Charge compensation and capacity fading in LiCoO2 at high voltage investigated by soft x-ray absorption spectroscopy

doi:10.1088/1674-1056/27/10/107802

中国物理B ›› 2018, Vol. 27 ›› Issue (10): 107802-107802.doi: 10.1088/1674-1056/27/10/107802

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Charge compensation and capacity fading in LiCoO₂ at high voltage investigated by soft x-ray absorption spectroscopy

1 State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China;
2 Center for Excellence in Superconducting Electronics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China;
3 University of Chinese Academy of Sciences, Beijing 100049, China;
4 Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA;
5 School of Physical Science and Technology, Shanghai Tech University, Shanghai 200031, China;
6 NingDe Amperex Technology Limited, Ningde 352100, China;
7 "National" Synchrotron Radiation Research Centre, Hsinchu 30076, Taiwan, China

收稿日期:2018-05-17 修回日期:2018-07-03 出版日期:2018-10-05 发布日期:2018-10-05
通讯作者: Peng-Fei Yu E-mail:ypfaq@mail.sim.ac.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 21503263, U1632269, 21473235, and 11227902).

Charge compensation and capacity fading in LiCoO₂ at high voltage investigated by soft x-ray absorption spectroscopy

Xing-Hui Long(龙兴辉)^1,2,3, Yan-Ru Wu(吴颜如)^1,2,3, Nian Zhang(张念)^1,2, Peng-Fei Yu(于鹏飞)^1,2, Xue-Fei Feng(冯雪飞)⁴, Shun Zheng(郑顺)^1,2,3, Jia-Min Fu(傅佳敏)^1,2,5, Xiao-Song Liu(刘啸嵩)^1,2,5, Na Liu(柳娜)⁶, Meng Wang(王梦)⁶, Lei-Min Xu(徐磊敏)⁶, Jin-Ming Chen(陈锦明)⁷, Jenn-Min Lee(李振民)⁷

1 State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China;
2 Center for Excellence in Superconducting Electronics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China;
3 University of Chinese Academy of Sciences, Beijing 100049, China;
4 Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA;
5 School of Physical Science and Technology, Shanghai Tech University, Shanghai 200031, China;
6 NingDe Amperex Technology Limited, Ningde 352100, China;
7 "National" Synchrotron Radiation Research Centre, Hsinchu 30076, Taiwan, China

Received:2018-05-17 Revised:2018-07-03 Online:2018-10-05 Published:2018-10-05
Contact: Peng-Fei Yu E-mail:ypfaq@mail.sim.ac.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 21503263, U1632269, 21473235, and 11227902).

摘要/Abstract

摘要：

In order to obtain an in-depth insight into the mechanism of charge compensation and capacity fading in LiCoO₂, the evolution of electronic structure of LiCoO₂ at different cutoff voltages and after different cycles are studied by soft x-ray absorption spectroscopy in total electron (TEY) and fluorescence (TFY) detection modes, which provide surface and bulk information, respectively. The spectra of Co L_2,3-edge indicate that Co contributes to charge compensation below 4.4 V. Combining with the spectra of O K-edge, it manifests that only O contributes to electron compensation above 4.4 V with the formation of local O 2p holes both on the surface and in the bulk, where the surficial O evolves more remarkably. The evolution of the O 2p holes gives an explanation to the origin of O₂^- or even O₂. A comparison between the TEY and TFY of O K-edge spectra of LiCoO₂ cycled in a range from 3 V to 4.6 V indicates both the structural change in the bulk and aggregation of lithium salts on the electrode surface are responsible for the capacity fading. However, the latter is found to play a more important role after many cycles.

关键词: soft x-ray absorption, LiCoO₂, charge compensation, capacity degradation

Abstract:

Key words: soft x-ray absorption, LiCoO₂, charge compensation, capacity degradation

中图分类号: (X-ray absorption spectra)

78.70.Dm

82.47.Aa (Lithium-ion batteries) 82.30.-b (Specific chemical reactions; reaction mechanisms)

龙兴辉, 吴颜如, 张念, 于鹏飞, 冯雪飞, 郑顺, 傅佳敏, 刘啸嵩, 柳娜, 王梦, 徐磊敏, 陈锦明, 李振民. Charge compensation and capacity fading in LiCoO₂ at high voltage investigated by soft x-ray absorption spectroscopy[J]. 中国物理B, 2018, 27(10): 107802-107802.

Xing-Hui Long(龙兴辉), Yan-Ru Wu(吴颜如), Nian Zhang(张念), Peng-Fei Yu(于鹏飞), Xue-Fei Feng(冯雪飞), Shun Zheng(郑顺), Jia-Min Fu(傅佳敏), Xiao-Song Liu(刘啸嵩), Na Liu(柳娜), Meng Wang(王梦), Lei-Min Xu(徐磊敏), Jin-Ming Chen(陈锦明), Jenn-Min Lee(李振民). Charge compensation and capacity fading in LiCoO₂ at high voltage investigated by soft x-ray absorption spectroscopy[J]. Chin. Phys. B, 2018, 27(10): 107802-107802.

参考文献 56

[1]	Mizushima K, Jones P C, Wiseman P J and Goodenough J B 1980 Mater. Res. Bull. 15 783 doi: 10.1016/0025-5408(80)90012-4
[2]	Ozawa K 1994 Solid State Ionics 69 212 doi: 10.1016/0167-2738(94)90411-1
[3]	Luo W and Dahn J R 2009 Electrochim. Acta 54 4655 doi: 10.1016/j.electacta.2009.03.068
[4]	Chen Z, Lu Z and Dahn J R 2002 J. Electrochem. Soc. 149 A1604
[5]	Jang Y I, Dudney N J, Blom D A and Allard L F 2002 J. Electrochem. Soc. 149 A1442
[6]	Aurbach D, Markovsky B, Rodkin A, Levi E, Cohen Y S, Kim H J and Schmidt M 2002 Electrochim. Acta 47 4291 doi: 10.1016/S0013-4686(02)00417-6
[7]	Choi S S and Lim H S 2002 J. Power Sources 111 130 doi: 10.1016/S0378-7753(02)00305-1
[8]	Zhang L, Wang L, Lyu C, Li J and Zheng J 2014 Energies 7 6282 doi: 10.3390/en7106282
[9]	Wang Z, Wang Z, Peng W, Guo H, Li X, Wang J and Qi A 2014 Ionics 20 1525 doi: 10.1007/s11581-014-1098-z
[10]	Tebbe J L, Holder A M and Musgrave C B 2015 ACS Appl. Mater. Interfaces 7 24265 doi: 10.1021/acsami.5b07887
[11]	Yano A, Shikano M, Ueda A, Sakaebe H and Ogumi Z 2017 J. Electrochem. Soc. 164 A6116
[12]	Zhang S, Li W J, Ling S G, Li H, Zhou Z B and Chen L Q 2015 Chin. Phys. B 24 078201 doi: 10.1088/1674-1056/24/7/078201
[13]	Oh S, Lee J K, Byun D, Cho W I and Won Cho B 2004 J. Power Sources 132 249 doi: 10.1016/j.jpowsour.2004.01.049
[14]	Sun Y K, Cho S W, Myung S T, Amine K and Prakash J 2007 Electrochim. Acta 53 1013 doi: 10.1016/j.electacta.2007.08.032
[15]	Dai X, Wang L, Xu J, Wang Y, Zhou A and Li J 2014 ACS Appl. Mater. Interfaces 6 15853 doi: 10.1021/am503260s
[16]	Aydinol M K, Kohan A F, Ceder G, Cho K and Joannopoulos J 1997 Phys. Rev. B 56 1354 doi: 10.1103/PhysRevB.56.1354
[17]	Ceder G, Chiang Y M, Sadoway D R, Aydinol M K, Jang Y I and Huang B 1998 Nature 392 694 doi: 10.1038/33647
[18]	Goodenough J B and Kim Y 2010 Chem. Mater. 22 587 doi: 10.1021/cm901452z
[19]	Laubach S, Laubach S, Schmidt P C, Ensling D, Schmid S, Jaegermann W, Thißen A, Nikolowski K and Ehrenberg H 2009 Phys. Chem. Chem. Phys. 11 3278 doi: 10.1039/b901200a
[20]	Ling S G, Gao J, Xiao R J and Chen L Q 2016 Chin. Phys. B 25 018208 doi: 10.1088/1674-1056/25/1/018208
[21]	Yang W, Liu X, Qiao R, Olalde-Velasco P, Spear J D, Roseguo L, Pepper J X, Chuang Y D, Denlinger J D and Hussain Z 2013 J. Electron. Spectrosc. Relat. Phenom. 190 64 doi: 10.1016/j.elspec.2013.03.008
[22]	Kemp J P and Cox P A 1990 J. Phys.:Condens. Matter 2 15
[23]	Galakhov V R, Kurmaev E Z, Uhlenbrock S, Neumann M, Kellerman D G and Gorshkov V S 1996 Solid State Commun. 99 221 doi: 10.1016/0038-1098(96)00251-7
[24]	Montoro L A, Abbate M, Almeida E C and Rosolen J M 1999 Chem. Phys. Lett. 309 14 doi: 10.1016/S0009-2614(99)00650-8
[25]	Montoro L A, Abbate M and Rosolen J M 1999 Electrochem. Solid-State Lett. 3 410 doi: 10.1149/1.1391162
[26]	Uchimoto Y, Sawada H and Yao T 2001 J. Synchrotron Rad. 8 872 doi: 10.1107/S0909049500020938
[27]	Graetz J, Hightower A, Ahn C C, Yazami R, Rez P and Fultz B 2002 J. Phys. Chem. B 106 1286
[28]	Yoon W S, Kim K B, Kim M G, Lee M K, Shin H J, Lee J M, Lee J S and Yo C H 2002 J. Phys. Chem. B 106 2526
[29]	Yoon W S, Kim K B, Kim M G, Lee M K, Shin H J and Lee J M 2002 J. Electrochem. Soc. 149 A1305
[30]	Chen C H, Hwang B J, Chen C Y, Hu S K, Chen J M, Sheu H S and Lee J F 2007 J. Power Sources 174 938 doi: 10.1016/j.jpowsour.2007.06.083
[31]	Dahéron L, Dedryvére R, Martinez H, Ménétrier M, Denage C, Delmas C and Gonbeau D 2008 Chem. Mater. 20 583 doi: 10.1021/cm702546s
[32]	Dahéron L, Martinez H, Dedryvére R, Baraille I, Ménétrier M, Denage C, Delmas C and Gonbeau D 2009 J. Phys. Chem. C 113 5843
[33]	Taguchi N, Sakaebe H, Tatsumi K and Akita T 2015 E-J. Surf. Sci. Nanotech. 13 284 doi: 10.1380/ejssnt.2015.284
[34]	Liu X, Liu J, Qiao R, Yu Y, Li H, Suo L, Hu Y S, Chuang Y D, Shu G, Chou F, Weng T C, Nordlund D, Sokaras D, Wang Y J, Lin H, Barbiellini B, Bansil A, Song X, Liu Z, Yan S, Liu G, Qiao S, Richardson T J, Prendergast D, Hussain Z, de Groot F M F and Yang W 2012 J. Am. Chem. Soc. 134 13708 doi: 10.1021/ja303225e
[35]	Liu X, Wang D, Liu G, Srinivasan V, Liu Z, Hussain Z and Yang W 2013 Nat. Commun. 4 2568 doi: 10.1038/ncomms3568
[36]	Liu X, Yang W and Liu Z 2014 Adv. Mater. 26 7710 doi: 10.1002/adma.201304676
[37]	Liu X, Wang Y J, Barbiellini B, Hafiz H, Basak S, Liu J, Richardson T, Shu G, Chou F, Weng T C, Nordlund D, Sokaras D, Moritz B, Devereaux T P, Qiao R, Chuang Y D, Bansil A, Hussain Z and Yang W 2015 Phys. Chem. Chem. Phys. 17 26369 doi: 10.1039/C5CP04739K
[38]	Qiao R, Wray L A, Kim J H, Pieczonka N P W, Harris S J and Yang W 2015 J. Phys. Chem. C 119 27228 doi: 10.1021/acs.jpcc.5b07479
[39]	Wang L, Song J, Qiao R, Wray L A, Hossain M A, Chuang Y D, Yang W, Lu Y, Evans D, Lee J J, Vail S, Zhao X, Nishijima M, Kakimoto S and Goodenough J B 2015 J. Am. Chem. Soc. 137 2548 doi: 10.1021/ja510347s
[40]	Yang W and Qiao R 2016 Chin. Phys. B 25 017104 doi: 10.1088/1674-1056/25/1/017104
[41]	Mizokawa T, Wakisaka Y, Sudayama T, Iwai C, Miyoshi K, Takeuchi J, Wadati H, Hawthorn D G, Regier T Z and Sawatzky G A 2013 Phys. Rev. Lett. 111 056404 doi: 10.1103/PhysRevLett.111.056404
[42]	Kumagai Y, Ikeno H, Oba F, Matsunaga K and Tanaka I 2008 Phys. Rev. B 77 155124 doi: 10.1103/PhysRevB.77.155124
[43]	Merz M, Nagel P, Pinta C, Samartsev A, v. Löhneysen H, Wissinger M, Uebe S, Assmann A, Fuchs D and Schuppler S 2010 Phys. Rev. B 82 174416 doi: 10.1103/PhysRevB.82.174416
[44]	Mesilov V V, Galakhov V R, Gizhevskii B A, Semenova A S, Kellerman D G, Raekers M and Neumann M 2013 Phys. Solid State 55 943 doi: 10.1134/S1063783413050247
[45]	van Elp J, Wiel, J L, Eskes H, Kuiper P, Sawatzky G A, de Groot F M F and Turner T S 1991 Phys. Rev. B 44 6090 doi: 10.1103/PhysRevB.44.6090
[46]	Cao K, Jiao L, Liu Y, Liu H, Wang Y and Yuan H 2015 Adv. Funct. Mater. 25 1082 doi: 10.1002/adfm.201403111
[47]	Kang Q, Cao L, Li J, Huang J, Xu Z, Cheng Y, Wang X, Bai J and Li Q 2016 Ceram. Int. 42 15920 doi: 10.1016/j.ceramint.2016.07.066
[48]	Bora D K, Cheng X, Kapilashrami M, Glans P A, Luo Y and Guo J H 2015 J. Synchrotron Rad. 22 1450 doi: 10.1107/S1600577515017178
[49]	Wolverton C and Zunger A 1998 Phys. Rev. Lett. 81 606 doi: 10.1103/PhysRevLett.81.606
[50]	Lee J, Papp J K, Clément R J, Sallis S, Kwon D H, Shi T, Yang W, McCloskey B D and Ceder G 2017 Nat. Commun. 8 981 doi: 10.1038/s41467-017-01115-0
[51]	Luo K, Roberts M R, Hao R, Guerrini N, Pickup D M, Liu Y S, Edström K, Guo J, Chadwick A V, Duda L C and Bruce P G 2016 Nat. Chem. 8 684 doi: 10.1038/nchem.2471
[52]	Xu J, Sun M, Qiao R, Renfrew S E, Ma L, Wu T, Hwang S, Nordlund D, Su D, Amine K, Lu J, McCloskey B D, Yang W and Tong W 2018 Nat. Commun. 9 947 doi: 10.1038/s41467-018-03403-9
[53]	Kang J S, Kim D H, Hwang J H, Baik J, Shin H J, Kim M, Jeong Y H and Min B I 2010 Phys. Rev. B 82 193102 doi: 10.1103/PhysRevB.82.193102
[54]	Oishi M, Yamanaka K, Watanabe I, Shimoda K, Matsunaga T, Arai H, Ukyo Y, Uchimoto Y, Ogumi Z and Ohta T 2016 J. Mater. Chem. A 4 9293 doi: 10.1039/C6TA00174B
[55]	Outka D A, Stöhr J, Madix R J, Rotermund H H, Hermsmeier B and Solomon J 1987 Surf. Sci. 185 53 doi: 10.1016/S0039-6028(87)80613-1
[56]	Yogi C, Takamatsu D, Yamanaka K, Arai H, Uchimoto Y, Kojima K, Watanabe I, Ohta T and Ogumi Z 2014 J. Power Sources 248 994 doi: 10.1016/j.jpowsour.2013.10.030

Charge compensation and capacity fading in LiCoO₂ at high voltage investigated by soft x-ray absorption spectroscopy

Charge compensation and capacity fading in LiCoO₂ at high voltage investigated by soft x-ray absorption spectroscopy

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 56

相关文章 5

Metrics

本文评价

推荐阅读 0

[1]	Zhi-Gang Wang(汪志刚), Yun-Feng Gong(龚云峰), and Zhuang Liu(刘壮). Modeling of high permittivity insulator structure with interface charge by charge compensation[J]. 中国物理B, 2022, 31(2): 28501-028501.
[2]	任国玺, 张念, 冯雪飞, 章辉, 于鹏飞, 郑顺, 周櫈, 田宗旺, 刘啸嵩. Photon-in/photon-out endstation for studies of energy materials at beamline 02B02 of Shanghai Synchrotron Radiation Facility[J]. 中国物理B, 2020, 29(1): 16101-016101.
[3]	户永清, 熊伦, 刘兴泉, 赵红远, 刘广涛, 白利刚, 崔巍然, 宫宇, 李晓东. Equation of state of LiCoO₂ under 30 GPa pressure[J]. 中国物理B, 2019, 28(1): 16402-016402.
[4]	张新, 徐旭辉, 邱建备, 余雪. Effects of Li⁺ on photoluminescence of Sr₃SiO₅：Sm³⁺ red phosphor[J]. 中国物理B, 2013, 22(9): 97801-097801.
[5]	王震坡, 刘鹏, 王丽芳. Analysis on the capacity degradation mechanism of a series lithium-ion power battery pack based on inconsistency of capacity[J]. 中国物理B, 2013, 22(8): 88801-088801.