中国物理B ›› 2015, Vol. 24 ›› Issue (8): 83301-083301.doi: 10.1088/1674-1056/24/8/083301
• ATOMIC AND MOLECULAR PHYSICS • 上一篇 下一篇
吴玲a, 尤素萍a, 邵旭萍b, 陈钢进a, 丁宁a, 汪友梅a, 杨晓华b
Wu Ling (吴玲)a, You Su-Ping (尤素萍)a, Shao Xu-Ping (邵旭萍)b, Chen Gang-Jin (陈钢进)a, Ding Ning (丁宁)a, Wang You-Mei (汪友梅)a, Yang Xiao-Hua (杨晓华)b
摘要: Adopting the experimentally available vibrational constants in a recent analysis of the strong perturbation between the A2Π3/2u and B2Δ3/2u states of Cl2+ in the A–X band system [Gharaibeh et al. 2012 J. Chem. Phys. 137 194317], an unambiguous vibrational assignment of the bands reported previously is carried out. The equilibrium rotational constants Be and αe of the X2Π3/2g and A2Π3/2u states for 35Cl2+ and 35Cl37Cl+ and those of the B2Δ3/2u state for 35Cl2+ are obtained by fitting the experimental values of Bv. In addition, the values of Be and αe of these three states for the minor isotopologues 35Cl37Cl+ and 37Cl2+ are predicted by employing the isotopic effect. The values of equilibrium internuclear distance Re of the three states for the three isotopologues are calculated as well.
中图分类号: (Rotation, vibration, and vibration-rotation constants)