Magnetocaloric properties of phenolic resin bonded La(Fe,Si)13-based plates and its use in a hybrid magnetic refrigerator

doi:10.1088/1674-1056/ac9fbf

中国物理B ›› 2023, Vol. 32 ›› Issue (2): 27502-027502.doi: 10.1088/1674-1056/ac9fbf

Magnetocaloric properties of phenolic resin bonded La(Fe,Si)₁₃-based plates and its use in a hybrid magnetic refrigerator

Shao-Shan Xu(徐少山)^1,2, Qi Fu(付琪)³, Yi-Fan Zhou(周益帆)³, Ling Peng(彭铃)³, Xin-Qiang Gao(高新强)^1,3,†, Zhen-Xing Li(李振兴)¹, Mao-Qiong Gong(公茂琼)¹, Xue-Qiang Dong(董学强)^1,2, and Jun Shen(沈俊)^1,2,‡

1 Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
2 University of Chinese Academy of Sciences, Beijing 100049, China;
3 Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341119, China

收稿日期:2022-09-27 修回日期:2022-10-31 接受日期:2022-11-03 出版日期:2023-01-10 发布日期:2023-02-07
通讯作者: Xin-Qiang Gao, Jun Shen E-mail:xqgao@gia.cas.cn;jshen@mail.ipc.ac.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 52171054 and 52171195) and the National Natural Science Foundation for Distinguished Young Scholars (Grant No. 51925605).

Magnetocaloric properties of phenolic resin bonded La(Fe,Si)₁₃-based plates and its use in a hybrid magnetic refrigerator

1 Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
2 University of Chinese Academy of Sciences, Beijing 100049, China;
3 Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341119, China

Received:2022-09-27 Revised:2022-10-31 Accepted:2022-11-03 Online:2023-01-10 Published:2023-02-07
Contact: Xin-Qiang Gao, Jun Shen E-mail:xqgao@gia.cas.cn;jshen@mail.ipc.ac.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 52171054 and 52171195) and the National Natural Science Foundation for Distinguished Young Scholars (Grant No. 51925605).

摘要/Abstract

摘要： We present a simple hot press-based method for processing La(Fe,Si)$_{13}$-based compounds consisting of La-Fe-Co-Si-C particles and phenolic resin. The magnetic entropy change $\Delta S$ per unit mass for the LaFe$_{10.87}$Co$_{0.63}$Si$_{1.5}$C$_{0.2}$/phenolic resin compounds have nearly the same magnitude with the base materials. With the content of phenolic resin of 5.0 wt%, the compound conductivity is 3.13 W$\cdot$m$^{-1}\cdot$K$^{-1}$. In order to measure the cooling performance of La(Fe,Si)$_{13}$-based compounds, the La(Fe$_{11.6-x}$Co$_{x}$)Si$_{1.4}$C$_{0.15}$ ($x=$0.60, 0.65, 0.75, 0.80, 0.85)/phenolic resin compounds were pressed into thin plates and tested in a hybrid refrigerator that combines the active magnetic refrigeration effect with the Stirling cycle refrigeration effect. The test results showed that a maximum cooling power of 41 W was achieved over a temperature span of 30 K.

关键词: magnetocaloric effect, La(Fe,Si)₁₃, phenolic resin, magnetic refrigeration, hybrid refrigerator

Abstract: We present a simple hot press-based method for processing La(Fe,Si)$_{13}$-based compounds consisting of La-Fe-Co-Si-C particles and phenolic resin. The magnetic entropy change $\Delta S$ per unit mass for the LaFe$_{10.87}$Co$_{0.63}$Si$_{1.5}$C$_{0.2}$/phenolic resin compounds have nearly the same magnitude with the base materials. With the content of phenolic resin of 5.0 wt%, the compound conductivity is 3.13 W$\cdot$m$^{-1}\cdot$K$^{-1}$. In order to measure the cooling performance of La(Fe,Si)$_{13}$-based compounds, the La(Fe$_{11.6-x}$Co$_{x}$)Si$_{1.4}$C$_{0.15}$ ($x=$0.60, 0.65, 0.75, 0.80, 0.85)/phenolic resin compounds were pressed into thin plates and tested in a hybrid refrigerator that combines the active magnetic refrigeration effect with the Stirling cycle refrigeration effect. The test results showed that a maximum cooling power of 41 W was achieved over a temperature span of 30 K.

Key words: magnetocaloric effect, La(Fe,Si)₁₃, phenolic resin, magnetic refrigeration, hybrid refrigerator

中图分类号: (Magnetocaloric effect, magnetic cooling)

75.30.Sg

65.40.gd (Entropy) 75.20.En (Metals and alloys)

Shao-Shan Xu(徐少山), Qi Fu(付琪), Yi-Fan Zhou(周益帆), Ling Peng(彭铃), Xin-Qiang Gao(高新强), Zhen-Xing Li(李振兴), Mao-Qiong Gong(公茂琼), Xue-Qiang Dong(董学强), and Jun Shen(沈俊). Magnetocaloric properties of phenolic resin bonded La(Fe,Si)₁₃-based plates and its use in a hybrid magnetic refrigerator[J]. 中国物理B, 2023, 32(2): 27502-027502.

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Magnetocaloric properties of phenolic resin bonded La(Fe,Si)₁₃-based plates and its use in a hybrid magnetic refrigerator

Magnetocaloric properties of phenolic resin bonded La(Fe,Si)₁₃-based plates and its use in a hybrid magnetic refrigerator

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