中国物理B ›› 2012, Vol. 21 ›› Issue (2): 23301-023301.doi: 10.1088/1674-1056/21/2/023301

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樊群超1,孙卫国1 2,李会东2,冯灏1   

  • 收稿日期:2011-07-28 修回日期:2011-09-16 出版日期:2012-01-30 发布日期:2012-01-30
  • 通讯作者: 孙卫国,weiguosun@x263.net E-mail:weiguosun@x263.net

P-branch emission spectra of the A1$\Pi$–X1Σ+ system of IrN

Fan Qun-Chao(樊群超)a), Sun Wei-Guo(孙卫国)a) b)†, Li Hui-Dong(李会东)b), and Feng Hao(冯灏)a)   

  1. a. School of Physics and Chemistry, Research Center for Advanced Computation, Xihua University, Chengdu 610039, China;
    b. Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China
  • Received:2011-07-28 Revised:2011-09-16 Online:2012-01-30 Published:2012-01-30
  • Contact: Sun Wei-Guo,weiguosun@x263.net E-mail:weiguosun@x263.net
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant No. 11074204), the Science Foundation of the Ministry of Education of China (Grant No. 20100181110085), the Research Fund of Key Disciplines of Atomic and Molecular Physics, and the Fund of Key Laboratory of Advanced Scientific Computation, Xihua University, China.

Abstract: The P-branch emission spectra of (4,1) and (3,1) bands of the A1$\Pi$-X1Σ+ system of IrN molecule are studied using an analytical formula which is derived from elementary expression of molecular total energy by taking multiple spectral differences. It not only reproduces the known experimental transition lines, but also predicts the unknown spectral lines up to J= 80 for each band by using a group of fifteen known experimental transition lines.

Key words: analytical formula, diatomic molecule, IrN, emission spectra

中图分类号:  (Rotation, vibration, and vibration-rotation constants)

  • 33.15.Mt
34.50.Ez (Rotational and vibrational energy transfer) 33.20.Sn (Rotational analysis) 33.20.Wr (Vibronic, rovibronic, and rotation-electron-spin interactions)