Intramolecular photoinduced electron-transfer in azobenzene-perylene diimide

doi:10.1088/1674-1056/19/11/113401

中国物理B ›› 2010, Vol. 19 ›› Issue (11): 113401-113402.doi: 10.1088/1674-1056/19/11/113401

Intramolecular photoinduced electron-transfer in azobenzene-perylene diimide

易文辉¹, 冯弈钰², 封伟², 冯文科³, 王树峰³, 龚旗煌³

(1)Department of Electronic Science and Technology, School of Information and Electronics Engineering, Xi'an Jiaotong University, Xi'an 710049, China; (2)School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China; Tianjin Key Laboratory of Composite and Functional Materials, Tianjin 300072, China; (3)State Key Laboratory for Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871, China

收稿日期:2009-11-25 修回日期:2010-04-16 出版日期:2010-11-15 发布日期:2010-11-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 10504001, 60878019, 10821062, 10934001, 60677002 and 10828407); the National Basic Research Program of China (Grant Nos. 2009CB930504, 2007CB307001, 2006CB921601 and 2006CB806007).

Intramolecular photoinduced electron-transfer in azobenzene-perylene diimide

Feng Wen-Ke(冯文科)^a), Feng Yi-Yu(冯弈钰)^b)c), Wang Shu-Feng(王树峰)^a)†, Feng Wei(封伟)^b)c), Yi Wen-Hui(易文辉)^d), and Gong Qi-Huang(龚旗煌)^a)‡

^a State Key Laboratory for Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871, China; ^b School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China; ^c Tianjin Key Laboratory of Composite and Functional Materials, Tianjin 300072, China; ^d Department of Electronic Science and Technology, School of Information and Electronics Engineering, Xi'an Jiaotong University, Xi'an 710049, China

Received:2009-11-25 Revised:2010-04-16 Online:2010-11-15 Published:2010-11-15
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 10504001, 60878019, 10821062, 10934001, 60677002 and 10828407); the National Basic Research Program of China (Grant Nos. 2009CB930504, 2007CB307001, 2006CB921601 and 2006CB806007).

摘要/Abstract

摘要： This paper studies the intramolecular photoinduced electron-transfer (PET) of covalent bonded azobenzene-perylene diimide (AZO-PDI) in solvents by using steady-state and time-resolved fluorescence spectroscopy together with ultrafast transient absorption spectroscopic techniques. Fast fluorescence quenching is observed when AZO-PDI is excited at characteristic wavelengths of AZO and perylene moieties. Reductive electron-transfer with transfer rate faster than 10¹¹ s^-1 is found. This PET process is also consolidated by femtosecond transient absorption spectra.

Abstract: This paper studies the intramolecular photoinduced electron-transfer (PET) of covalent bonded azobenzene-perylene diimide (AZO-PDI) in solvents by using steady-state and time-resolved fluorescence spectroscopy together with ultrafast transient absorption spectroscopic techniques. Fast fluorescence quenching is observed when AZO-PDI is excited at characteristic wavelengths of AZO and perylene moieties. Reductive electron-transfer with transfer rate faster than 10¹¹ s^-1 is found. This PET process is also consolidated by femtosecond transient absorption spectra.

Key words: electron-transfer, femtosecond, AZO-PDI, transient absorption

中图分类号: (Infrared, submillimeter wave, microwave and radiowave instruments and equipment)

07.57.-c

33.15.Fm (Bond strengths, dissociation energies) 33.50.Dq (Fluorescence and phosphorescence spectra) 33.70.Jg (Line and band widths, shapes, and shifts)

冯文科, 冯弈钰, 王树峰, 封伟, 易文辉, 龚旗煌. Intramolecular photoinduced electron-transfer in azobenzene-perylene diimide[J]. 中国物理B, 2010, 19(11): 113401-113402.

Feng Wen-Ke(冯文科), Feng Yi-Yu(冯弈钰), Wang Shu-Feng(王树峰), Feng Wei(封伟), Yi Wen-Hui(易文辉), and Gong Qi-Huang(龚旗煌). Intramolecular photoinduced electron-transfer in azobenzene-perylene diimide[J]. Chin. Phys. B, 2010, 19(11): 113401-113402.

参考文献 28

[1]	Neuteboom E E, Meskers S C J, Beckers E H A, Chopin S and Janssen R A J 2006 J. Phys. Chem. A 110 12363
[2]	Kelley R F, Tauber M J and Wasielewski M R 2006 J. Am. Chem. Soc. 128 4779
[3]	Bauer P, Wietasch H, Lindner S and Thelakket M 2007 Chem. Mater. 19 88
[4]	Hippius C, Stokkum I H M, Zangrando E, Williams R M and Würthner F 2007 J. Phys. Chem. C 111 13988
[5]	Hippius C, Schlosser F, Vysotsky M O, Böhmer V and Würthner F 2006 J. Am. Chem. Soc. 128 3870
[6]	Fujitsuka M, Harada K, Sugimoto A and Majima T 2008 J. Phys. Chem. A 112 10193
[7]	Neuteboom E E, Meskers S C J, Hal P A, Duren J K J, Meijer E W, Janssen R A J, Dupin H, Pourtois G, Cornil J, Lazzaroni R, Br'edas J L and Beljonne D 2003 J. Am. Chem. Soc. 125 8625
[8]	Beckers E H A, Meskers S C J, Schenning A P H J, Chen Z, Würthner F and Janssen R A J 2004 J. Phys. Chem. A 108 6933
[9]	Struijk C W, Sieval A B, Dakhorst J E J, Dijk M V, Kimkes P, Koehorst R B M, Donker H, Schaafsma T J, Picken S J, Craats A M, Warman J M, Zuilhof H and Sudhölter E J R 2000 J. Am. Chem. Soc. 122 11057
[10]	Feng Y and Feng W 2008 Optical Materials 30 876
[11]	Wurthner F, Chen Z, Dehm V and Stepanenko V 2006 Chem. Commun. 11 1188
[12]	Icli S, Demic S, Dindar B, Doroshenko A O and Timur C 2000 J. Photochem. Photobio. A: Chem. 136 15
[13]	Nagao Y 1997 Progress in Organic Coatings 31 43
[14]	Flors C, Oesterling I, Schnitzler T, Fron E, Schweitzer G, Sliwa M, Herrmann A, Auweraer M, Schryver F C D, Müllen K and Hofkens J 2007 J. Phys. Chem. C 111 4861
[15]	Sinks L E, Rybtchinski B, Iimura M, Jones B A, Goshe A J, Zuo X, Tiede D M, Li X and Wasielewski M R 2005 Chem. Mater. 17 6295
[16]	Kirmaier C, Hindin E, Schwartz J K, Sazanovich I V, Diers J R, Muthukumaran K, Taniguchi M, Bocian D F, Lindsey J S and Holten D 2003 J. Phys. Chem. B 107 3443
[17]	Tegeder P, Hagen S, Leyssner F, Peters M V, Hecht S, Klamroth T, Saalfrank P and Wolf M 2007 Appl. Phys. A 88 465
[18]	Choi B Y, Kahng S J, Kim S, Kim H, Kim H W, Song Y J, Ihm J and Kuk Y 2006 Phys. Rev. Lett. 96 156106
[19]	Beckers E H A, Meskers S C J, Schenning A P H J, Chen Z, Wurthner F, Marsal P, Beljonne D, Cornil J and Janssen R A J 2006 J. Am. Chem. Soc. 128 649
[20]	Schmidt B, Sobotta C, Malkmus S, Laimgruber S, Braun M, Zinth W and Gilch P 2004 J. Phys. Chem. A 108 4399
[21]	Chang C W, Lu Y C, Wang T T and Diau E W G 2004 J. Am. Chem. Soc. 126 10109
[22]	Holman M W, Liu R, Zang L, Yan P, DiBenedetto S A, Bowers R D and Adams D M 2004 J. Am. Chem. Soc. 126 16126
[23]	Ramos A M, Beckers E H A, Offermans T, Meskers S C J and Janssen R A J 2004 J. Phys. Chem. A 108 8201
[24]	Rybtchinski B, Sinks L E and Wasielewski M R 2004 J. Phys. Chem. A 108 7497
[25]	Anh N V, Schlosser F, Groeneveld M M, Stokkum I H M, Wurthner F and Williams R M 2009 J. Phys. Chem. C 113 18358
[26]	Hippius C, Stokkum I H M, Gsa1nger M, Groeneveld M M, Williams R M and Wu1rthner F 2008 J. Phys. Chem. C 112 2476
[27]	Yamaguchi A, Nakagawa N Igarashi K Sekikawa T Nishioka H, Asanuma H and Yamashita M 2009 Applied Surface Science 255 9864
[28]	Ho J W, Chen W K and Cheng P Y 2009 J. Chem. Phys. 131 134308 endfootnotesize

Intramolecular photoinduced electron-transfer in azobenzene-perylene diimide

Intramolecular photoinduced electron-transfer in azobenzene-perylene diimide

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 28

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Yu He(贺羽), Runqi Kang(康润琪), Zhifu Shi(石致富), Xing Rong(荣星), and Jiangfeng Du(杜江峰). A design of resonant cavity with an improved coupling-adjusting mechanism for the W-band EPR spectrometer[J]. 中国物理B, 2022, 31(11): 117601-117601.
[2]	Yuxiao Guo(郭玉箫), Muguang Wang(王目光), Hongqian Mu(牟宏谦), and Guofang Fan(范国芳). Switchable down-, up- and dual-chirped microwave waveform generation with improved time-bandwidth product based on polarization modulation and phase encoding[J]. 中国物理B, 2022, 31(7): 78403-078403.
[3]	Kangyi Zhao(赵康伊), Shuanglong Feng(冯双龙), Chan Yang(杨婵),Jun Shen(申钧), and Yongqi Fu(付永启). Facile sensitizing of PbSe film for near-infrared photodetector by microwave plasma processing[J]. 中国物理B, 2022, 31(3): 38504-038504.
[4]	Chuangye Wang(王创业), Tigang Ning(宁提纲), Jing Li(李晶), Li Pei(裴丽), Jingjing Zheng(郑晶晶), and Jingchuan Zhang(张景川). Instantaneous frequency measurement using two parallel I/Q modulators based on optical power monitoring[J]. 中国物理B, 2022, 31(1): 10702-010702.
[5]	闫露露, 赵文宇, 张颜艳, 邰朝阳, 张攀, 饶冰洁, 宁凯, 张晓斐, 郭文阁, 张首刚, 姜海峰. Photonic generation of RF and microwave signal with relative frequency instability of 10^-15[J]. 中国物理B, 2018, 27(3): 30601-030601.
[6]	李欧鹏, 张勇, 徐锐敏, 程伟, 王元, 牛斌, 陆海燕. A G-band terahertz monolithic integrated amplifier in 0.5-μm InP double heterojunction bipolar transistor technology[J]. 中国物理B, 2016, 25(5): 58401-058401.
[7]	李兴兴, 袁学松, 张宇, 鄢扬. Theoretical research on electron beam modulation in a field-emission cold cathode electron gun[J]. 中国物理B, 2014, 23(3): 37901-037901.
[8]	涂学凑, 康琳, 刘新华, 毛庆凯, 万超, 陈健, 金飚兵, 吉争鸣, 许伟伟, 吴培亨. Nb₅N₆ microbolometer array for terahertz detection[J]. Chin. Phys. B, 2013, 22(4): 40701-040701.
[9]	尹国冰, 李曙光, 王晓琰, 刘硕. High birefringence, low loss terahertz photonic crystal fibres with zero dispersion at 0.3 THz[J]. 中国物理B, 2011, 20(9): 90701-090701.
[10]	孟现柱, 王明红, 任忠民. Smith–Purcell free electron laser based on the semi-elliptical resonator[J]. 中国物理B, 2011, 20(5): 50702-050702.
[11]	祁春超, 左都罗, 卢彦兆, 唐建, 程祖海. Transmittance investigation on capacitive mesh on thick dielectric substrates as output windows for optically pumped terahertz lasers[J]. 中国物理B, 2010, 19(11): 114202-114204.
[12]	徐嘉鑫, 凤艳艳, 孙桂娟, 戴振文. Radiative lifetime measurements of odd-parity high-excited levels of Sn I by time-resolved laser spectroscopy[J]. 中国物理B, 2009, 18(9): 3828-3832.
[13]	张洪英, 鲁振中, 樊荣伟, 陈德应. Xe-Kr laser induced collisional ionization system and experimental preparation of its initial state: Four-photon resonant excitation[J]. 中国物理B, 2008, 17(12): 4504-4509.
[14]	候继东, 李义民, 杨东海, 王义遒. EXPERIMENTAL STUDY ON LASER COOLING OF CESIUM ATOMS BY OPTICAL MOLASSES[J]. 中国物理B, 1998, 7(12): 881-885.
[15]	V.A.KAPITANOV, B.A.TIKHOMIROV, O.V.TIKHOMIROVA. METHOD FOR THE STUDY OF FAST VIBRATIONAL RELAXATION OF MOLECULES USING SPECTROPHONE[J]. 中国物理B, 1997, 6(11): 837-840.