Er-Jun(梁二军)^†, and Yuan Bin(袁斌)

School of Physical Science & Engineering and Key Laboratory of Materials Physics of Ministry of Education of China, Zhenghou University, Zhengzhou 450052, China

Received:2011-06-05 Revised:2011-12-24 Online:2012-02-29 Published:2012-02-29
Contact: Liang Er-Jun,ejliang@zzu.edu.cn E-mail:ejliang@zzu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 10974183).

摘要/Abstract

Abstract: Materials with the formula Yb_2-xAl_xMo₃O₁₂ (x=0.1, 0.2, 0.3, 0.4, 0.5, 0.7, 0.9, 1.0, 1.1, 1.3, 1.5, and 1.8) were synthesized and their structures, phase transitions, and hygroscopicity investigated using X-ray powder diffraction, Raman spectroscopy, and thermal analysis. It is shown that Yb_2-xAl_xMo₃O₁₂ solid solutions crystallize in a single monoclinic phase for 1.7≤ x≤ 2.0 and in a single orthorhombic phase for $0.1\le x\le 0.4$, and exhibit the characteristics of both monoclinic and orthorhombic structures outside these compositional ranges. The monoclinic to orthorhombic phase transition temperature of Al₂Mo₃O₁₂ can be reduced by partial substitution of Al³⁺ by Yb³⁺, and the Yb_2-xAl_xMo₃O₁₂ (0.0< x≤ 2.0) materials are hydrated at room temperature and contain two kinds of water species. One of these interacts strongly with and hinders the motions of the polyhedra, while the other does not. The partial substitution of Al³⁺ for Yb³⁺ in Yb₂Mo₃O₁₂ decreases its hygroscopicity, and the linear thermal expansion coefficients after complete removal of water species are measured to be -9.1× 10^-6/K, -5.5× 10^-6/K, 5.74× 10^-6/K, and -9.5× 10^-6/K for Yb_1.8Al_0.2(MoO₄)₃, Yb_1.6Al_0.4(MoO₄)₃, Yb_0.4Al_1.6(MoO₄)₃, and Yb_0.2Al_1.8(MoO₄)₃, respectively.

Key words: negative thermal expansion material, phase transition, hygrosopicity, Raman spectroscopy

中图分类号: (Thermal expansion; thermomechanical effects)

65.40.De

61.50.Ks (Crystallographic aspects of phase transformations; pressure effects) 82.30.Rs (Hydrogen bonding, hydrophilic effects) 78.30.-j (Infrared and Raman spectra)

李求杰, 袁保合, 宋文博, 梁二军, 袁斌. [J]. 中国物理B, 2012, 21(4): 46501-046501.

Li Qiu-Jie(李求杰), Yuan Bao-He(袁保合), Song Wen-Bo(宋文博), Liang Er-Jun(梁二军), and Yuan Bin(袁斌) . The phase transition, hygroscopicity, and thermal expansion properties of Yb_2-xAl_xMo₃O₁₂[J]. Chin. Phys. B, 2012, 21(4): 46501-046501.

参考文献 23

[1]	Barrera G D, Bruno J A O, Barron T H K and Allan N L 2005 J. Phys: Condens. Matter 17 217
[2]	Mittal R and Chaplot S L 2006 Prog. Mat. Sci. 51 211
[3]	Grima J N, Zammit V and Gatt R 2006 Xjenza. 11 17
[4]	Miller W, Smith C W, Mackenzie D S and Evans K E 2009 J. Mater. Sci. 44 5441
[5]	Liang E J 2010 Recent Patents Mater. Sci. 3 106
[6]	Evans J S O, Mary T A and Sleight A W 1998 J. Solid State Chem. 137 148
[7]	Sleight A W 1998 Ann. Rev. Mater. Sci. 28 29
[8]	Marinkovic B A, Jardim P M, de Avillez R R and Rizzo F 2005 Solid State Sci. 7 1377
[9]	Sumithra S and Umarji A M 2006 Solid State Sci. 8 1453
[10]	Evans J S O, Mary T A and Sleight A W 1997 J. Solid State Chem. 133 580
[11]	Mary T A and Sleight A W 1999 J. Mater. Res. 14 912
[12]	Liang E J, Huo H L,Wang J P and Chao M J 2008 J. Phys. Chem. C 112 6577
[13]	Sumithra S and Umarji A M 2005 Mater. Res. Bull. 40 167
[14]	Liu F S, Chen X P, Xie H X, Ao W Q and Li J Q 2010 Acta Phys. Sin. 59 3350 (in Chinese)
[15]	Sumithra S, Tyagi A K and Umarji A M 2005 Mater. Sci. Eng. B 116 14
[16]	Nassau K and Levinstein H J 1965 Phys. Chem. Solids 36 1805
[17]	Tyagi A K, Achary S N and Mathews M D 2002 J. Alloys Compd. 339 207
[18]	Sleight A W and Brixner L H 1973 J. Solid State Chem. 7 172
[19]	Evans J S O and Mary T A 2000 Int. J. Inorg. Mater. 2 143
[20]	Sumithra S and Umarji A M 2004 Solid State Sci. 6 1313
[21]	Wu M M, Xiao X L, Hu Z B, Liu Y T and Chen D F 2009 Solid State Sci. 11 325
[22]	Li Z Y, Song W B and Liang E J 2011 J. Phys. Chem. C 115 17806
[23]	Wang Z P, Song W B, Zhao Y, Jiang Y J and Liang E J 2011 The Journal of Light Scattering 23 250

The phase transition, hygroscopicity, and thermal expansion properties of Yb_2-xAl_xMo₃O₁₂

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