中国物理B ›› 2024, Vol. 33 ›› Issue (6): 66801-066801.doi: 10.1088/1674-1056/ad39d5

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Influences of divalent ion substitution on the magnetic and dielectric properties of W-type barium ferrite

Shiyue He(何诗悦)1,2,3, Ruoshui Liu(刘若水)3, Xujie Liu(刘煦婕)3, Xianping Ye(叶先平)3, Lichen Wang(王利晨)3,†, and Baogen Shen(沈保根)1,2,3,4,‡   

  1. 1 School of Rare Earths, University of Science and Technology of China, Hefei 230026, China;
    2 Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341119, China;
    3 Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China;
    4 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
  • 收稿日期:2024-02-17 修回日期:2024-04-03 接受日期:2024-04-03 出版日期:2024-06-18 发布日期:2024-06-18
  • 通讯作者: Lichen Wang, Baogen Shen E-mail:wanglichen@nimte.ac.cn;shenbaogen@nimte.ac.cn
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant No. 52088101), the Kunpeng Plan of Zhejiang Province, and Ningbo Top Talent Program.

Influences of divalent ion substitution on the magnetic and dielectric properties of W-type barium ferrite

Shiyue He(何诗悦)1,2,3, Ruoshui Liu(刘若水)3, Xujie Liu(刘煦婕)3, Xianping Ye(叶先平)3, Lichen Wang(王利晨)3,†, and Baogen Shen(沈保根)1,2,3,4,‡   

  1. 1 School of Rare Earths, University of Science and Technology of China, Hefei 230026, China;
    2 Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341119, China;
    3 Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China;
    4 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
  • Received:2024-02-17 Revised:2024-04-03 Accepted:2024-04-03 Online:2024-06-18 Published:2024-06-18
  • Contact: Lichen Wang, Baogen Shen E-mail:wanglichen@nimte.ac.cn;shenbaogen@nimte.ac.cn
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant No. 52088101), the Kunpeng Plan of Zhejiang Province, and Ningbo Top Talent Program.

摘要: Saturation magnetization, magneto-crystalline anisotropy field, and dielectric properties are closely related to microwave devices applied at different frequencies. For regulating the magnetic and dielectric properties of W-type barium ferrites, single-phase Ba$Me_{2}$Fe$_{16}$O$_{27}$ ($Me= {\rm Fe}$, Mn, Zn, Ni, Co) with different \textit{Me} ions were synthesized by the high-temperature solid-state method. The saturation magnetization ($M_{\rm s}$) range from 47.77emu/g to 95.34emu/g and the magnetic anisotropy field ($H_{\rm a}$) range from 10700.60Oe (1Oe=79.5775A$\cdot$m$^{-1}$) to 13739.57Oe, depending on the type of cation substitution in the hexagonal lattice. The dielectric permittivity and dielectric loss decrease with increasing frequency of the AC electric field in the low-frequency region, while they almost remain constant in the high-frequency region. The characteristics of easy regulation and preparation make it a potential candidate for use in microwave device applications.

关键词: W-type hexaferrite, Raman spectra, magnetic properties, dielectric properties

Abstract: Saturation magnetization, magneto-crystalline anisotropy field, and dielectric properties are closely related to microwave devices applied at different frequencies. For regulating the magnetic and dielectric properties of W-type barium ferrites, single-phase Ba$Me_{2}$Fe$_{16}$O$_{27}$ ($Me= {\rm Fe}$, Mn, Zn, Ni, Co) with different \textit{Me} ions were synthesized by the high-temperature solid-state method. The saturation magnetization ($M_{\rm s}$) range from 47.77emu/g to 95.34emu/g and the magnetic anisotropy field ($H_{\rm a}$) range from 10700.60Oe (1Oe=79.5775A$\cdot$m$^{-1}$) to 13739.57Oe, depending on the type of cation substitution in the hexagonal lattice. The dielectric permittivity and dielectric loss decrease with increasing frequency of the AC electric field in the low-frequency region, while they almost remain constant in the high-frequency region. The characteristics of easy regulation and preparation make it a potential candidate for use in microwave device applications.

Key words: W-type hexaferrite, Raman spectra, magnetic properties, dielectric properties

中图分类号:  (Defects and impurities: doping, implantation, distribution, concentration, etc.)

  • 68.55.Ln
75.30.Gw (Magnetic anisotropy) 75.47.Lx (Magnetic oxides) 87.64.kp (Raman)