Alternating current characterization of nano-Pt(II) octaethylporphyrin (PtOEP) thin film as a new organic semiconductor

doi:10.1088/1674-1056/25/6/067201

中国物理B ›› 2016, Vol. 25 ›› Issue (6): 67201-067201.doi: 10.1088/1674-1056/25/6/067201

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Alternating current characterization of nano-Pt(II) octaethylporphyrin (PtOEP) thin film as a new organic semiconductor

M Dongol, M M El-Nahass, A El-Denglawey, A A Abuelwafa, T Soga

1 Nano and Thin Film Laboratory, Physics Department, Faculty of Science, South Valley University, Qena 83523, Egypt;
2 Physics Department, Faculty of Education, Ain Shams University, Roxy, Cairo 11757, Egypt;
3 Physics Department, Faculty of Applied Medical Science, Taif University, Turabah 21995, Kingdom of Saudi Arabia;
4 Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan

收稿日期:2015-10-31 修回日期:2016-01-24 出版日期:2016-06-05 发布日期:2016-06-05
通讯作者: A El-Denglawey E-mail:denglawey@lycos.com

Alternating current characterization of nano-Pt(II) octaethylporphyrin (PtOEP) thin film as a new organic semiconductor

M Dongol¹, M M El-Nahass², A El-Denglawey^1,3, A A Abuelwafa^1,4, T Soga⁴

1 Nano and Thin Film Laboratory, Physics Department, Faculty of Science, South Valley University, Qena 83523, Egypt;
2 Physics Department, Faculty of Education, Ain Shams University, Roxy, Cairo 11757, Egypt;
3 Physics Department, Faculty of Applied Medical Science, Taif University, Turabah 21995, Kingdom of Saudi Arabia;
4 Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan

Received:2015-10-31 Revised:2016-01-24 Online:2016-06-05 Published:2016-06-05
Contact: A El-Denglawey E-mail:denglawey@lycos.com

摘要/Abstract

摘要：

Alternating current (AC) conductivity and dielectric properties of thermally evaporated Au/PtOEP/Au thin films are investigated each as a function of temperature (303 K-473 K) and frequency (50 Hz-5 MHz). The frequency dependence of AC conductivity follows the Jonscher universal dynamic law. The AC-activation energies are determined at different frequencies. It is found that the correlated barrier hopping (CBH) model is the dominant conduction mechanism. The variation of the frequency exponent s with temperature is analyzed in terms of the CBH model. Coulombic barrier height W_m, hopping distance R_ω, and the density of localized states N(E_F) are valued at different frequencies. Dielectric constant ε₁(ω,T) and dielectric loss ε₂(ω,T) are discussed in terms of the dielectric polarization process. The dielectric modulus shows the non-Debye relaxation in the material. The extracted relaxation time by using the imaginary part of modulus (M") is found to follow the Arrhenius law.

关键词: PtOEP thin films, AC conductivity, dielectric constants, organic semiconductors, solar cell, nano materials

Abstract:

Key words: PtOEP thin films, AC conductivity, dielectric constants, organic semiconductors, solar cell, nano materials

中图分类号: (Electronic conduction in metals and alloys)

72.15.-v

72.20.-i (Conductivity phenomena in semiconductors and insulators)

M Dongol, M M El-Nahass, A El-Denglawey, A A Abuelwafa, T Soga. Alternating current characterization of nano-Pt(II) octaethylporphyrin (PtOEP) thin film as a new organic semiconductor[J]. 中国物理B, 2016, 25(6): 67201-067201.

参考文献 63

[1]	Trogler W C and Choy H C 2013 Organic Solar Cells Materials and Device Physics p. 250
[2]	Dongol M, El-Denglawey A, Elhady A F and Abuelwafa A A 2015 Appl. Phys. A 118 345
[3]	Schon J H, Kloc C and Batlogg B 2001 Phys. Rev. Lett. 86 3843
[4]	Perepichka D F, BryceM R, Batsanov A S, McInnes E J L, Zhao J P and Farley R D 2002 Chem. Eur. J. 8 4656
[5]	Brütting W 2005 Physics of Organic Semiconductors (WILEY-VCH: Verlag GmbH & Co. KGaA)
[6]	Toal S J and Trogler W C 2006 J. Mater. Chem. 16 2871
[7]	Dongol M, El-Nahass M M, El-Denglawey A, Elhady A F and Abuelwafa A A 2012 Curr. Appl. Phys. 12 1178
[8]	Dongol M, El-Denglawey A, Elhady A F and Abuelwafa A A 2012 Curr. Appl. Phys. 12 1334
[9]	Li X, Zhang C, Wu Y, Zhang H, Wang W, Yuan L, Yang H, Liu Z and Chen H 2015 Int. J. Mol. Sci. 16 27707
[10]	Lee C, Hwang I, Byeon C C, Kim B H and Greenham N C 2010 Adv. Funct. Mater. 20 2945
[11]	Tsuboi T, Wasai Y and Gabain N 2006 Thin Solid Films 496 674
[12]	Xiong K, Hou L, Wang P, Xia Y, Chen D and Xiao B 2014 J. Lumin. 151 193
[13]	Eldenglawey A 2013 Structural, optical and electrical properties of As-Se-Tl films: Physical properties of As-Se-Tl films (LAP LAMBERT Academic Publishing) p. 85
[14]	Darwish A A A, El-Nahass M M and Bekheet A E 2014 J. Alloys Compd. 586 142
[15]	Mohamed R I 2000 J. Phys. Chem. Solids 61 1357
[16]	El-Nahass M M, Atta A A, Kamel M A and Huthaily S Y 2013 Vacuum 91 14
[17]	Elliott S R 1979 Phil. Mag. B 40 507
[18]	Zeyada H M, El-Nahass M M and Makhlouf M M 2011 Curr. Appl. Phys. 11 1326
[19]	El-Nahass M M, Metwally H S, El-Sayed H E A and Hassanien A M 2012 Mater. Chem. Phys. 133 649
[20]	El-Nahass M M, Farag A A M, Abu-Samaha F S H and Elesh E 2014 Vacuum 99 153
[21]	El-Nahass M M, Atta A A, El-Zaidia E F M, Farag A A M and Ammar A H 2014 Mater. Chem. Phys. 143 490
[22]	Nawar A M, Abd El-Khalek H M and El-Nahass M M 2015 Org. Opto-Elect. 1 25
[23]	Abuelwafaa A A, El-Denglawey A, Dongol M, El-Nahass M M and Soga T 2016 J. Alloys Compd. 655 415
[24]	Abuelwafaa A A, El-Denglawey A, Dongol M, El-Nahass M M and Soga T 2015 Opt. Mater. 49 271
[25]	Tolansky T 1948 Multiple-Beam Interferometry of Surface and Films (London: Oxford University Press) p. 125
[26]	Jonscher A K 1977 Nature 267 673
[27]	Elliott S R 1987 Adv. Phys. 36 135
[28]	Long A R 1982 Adv. Phys. 31 553
[29]	Elliott S R 1977 Philos. Mag. B 36 1291
[30]	Elliott S R 1978 Philos. Mag. B 37 135
[31]	Shimakawa K and Kondo A 1983 Phys. Rev. B 72 1136
[32]	Pike G E 1972 Phys. Rev. B 6 1572
[33]	Atyia H E 2014 Acta Phys. Pol. A 125 98
[34]	Kahouli A, Sylvestre A, Jomni F, Yangui B and Legrand J 2012 J. Phys. Chem. A 116 1051
[35]	Austin I G and Mott N F 1969 Adv. Phys. 18 41
[36]	Macedo P B, Moynihan C T and Laberge N L 1973 Phys. Chem. Glasses 14 122
[37]	Macedo P B, Moynihan C T and Bose R 1972 Phys. Chem. Glasses 13 171
[38]	Wonga Y J, Hassan J and Hashim M 2013 J. Alloys Compd. 571 138
[39]	El-Nahass M M and Ali H A M 2012 Solid State Commun. 152 1084
[40]	Dakhel A A 2006 Thin Solid Films 496 353
[41]	Chen R H, Chang R Y and Shern S C 2002 J. Phys. Chem. Solids 63 2069
[42]	Chen R H, Shern S C and Fukami T 2002 J. Phys. Chem. Solids 63 203
[43]	Farag A A M, Mansour A M, Ammar A H, Abdel Rafea M and Farid A M 2012 J. Alloys Compd. 513 404
[44]	Yakuphanoglu F, Aydogdu Y, Schatzschneider U and Rentschler E 2003 Solid State Commun. 128 63
[45]	El-Menyawy E M, Zeyada H M and El-Nahass M M 2010 Solid State Sci. 12 2182
[46]	El-Nahass M M, Kamal H, Elshorbagy M H and Abdel-Hady K 2013 Org. Electron. 14 2847
[47]	Ayouchi R, Leien D, Martin F, Gabas M, Dalchiele E and Barrodo J R 2003 Thin Solid Films 68 426
[48]	Rhouma F H I, Dhahri A, Dhahri J and Valente M A 2012 Appl. Phys. A 108 593
[49]	Hegab N A and El-Mallah H M 2009 Acta Phys. Pol. A 116 1048
[50]	Atyia H E Hegab N A, Affi M A and Ismail M A 2013 J. Alloys Compd. 574 345
[51]	Atyia H E 2014 J. Nonlinear Cryst. Solids 391 83
[52]	Atyia H E, Farid A M and Hegab N A 2008 Physica B 403 3980
[53]	Yahia I S, Hegab N A, Shakra A M and AL-Ribaty A M 2012 Physica B 407 2476
[54]	Stevels J M 1975 Handbuch der Physik. In: Flugge (Berlin: Springer) p. 108
[55]	El-Nahass M M, Ali H A M, Saadeldin M and Zaghllol M 2012 Physica B 407 4453
[56]	Smyth P 1965 Dielectric Behavior and Structure (New York: McGraw-Hill)
[57]	Barsoum M 1997 Fundamental of Ceramics (London: McGraw Hill) p. 215
[58]	Tareev B 1975 Physics of Dielectric Materials (Moscow: Mir Publishers) p. 187
[59]	Sharma A and Mehtaa N 2012 Eur. Phys. J. Appl. Phys. 59 10101
[60]	Tabib A, Sdiri N, Elhouichet H and Fe'rid M 2015 J. Alloys Compd. 622 138
[61]	Dult M, Kundu R S, Hooda J, Murugavel S, Punia R and Kishore N 2015 J. Non-Cryst. Solids 423-424 1
[62]	Atif M and Nadeem M 2015 J. Alloys Compd. 623 447
[63]	El-Menyawy E M, Zedan I T, Mansour A M and Nawar H H 2014 J. Alloys Compd. 611 50

Alternating current characterization of nano-Pt(II) octaethylporphyrin (PtOEP) thin film as a new organic semiconductor

Alternating current characterization of nano-Pt(II) octaethylporphyrin (PtOEP) thin film as a new organic semiconductor

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 63

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Xue-Fei Li(李雪飞), Wen-Xian Yang(杨文献), Jun-Hua Long(龙军华), Ming Tan(谭明), Shan Jin(金山), Dong-Ying Wu(吴栋颖), Yuan-Yuan Wu(吴渊渊), and Shu-Long Lu(陆书龙). Electroluminescence explored internal behavior of carriers in InGaAsP single-junction solar cell[J]. 中国物理B, 2023, 32(1): 17801-017801.
[2]	Yi Li(李依), Dong Wei(魏东), Gaofu Guo(郭高甫), Gao Zhao(赵高), Yanan Tang(唐亚楠), and Xianqi Dai(戴宪起). Hexagonal boron phosphide and boron arsenide van der Waals heterostructure as high-efficiency solar cell[J]. 中国物理B, 2022, 31(9): 97301-097301.
[3]	Xiufang Yang(杨秀芳), Shengsheng Zhao(赵生盛), Qian Huang(黄茜), Cao Yu(郁超), Jiakai Zhou(周佳凯), Xiaoning Liu(柳晓宁), Xianglin Su(苏祥林),Ying Zhao(赵颖), and Guofu Hou(侯国付). Sub-stochiometric MoO_x by radio-frequency magnetron sputtering as hole-selective passivating contacts for silicon heterojunction solar cells[J]. 中国物理B, 2022, 31(9): 98401-098401.
[4]	Min Yue(岳敏), Yan Wang(王燕), Hui-Li Liang(梁会力), and Zeng-Xia Mei (梅增霞). Optical simulation of CsPbI₃/TOPCon tandem solar cells with advanced light management[J]. 中国物理B, 2022, 31(8): 88801-088801.
[5]	Zi-Jun Wang(王子君), Jia-Wen Li(李嘉文), Da-Yong Zhang(张大勇), Gen-Jie Yang(杨根杰), and Jun-Sheng Yu(于军胜). Improving efficiency of inverted perovskite solar cells via ethanolamine-doped PEDOT:PSS as hole transport layer[J]. 中国物理B, 2022, 31(8): 87802-087802.
[6]	Zi-Xuan Chen(陈子轩), Jia-Lin Sun(孙家林), Qiang Zhang(张强), Chong-Xin Qian(钱崇鑫), Ming-Zi Wang(王明梓), and Hong-Jian Feng(冯宏剑). Ferroelectric Ba_0.75Sr_0.25TiO₃ tunable charge transfer in perovskite devices[J]. 中国物理B, 2022, 31(5): 57202-057202.
[7]	Limin Cang(苍利民), Zongyao Qian(钱宗耀), Jinpei Wang(王金培), Libao Chen(陈利豹), Zhigang Wan(万志刚), Ke Yang(杨柯), Hui Zhang(张辉), and Yonghua Chen(陈永华). Applications and functions of rare-earth ions in perovskite solar cells[J]. 中国物理B, 2022, 31(3): 38402-038402.
[8]	He-Ju Xu(许贺菊), Li-Tao Xin(辛利桃), Dong-Qiang Chen(陈东强), Ri-Dong Cong(丛日东), and Wei Yu(于威). Analysis of the generation mechanism of the S-shaped J—V curves of MoS₂/Si-based solar cells[J]. 中国物理B, 2022, 31(3): 38503-038503.
[9]	Gang Li(李刚), Yuqian Huang(黄玉茜), Rongfeng Tang(唐荣风), Bo Che(车波), Peng Xiao(肖鹏), Weitao Lian(连伟涛), Changfei Zhu(朱长飞), and Tao Chen(陈涛). An n—n type heterojunction enabling highly efficientcarrier separation in inorganic solar cells[J]. 中国物理B, 2022, 31(3): 38803-038803.
[10]	Ying Hu(胡颖), Jiaping Wang(王家平), Peng Zhao(赵鹏), Zhenhua Lin(林珍华), Siyu Zhang(张思玉), Jie Su(苏杰), Miao Zhang(张苗), Jincheng Zhang(张进成), Jingjing Chang(常晶晶), and Yue Hao(郝跃). Reveal the large open-circuit voltage deficit of all-inorganicCsPbIBr₂ perovskite solar cells[J]. 中国物理B, 2022, 31(3): 38804-038804.
[11]	Qinxuan Dai(戴沁煊), Chao Luo(骆超), Xianjin Wang(王显进), Feng Gao(高峰), Xiaole Jiang(姜晓乐), and Qing Zhao(赵清). Surface modulation of halide perovskite films for efficient and stable solar cells[J]. 中国物理B, 2022, 31(3): 37303-037303.
[12]	Qiaopeng Cui(崔翘鹏), Liang Zhao(赵亮), Xuewen Sun(孙学文), Qiannan Yao(姚倩楠), Sheng Huang(黄胜), Lei Zhu(朱磊), Yulong Zhao(赵宇龙), Jian Song(宋健), and Yinghuai Qiang(强颖怀). Charge transfer modification of inverted planar perovskite solar cells by NiO_x/Sr:NiO_x bilayer hole transport layer[J]. 中国物理B, 2022, 31(3): 38801-038801.
[13]	Li-Jia Chen(陈丽佳), Guo-Xi Niu(牛国玺), Lian-Bin Niu(牛连斌), and Qun-Liang Song(宋群梁). Effect of net carriers at the interconnection layer in tandem organic solar cells[J]. 中国物理B, 2022, 31(3): 38802-038802.
[14]	Youming Huang(黄友铭), Yizhi Wu(吴以治), Xiaoliang Xu(许小亮), Feifei Qin(秦飞飞), Shihan Zhang(张诗涵), Jiakai An(安嘉凯), Huijie Wang(王会杰), and Ling Liu(刘玲). Nano Ag-enhanced photoelectric conversion efficiency in all-inorganic, hole-transporting-layer-free CsPbIBr₂ perovskite solar cells[J]. 中国物理B, 2022, 31(12): 128802-128802.
[15]	Ruiqi Cao(曹瑞琪), Yaochang Yue(乐耀昌), Hong Zhang(张弘), Qian Cheng(程倩), Boxin Wang(王博欣), Shilin Li(李世麟), Yuan Zhang(张渊), Shuhong Li(李书宏), and Huiqiong Zhou(周惠琼). A silazane additive for CsPbI₂Br perovskite solar cells[J]. 中国物理B, 2022, 31(11): 110101-110101.