中国物理B ›› 2025, Vol. 34 ›› Issue (4): 47102-047102.doi: 10.1088/1674-1056/adb680

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Electronic structure of a narrow-gap semiconductor KAg3Te2

Rong Feng(冯荣)1, Haotian Zheng(郑昊天)1, Haoran Liu(刘浩然)1, Binru Zhao(赵彬茹)1, Xunqing Yin(尹训庆)1, Zhihua Liu(刘智华)1, Feng Liu(刘峰)1, Guohua Wang(王国华)1, Xiaofeng Xu(许晓峰)2, Wentao Zhang(张文涛)1,3, Weidong Luo(罗卫东)1, Wei Zhou(周苇)4, and Dong Qian(钱冬)1,5,6,†   

  1. 1 Key Laboratory of Artificial Structures and Quantum Control (Ministry of Education), School of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240, China;
    2 School of Physics, Zhejiang University of Technology, Hangzhou 310023, China;
    3 Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
    4 School of Electronic and Information Engineering, Changshu Institute of Technology, Changshu 215500, China;
    5 Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China;
    6 Tsung-Dao Lee Institute, Shanghai Jiao Tong University, Shanghai 200240, China
  • 收稿日期:2025-01-02 修回日期:2025-02-13 接受日期:2025-02-15 出版日期:2025-04-15 发布日期:2025-04-15
  • 通讯作者: Dong Qian E-mail:dqian@sjtu.edu.cn
  • 基金资助:
    Project supported by the National Key Research and Development Program of China and the National Natural Science Foundation of China.

Electronic structure of a narrow-gap semiconductor KAg3Te2

Rong Feng(冯荣)1, Haotian Zheng(郑昊天)1, Haoran Liu(刘浩然)1, Binru Zhao(赵彬茹)1, Xunqing Yin(尹训庆)1, Zhihua Liu(刘智华)1, Feng Liu(刘峰)1, Guohua Wang(王国华)1, Xiaofeng Xu(许晓峰)2, Wentao Zhang(张文涛)1,3, Weidong Luo(罗卫东)1, Wei Zhou(周苇)4, and Dong Qian(钱冬)1,5,6,†   

  1. 1 Key Laboratory of Artificial Structures and Quantum Control (Ministry of Education), School of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240, China;
    2 School of Physics, Zhejiang University of Technology, Hangzhou 310023, China;
    3 Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
    4 School of Electronic and Information Engineering, Changshu Institute of Technology, Changshu 215500, China;
    5 Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China;
    6 Tsung-Dao Lee Institute, Shanghai Jiao Tong University, Shanghai 200240, China
  • Received:2025-01-02 Revised:2025-02-13 Accepted:2025-02-15 Online:2025-04-15 Published:2025-04-15
  • Contact: Dong Qian E-mail:dqian@sjtu.edu.cn
  • Supported by:
    Project supported by the National Key Research and Development Program of China and the National Natural Science Foundation of China.

摘要: KAg$_{3}$Te$_{2}$ with a layered crystal structure has been predicted to be a possible topological insulator. Through electrical transport measurements, we revealed its semiconducting behavior with a narrow band gap of $\sim 0.4$ eV and p-type character. The infrared transmission spectra of single crystals yielded an optical band gap of $\sim 0.3$ eV. Angle-resolved photoemission spectroscopy reveals a bulk energy gap at the Brillouin zone center, with no observable surface state, suggesting that KAg$_{3}$Te$_{2}$ is a topological trivial narrow-gap semiconductor. The experimentally determined effective mass of the holes in KAg$_{3}$Te$_{2 }$ is very small ($\sim 0.12 m_{\rm e}$). The valence band maximum is quasi-two-dimensional, while the conduction band minimum is fully three-dimensional. Such intriguing dimensional anisotropy can be attributed to the distinct orbital contributions from K, Ag, and Te atoms to the respective bands.

关键词: KAg$_{3}$Te$_{2}$ crystals, narrow-gap semiconductor, angle-resolved photoemission spectroscopy, small effective hole mass, dimensional anisotropy

Abstract: KAg$_{3}$Te$_{2}$ with a layered crystal structure has been predicted to be a possible topological insulator. Through electrical transport measurements, we revealed its semiconducting behavior with a narrow band gap of $\sim 0.4$ eV and p-type character. The infrared transmission spectra of single crystals yielded an optical band gap of $\sim 0.3$ eV. Angle-resolved photoemission spectroscopy reveals a bulk energy gap at the Brillouin zone center, with no observable surface state, suggesting that KAg$_{3}$Te$_{2}$ is a topological trivial narrow-gap semiconductor. The experimentally determined effective mass of the holes in KAg$_{3}$Te$_{2 }$ is very small ($\sim 0.12 m_{\rm e}$). The valence band maximum is quasi-two-dimensional, while the conduction band minimum is fully three-dimensional. Such intriguing dimensional anisotropy can be attributed to the distinct orbital contributions from K, Ag, and Te atoms to the respective bands.

Key words: KAg$_{3}$Te$_{2}$ crystals, narrow-gap semiconductor, angle-resolved photoemission spectroscopy, small effective hole mass, dimensional anisotropy

中图分类号:  (Semiconductor compounds)

  • 71.20.Nr
79.60.-i (Photoemission and photoelectron spectra) 71.20.-b (Electron density of states and band structure of crystalline solids)