Structural color of metallic glass through picosecond laser

doi:10.1088/1674-1056/ad7672

中国物理B ›› 2024, Vol. 33 ›› Issue (10): 108104-108104.doi: 10.1088/1674-1056/ad7672

Structural color of metallic glass through picosecond laser

Yue'e Zhang(张月娥)^1,2, Xing Tong(童星)^2,†, Yuqiang Yan(闫玉强)², Shuo Cao(曹硕)¹, Hai-Bo Ke(柯海波)^2,‡, and Wei-Hua Wang(汪卫华)^1,2,3

1 College of Physics, Liaoning University, Shenyang 110036, China;
2 Songshan Lake Materials Laboratory, Dongguan 523808, China;
3 Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

收稿日期:2024-07-24 修回日期:2024-08-27 接受日期:2024-09-03 发布日期:2024-09-29
通讯作者: Xing Tong, Hai-Bo Ke E-mail:tongxing@sslab.org.cn;kehaibo@sslab.org.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 52071222 and 52471180), Guangdong Major Project of Basic and Applied Basic Research, China (Grant No. 2019B030302010), Guangdong Basic and Applied Basic Research, China (Grant No. 2020B1515130007), the National Key Research and Development Program of China (Grant No. 2021YFA0716302), and the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB30000000).

Structural color of metallic glass through picosecond laser

Yue'e Zhang(张月娥)^1,2, Xing Tong(童星)^2,†, Yuqiang Yan(闫玉强)², Shuo Cao(曹硕)¹, Hai-Bo Ke(柯海波)^2,‡, and Wei-Hua Wang(汪卫华)^1,2,3

1 College of Physics, Liaoning University, Shenyang 110036, China;
2 Songshan Lake Materials Laboratory, Dongguan 523808, China;
3 Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Received:2024-07-24 Revised:2024-08-27 Accepted:2024-09-03 Published:2024-09-29
Contact: Xing Tong, Hai-Bo Ke E-mail:tongxing@sslab.org.cn;kehaibo@sslab.org.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 52071222 and 52471180), Guangdong Major Project of Basic and Applied Basic Research, China (Grant No. 2019B030302010), Guangdong Basic and Applied Basic Research, China (Grant No. 2020B1515130007), the National Key Research and Development Program of China (Grant No. 2021YFA0716302), and the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB30000000).

1. 2024-108104-SI.pdf(1039KB)

摘要/Abstract

摘要： The alteration in surface color of metallic glasses (MGs) holds great significance in the context of microstructure design and commercial utility. It is essential to accurately describe the structures that are formed during the laser and color separation processes in order to develop practical laser coloring applications. Due to the high oxidation sensitivity of La-based metallic glass, it can broaden the color range but make it more complex. Structure coloring by laser processing on the surface of La-based metallic glass can be conducted after thermoplastic forming. It is particularly important to clarify the role of structure and composition in the surface coloring process. The aim is to study the relationship between amorphous surface structural color, surface geometry, and oxide formation by laser processing in metallic glasses. The findings revealed that the periodic structure primarily determines the surface color at laser energy densities below 1.0 J/mm$^{2}$. In contrast, the surface color predominantly depends on the proportion of oxides that are formed when energy densities exceed 1.0 J/mm$^{2}$. Consequently, this study provides a novel concept for the fundamental investigation of laser coloring and establishes a new avenue for practical application.

关键词: metallic glass, picosecond laser, periodic structure, oxides

Abstract: The alteration in surface color of metallic glasses (MGs) holds great significance in the context of microstructure design and commercial utility. It is essential to accurately describe the structures that are formed during the laser and color separation processes in order to develop practical laser coloring applications. Due to the high oxidation sensitivity of La-based metallic glass, it can broaden the color range but make it more complex. Structure coloring by laser processing on the surface of La-based metallic glass can be conducted after thermoplastic forming. It is particularly important to clarify the role of structure and composition in the surface coloring process. The aim is to study the relationship between amorphous surface structural color, surface geometry, and oxide formation by laser processing in metallic glasses. The findings revealed that the periodic structure primarily determines the surface color at laser energy densities below 1.0 J/mm$^{2}$. In contrast, the surface color predominantly depends on the proportion of oxides that are formed when energy densities exceed 1.0 J/mm$^{2}$. Consequently, this study provides a novel concept for the fundamental investigation of laser coloring and establishes a new avenue for practical application.

Key words: metallic glass, picosecond laser, periodic structure, oxides

中图分类号: (Glasses (including metallic glasses))

81.05.Kf

81.40.Tv (Optical and dielectric properties related to treatment conditions) 81.16.Rf (Micro- and nanoscale pattern formation) 81.65.Mq (Oxidation)

Yue'e Zhang(张月娥), Xing Tong(童星), Yuqiang Yan(闫玉强), Shuo Cao(曹硕), Hai-Bo Ke(柯海波), and Wei-Hua Wang(汪卫华). Structural color of metallic glass through picosecond laser[J]. 中国物理B, 2024, 33(10): 108104-108104.

Yue'e Zhang(张月娥), Xing Tong(童星), Yuqiang Yan(闫玉强), Shuo Cao(曹硕), Hai-Bo Ke(柯海波), and Wei-Hua Wang(汪卫华). Structural color of metallic glass through picosecond laser[J]. Chin. Phys. B, 2024, 33(10): 108104-108104.

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Structural color of metallic glass through picosecond laser

Structural color of metallic glass through picosecond laser

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