Magnetic properties and magnetocaloric effects in (Ho1-xYx)5Pd2 compounds

doi:10.1088/1674-1056/28/5/057502

中国物理B ›› 2019, Vol. 28 ›› Issue (5): 57502-057502.doi: 10.1088/1674-1056/28/5/057502

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Magnetic properties and magnetocaloric effects in (Ho_1-xY_x)₅Pd₂ compounds

X F Wu(武小飞), C P Guo(郭翠萍), G Cheng(成钢), C R Li(李长荣), J Wang(王江), Y S Du(杜玉松), G H Rao(饶光辉), Z M Du(杜振民)

1 School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;
2 School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, China;
3 Guangxi Key Laboratory of Information Materials, Guilin 541004, China

收稿日期:2018-12-26 修回日期:2019-02-09 出版日期:2019-05-05 发布日期:2019-05-05
通讯作者: C P Guo, Y S Du E-mail:cpguo@ustb.edu.cn;duyusong@guet.edu.cn
基金资助:
Project supported by the National Basic Research Program of China (Grant No. 2014CB643703), the National Key Research and Development Program of China (Grant No. 2016YFB0700901), the National Natural Science Foundation of China (Grant Nos. 51261004 and 51761007), and Guangxi Natural Science Foundation, China (Grant No. 2018GXNSFAA294051).

Magnetic properties and magnetocaloric effects in (Ho_1-xY_x)₅Pd₂ compounds

X F Wu(武小飞)^1,2,3, C P Guo(郭翠萍)¹, G Cheng(成钢)^2,3, C R Li(李长荣)¹, J Wang(王江)^2,3, Y S Du(杜玉松)^2,3, G H Rao(饶光辉)^2,3, Z M Du(杜振民)¹

1 School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;
2 School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, China;
3 Guangxi Key Laboratory of Information Materials, Guilin 541004, China

Received:2018-12-26 Revised:2019-02-09 Online:2019-05-05 Published:2019-05-05
Contact: C P Guo, Y S Du E-mail:cpguo@ustb.edu.cn;duyusong@guet.edu.cn
Supported by:
Project supported by the National Basic Research Program of China (Grant No. 2014CB643703), the National Key Research and Development Program of China (Grant No. 2016YFB0700901), the National Natural Science Foundation of China (Grant Nos. 51261004 and 51761007), and Guangxi Natural Science Foundation, China (Grant No. 2018GXNSFAA294051).

摘要/Abstract

摘要：

The crystal structure, magnetic and magnetocaloric properties of (Ho_1-xY_x)₅Pd₂ (x=0, 0.25, and 0.5) compounds are investigated. All the compounds crystallize in a cubic Dy₅Pd₂-type structure with the space group Fd3m and undergo a second order transition from spin glass (SG) state to paramagnetic (PM) state. The spin glass transition temperatures T_g decrease from 26 K for x=0 to 13 K for x=0.5. In the PM region, the reciprocal susceptibilities for all the compounds obey the Curie-Weiss law. The paramagnetic Curie temperatures (θ_p) for Ho₅Pd₂, (Ho_0.75Y_0.25)₅Pd₂, and (Ho_0.5Y_0.5)₅Pd₂ are determined to be 32 K, 30 K, and 22 K, respectively, and the corresponding effective magnetic moments (μ_eff) are 10.8 μ_B/Ho, 10.3 μ_B/RE, and 7.5 μ_B/RE, respectively. Magnetocaloric effect (MCE) is anticipated according to the Maxwell relation, based on the isothermal magnetization curves. For a magnetic field change of 0-5 T, the maximum values of the isothermal magnetic entropy change -ΔS_M of the (Ho_1-xY_x)₅Pd₂ (x=0, 0.25, and 0.5) compounds are determined to be 11.5 J·kg^-1·K^-1, 11.1 J·kg^-1·K^-1, and 8.9 K J·kg^-1·K^-1, with corresponding refrigerant capacity values of 382.3 J·kg^-1, 336.2 J·kg^-1, and 242.5 J·kg^-1, respectively.

关键词: (Ho_1-xY_x)₅Pd₂ compounds, magnetic transition, magnetocaloric effect

Abstract:

Key words: (Ho_1-xY_x)₅Pd₂ compounds, magnetic transition, magnetocaloric effect

中图分类号: (Rare earth metals and alloys)

71.20.Eh

75.30.Kz (Magnetic phase boundaries (including classical and quantum magnetic transitions, metamagnetism, etc.)) 75.30.Sg (Magnetocaloric effect, magnetic cooling)

武小飞, 郭翠萍, 成钢, 李长荣, 王江, 杜玉松, 饶光辉, 杜振民. Magnetic properties and magnetocaloric effects in (Ho_1-xY_x)₅Pd₂ compounds[J]. 中国物理B, 2019, 28(5): 57502-057502.

X F Wu(武小飞), C P Guo(郭翠萍), G Cheng(成钢), C R Li(李长荣), J Wang(王江), Y S Du(杜玉松), G H Rao(饶光辉), Z M Du(杜振民). Magnetic properties and magnetocaloric effects in (Ho_1-xY_x)₅Pd₂ compounds[J]. Chin. Phys. B, 2019, 28(5): 57502-057502.

参考文献 60

[1]	Gschneidner Jr K A, Pecharsky V K and Tsokol A O 2005 Rep. Prog. Phys. 68 1479 doi: 10.1088/0034-4885/68/6/R04
[2]	Shen B G, Sun J R, Hu F X, Zhang H W and Cheng Z H 2009 Adv. Mater. 21 4545 doi: 10.1002/adma.200901072
[3]	Brück E 2005 J. Phys. D: Appl. Phys. 38 R381
[4]	de Oliveira N A and Von Ranke P J 2010 Phys. Rep. 489 89
[5]	Pecharsky V K and Gschneidner Jr K A 1999 J. Magn. Magn. Mater. 200 44 doi: 10.1016/S0304-8853(99)00397-2
[6]	Pecharsky V K and Gschneidner Jr K A 2001 J. Appl. Phys. 90 4614 doi: 10.1063/1.1405836
[7]	Provenzano V, Shapiro A J and Shull R D 2004 Nature 429 853 doi: 10.1038/nature02657
[8]	Shen J, Gao B, Zhang H W, Hu F X, Li Y X, Sun J R and Shen B G 2007 Appl. Phys. Lett. 91 142504 doi: 10.1063/1.2794412
[9]	Pecharsky V K and Gschneidner Jr K A 1997 Phys. Rev. Lett. 78 4494 doi: 10.1103/PhysRevLett.78.4494
[10]	Gschneidner Jr K A 2009 Acta Mater. 57 18 doi: 10.1016/j.actamat.2008.08.048
[11]	Hu F X, Shen B G, Sun J R, Cheng Z H, Rao G H and Zhang X X 2001 Appl. Phys. Lett. 78 3675 doi: 10.1063/1.1375836
[12]	Hu F X, Shen B G, Sun J R and Zhang X X 2000 Chin. Phys. 9 0550 doi: 10.1088/1009-1963/9/7/016
[13]	Zhang X X, Wen G H, Wang F W, Wang W H, Yu C H and Wu G H 2000 Appl. Phys. Lett. 77 3072 doi: 10.1063/1.1323993
[14]	Zhang X X, Wang F W and Wen G H 2001 J. Phys.: Condens. Matter 13 L747
[15]	Tegus O, Brück E, Buschow K H J and De Boer F R 2002 Nature 415 150 doi: 10.1038/415150a
[16]	Wada H and Tanabe Y 2001 Appl. Phys. Lett. 79 3302 doi: 10.1063/1.1419048
[17]	Hu F X, Shen B G, Sun J R and Wu G H 2001 Phys. Rev. B 64 132412 doi: 10.1103/PhysRevB.64.132412
[18]	Krenke T, Duman E, Acet M, Wassermann E F, Moya X, Mãnosa L and Planes A 2005 Nat. Mater. 4 450 doi: 10.1038/nmat1395
[19]	Kainuma R, Imano Y, Ito W, Sutou Y, Morito H, Okamoto S, Kitakami O, Oikawa K, Fujita A, Kanomata T and Ishida K 2006 Nature 439 957 doi: 10.1038/nature04493
[20]	Planes A, Mãnosa L and Acet M 2009 J. Phys.: Condens. Matter 21 233201 doi: 10.1088/0953-8984/21/23/233201
[21]	Liu J, Gottschall T, Skokov K P, Moore J D and Gutfleisch O 2012 Nat. Mater. 11 620 doi: 10.1038/nmat3334
[22]	Tishin A M, Spichkin Y I, in: Coey J M D, Tilley D R and Vij D R 2003 The Magnetocaloric Effect and its Applications (Bristol: Institute of Physics Publishing)
[23]	Wada H, Tanabe Y, Shiga M, Sugawara H and Sato H 2001 J. Alloys Compd. 316 245 doi: 10.1016/S0925-8388(00)01305-0
[24]	Li L W, Yi Y L, Su K P, Qi Y, Huo D X and Pöttgen R 2016 J. Mater. Sci. 51 5421 doi: 10.1007/s10853-016-9845-3
[25]	Huo J J, Du Y S, Cheng G, Wu X F, Ma L, Wang J, Xia Z C and Rao G H 2018 J. Rare Earth 36 1044 doi: 10.1016/j.jre.2018.03.016
[26]	Chen J, Shen B G, Dong Q Y and Sun J R 2010 Solid State Commun. 150 157 doi: 10.1016/j.ssc.2009.10.023
[27]	Wang L C and Shen B G 2014 Rare Met. 33 239 doi: 10.1007/s12598-014-0310-7
[28]	Chen J, Shen B G, Dong Q Y and Sun J R 2010 Solid State Commun. 150 1429 doi: 10.1016/j.ssc.2010.05.017
[29]	Singh N K, Kumar P, Mao Z, Paudyal D, Neu V, Suresh K G, Pecharsky V K and Gschneidner K A 2009 J. Phys.: Condens. Matter 21 456004 doi: 10.1088/0953-8984/21/45/456004
[30]	Mo Z J, Shen J, Gao X Q, Liu Y, Wu J F, Shen B G and Sun J R 2015 Chin. Phys. B 24 037503 doi: 10.1088/1674-1056/24/3/037503
[31]	Zheng X Q, Shen J, Hu F X, Sun J R and Shen B G 2016 Acta Phys. Sin. 65 217502 (in Chinese)
[32]	Mo Z J, Sun Q L, Wang C H, Wu H Z, Li L, Meng F B, Tang C C, Zhao Y and Shen J 2017 Ceram. Int. 43 2083 doi: 10.1016/j.ceramint.2016.10.184
[33]	Wang Y X, Zhang H, Wu M L, Tao K, Li Y W, Yan T, Long K W, Long T, Pang Z and Long Y 2016 Chin. Phys. B 25 127104 doi: 10.1088/1674-1056/25/12/127104
[34]	Zhang H, Shen B G, Xu Z Y, Shen J, Hu F X, Sun J R and Long Y 2013 Appl. Phys. Lett. 102 092401 doi: 10.1063/1.4794415
[35]	Zhang H, Sun Y J, Yang L H, Niu E, Wang H S, Hu F X, Sun J R and Shen B G 2014 J. Appl. Phys. 115 063901 doi: 10.1063/1.4865297
[36]	Wu M L, Zhang H, Xu Z Y, Wang Y X, Tao K, Zhang Y L, Yan T, Long K W, Li Y W, Shen J Y and Long Y 2017 Intermetallics 83 38 doi: 10.1016/j.intermet.2016.12.009
[37]	Wang Y X, Zhang H, Long K W, Xing C F, Xiao Y N, Su L Q, Wang L C and Long Y 2018 Intermetallics 100 175 doi: 10.1016/j.intermet.2018.06.018
[38]	Mo Z J, Hao Z H, Shen J, Li L, Wu J F, Hu F X, Sun J R and Shen B G 2015 J. Alloys Compd. 649 674 doi: 10.1016/j.jallcom.2015.07.176
[39]	Li L W, Xu C, Yuan Y and Zhou S Q 2018 Mater. Res. Lett. 6 413 doi: 10.1080/21663831.2018.1471749
[40]	Wu M L, Zhang H, Long K W, Tao K, Wang Y X, Xing C F, Xiao Y N, Wang L C and Long Y 2017 Mater. Lett. 205 40 doi: 10.1016/j.matlet.2017.06.061
[41]	Zheng X Q and Shen B G 2017 Chin. Phys. B 26 027501 doi: 10.1088/1674-1056/26/2/027501
[42]	Li Y W, Zhang H, Yan T, Long K W, Wang H S, Xue Y J, Cheng C and Zhou H B 2015 J. Alloys Compd. 651 278 doi: 10.1016/j.jallcom.2015.08.087
[43]	Mo Z J, Shen J, Gao X Q, Liu Y, Tang C C, Wu J F, Hu F X, Sun J R and Shen B G 2015 J. Alloys Compd. 626 145 doi: 10.1016/j.jallcom.2014.11.174
[44]	Li L W, Hu G H, Qi Y and Umehara I 2017 Sci. Rep. 7 42908 doi: 10.1038/srep42908
[45]	Mo Z J, Shen J, Yan L Q, Wu J F, Wang L C, Lin J, Tang C C and Shen B G 2013 Appl. Phys. Lett. 102 192407 doi: 10.1063/1.4804576
[46]	Mo Z J, Shen J, Yan L Q, Tang C C, Lin J, Wu J F, Sun J R, Wang L C, Zheng X Q and Shen B G 2013 Appl. Phys. Lett. 103 052409 doi: 10.1063/1.4816729
[47]	Berkowitz A E, Holtzberg F and Methfessel S 1964 J. Appl. Phys. 35 1030 doi: 10.1063/1.1713364
[48]	Loebich O and Raub J R E 1973 J. Less Common Met. 30 47 doi: 10.1016/0022-5088(73)90006-4
[49]	Fornasini M L and Palenzona A 1974 J. Less Common Met. 38 77 doi: 10.1016/0022-5088(74)90205-7
[50]	Yakinthos J K, Anagnostopoulos T and Ikonomou P F 1977 J. Less Common Met. 51 113 doi: 10.1016/0022-5088(77)90178-3
[51]	Klimczak M, Talik E, Winiarski A and Troć R 2006 J. Alloys Compd. 423 62 doi: 10.1016/j.jallcom.2005.12.036
[52]	Sharma M K, Yadav K and Mukherjee K 2018 J. Phys.: Condens. Matter 30 215803 doi: 10.1088/1361-648X/aabbfe
[53]	Paramanik T, Samanta T, Ranganathna R and Das I 2015 RSC Adv. 5 47860 doi: 10.1039/C5RA06970J
[54]	Gubkin A F, A Sherstobitova E, Terentyev P B, Hoser A and Baranov N V 2013 J. Phys.: Condens. Matter 25 236003 doi: 10.1088/0953-8984/25/23/236003
[55]	Samanta T, Das I and Banerjee S 2007 Appl. Phys. Lett. 91 082511 doi: 10.1063/1.2775050
[56]	Toyoizumi S, Kitazawa H, Kawamura Y, Mamiya H, Terada N, Tamura R, Dönni A, Morita K and Tamaki A 2015 J. Appl. Phys. 117 17D101
[57]	Mydosh J A 1993 Spin Glasses: an Experimental Introduction (London: Taylor and Francis)
[58]	Sh, P M, Meyer A L, Streicher M, Wilson A, Rash T, Roth M W, Kidd T E and Strauss L H 2012 Phys. Rev. B 85 144432 doi: 10.1103/PhysRevB.85.144432
[59]	McDannald A, Kuna L, Jain M 2013 J. Appl. Phys. 114 113904 doi: 10.1063/1.4821016
[60]	Banerjee B K 1964 Phys. Lett. 12 16

Magnetic properties and magnetocaloric effects in (Ho_1-xY_x)₅Pd₂ compounds

Magnetic properties and magnetocaloric effects in (Ho_1-xY_x)₅Pd₂ compounds

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 60

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Qidi Ren(任启迪), Kang Lai(赖康), Jiahao Chen(陈家浩), Xiaoxiang Yu(余晓翔), and Jiayu Dai(戴佳钰). A novel monoclinic phase and electrically tunable magnetism of van der Waals layered magnet CrTe₂[J]. 中国物理B, 2023, 32(2): 27201-027201.
[2]	Shao-Shan Xu(徐少山), Qi Fu(付琪), Yi-Fan Zhou(周益帆), Ling Peng(彭铃), Xin-Qiang Gao(高新强), Zhen-Xing Li(李振兴), Mao-Qiong Gong(公茂琼), Xue-Qiang Dong(董学强), and Jun Shen(沈俊). Magnetocaloric properties of phenolic resin bonded La(Fe,Si)₁₃-based plates and its use in a hybrid magnetic refrigerator[J]. 中国物理B, 2023, 32(2): 27502-027502.
[3]	Zhaojun Mo(莫兆军), Jianjian Gong(巩建建), Huicai Xie(谢慧财), Lei Zhang(张磊), Qi Fu(付琪), Xinqiang Gao(高新强), Zhenxing Li(李振兴), and Jun Shen(沈俊). Giant low-field cryogenic magnetocaloric effect in polycrystalline LiErF₄ compound[J]. 中国物理B, 2023, 32(2): 27503-027503.
[4]	Tina Raoufi, Jincheng He(何金城), Binbin Wang(王彬彬), Enke Liu(刘恩克), and Young Sun(孙阳). Magnetocaloric properties and Griffiths phase of ferrimagnetic cobaltite CaBaCo₄O₇[J]. 中国物理B, 2023, 32(1): 17504-017504.
[5]	Yong Li(李勇), Liang Qin(覃亮), Hongguo Zhang(张红国), and Lingwei Li(李领伟). Tailored martensitic transformation and enhanced magnetocaloric effect in all-d-metal Ni₃₅Co₁₅Mn₃₃Fe₂Ti₁₅ alloy ribbons[J]. 中国物理B, 2022, 31(8): 87103-087103.
[6]	Yan Zhang(张艳), You-Guo Shi(石友国), Li-Chen Wang(王利晨), Xin-Qi Zheng(郑新奇), Jun Liu(刘俊), Ya-Xu Jin(金亚旭), Ke-Wei Zhang(张克维), Hong-Xia Liu(刘虹霞), Shuo-Tong Zong(宗朔通), Zhi-Gang Sun(孙志刚), Ji-Fan Hu(胡季帆), Tong-Yun Tong(赵同云), and Bao-Gen Shen(沈保根). Large inverse and normal magnetocaloric effects in HoBi compound with nonhysteretic first-order phase transition[J]. 中国物理B, 2022, 31(7): 77501-077501.
[7]	Yao-Dong Wu(吴耀东), Wei-Wei Duan(段薇薇), Qiu-Yue Li(李秋月), Yong-Liang Qin(秦永亮),Zhen-Fa Zi(訾振发), and Jin Tang(汤进). Magnetic and magnetocaloric effect in a stuffed honeycomb polycrystalline antiferromagnet GdInO₃[J]. 中国物理B, 2022, 31(6): 67501-067501.
[8]	Xiyu Chen(陈西煜), Ning Ding(丁宁), Meifeng Liu(刘美风), Tao Zou(邹涛), V. Ovidiu Garlea, Jingwen Gong(龚婧雯), Fei Liu(刘飞), Yunlong Xie(谢云龙), Lun Yang(杨伦), Shuhan Zheng(郑书翰), Xiuzhang Wang(王秀章), Shuai Dong(董帅), T. Charlton, and Jun-Ming Liu(刘俊明). Incommensurate-commensurate magnetic phase transition in double tungstate Li₂Co(WO₄)₂[J]. 中国物理B, 2022, 31(4): 47501-047501.
[9]	Hao Sun(孙浩), Junfeng Wang(王俊峰), Lu Tian(田路), Jianjian Gong(巩建建), Zhaojun Mo(莫兆军), Jun Shen(沈俊), and Baogen Shen(沈保根). Magnetic properties and magnetocaloric effects of Tm_1-xEr_xCuAl (x = 0.25, 0.5, and 0.75) compounds[J]. 中国物理B, 2022, 31(12): 127501-127501.
[10]	Hao Sun(孙浩), Junfeng Wang(王俊峰), Lu Tian(田路), Jianjian Gong(巩建建), Zhaojun Mo(莫兆军), Jun Shen(沈俊), and Baogen Shen(沈保根). Magnetic properties and magnetocaloric effect in RE₅₅Co₃₀Al₁₀Si₅ (RE = Er and Tm) amorphous ribbons[J]. 中国物理B, 2022, 31(11): 117503-117503.
[11]	Lu-Ling Li(李炉领), Xiao-Yu Yue(岳小宇), Wen-Jing Zhang(张文静), Hu Bao(鲍虎), Dan-Dan Wu(吴丹丹), Hui Liang(梁慧), Yi-Yan Wang(王义炎), Yan Sun(孙燕), Qiu-Ju Li(李秋菊), and Xue-Feng Sun(孙学峰). Magnetism and giant magnetocaloric effect in rare-earth-based compounds R₃BWO₉ (R = Gd, Dy, Ho)[J]. 中国物理B, 2021, 30(7): 77501-077501.
[12]	丁燕红, 孟凡振, 王利晨, 刘若水, 沈俊. Metamagnetic transition and reversible magnetocaloric effect in antiferromagnetic DyNiGa compound[J]. 中国物理B, 2020, 29(7): 77501-077501.
[13]	唐本镇, 刘晓萍, 李冬梅, 余鹏, 夏雷. Effect of Ni substitution on the formability and magnetic properties of Gd₅₀Co₅₀ amorphous alloy[J]. 中国物理B, 2020, 29(5): 56401-056401.
[14]	刘鹏飞, 彭杰, 薛面起, 王铂森. Magnetocaloric effect and critical behavior of the Mn-rich itinerant material Mn₃GaC with enhanced ferromagnetic interaction[J]. 中国物理B, 2020, 29(4): 47503-047503.
[15]	郝嘉政, 胡凤霞, 尉紫冰, 沈斐然, 周厚博, 高怡红, 乔凯明, 李佳, 张丞, 梁文会, 王晶, 何峻, 孙继荣, 沈保根. Multicaloric and coupled-caloric effects[J]. 中国物理B, 2020, 29(4): 47504-047504.