Synthesis of ternary compound in H-S-Se system at high pressures

doi:10.1088/1674-1056/abf7aa

中国物理B ›› 2021, Vol. 30 ›› Issue (12): 127801-127801.doi: 10.1088/1674-1056/abf7aa

Synthesis of ternary compound in H-S-Se system at high pressures

Xiao Zhang(张晓)^1,2,†

1 Key Laboratory of Materials Physics, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences(CAS), Hefei 230031, China;
2 University of Science and Technology of China, Hefei 230026, China

收稿日期:2021-02-13 修回日期:2021-04-08 接受日期:2021-04-14 出版日期:2021-11-15 发布日期:2021-11-23
通讯作者: Xiao Zhang E-mail:xiaozhang@issp.ac.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 51672279, 51727806, 11874361, and 11774354), the Science Challenge Project, China (Grant No. TZ2016001), the CAS Innovation Fund (Grant No. CXJJ-19-B08), and the CASHIPS Director's Fund (Grant No. YZJJ201705).

Synthesis of ternary compound in H-S-Se system at high pressures

Xiao Zhang(张晓)^1,2,†

1 Key Laboratory of Materials Physics, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences(CAS), Hefei 230031, China;
2 University of Science and Technology of China, Hefei 230026, China

Received:2021-02-13 Revised:2021-04-08 Accepted:2021-04-14 Online:2021-11-15 Published:2021-11-23
Contact: Xiao Zhang E-mail:xiaozhang@issp.ac.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 51672279, 51727806, 11874361, and 11774354), the Science Challenge Project, China (Grant No. TZ2016001), the CAS Innovation Fund (Grant No. CXJJ-19-B08), and the CASHIPS Director's Fund (Grant No. YZJJ201705).

摘要/Abstract

摘要： The chemical reaction products of elemental sulfur (S), selenium (Se), and molecular hydrogen (H₂) at high pressures and room temperature are probed by Raman spectroscopy. Two known compounds H₂S and H₂Se can be synthesized after laser heating at pressures lower than 1 GPa. Under further compression at room temperature, an H₂S-H₂Se and an H₂S-H₂Se-H₂ van der Waals compounds are synthesized at 4 GPa and 6 GPa, respectively. The later is of guest-host structure and can be identified as (H₂S)_x(H₂Se)_(2-x)H₂. It can be maintained up to 37 GPa at least, and the stability of its H₂Se molecules is extended:the H-Se stretching mode can be detected at least to 36 GPa but disappears at 22 GPa in (H₂Se)₂H₂. The pressure dependence of S-H and Se-H stretching modes of this ternary compound is in line with that of (H₂S)₂H₂ and (H₂Se)₂H₂, respectively. However, its hydrogen subsystem only shows the relevance to (H₂S)₂H₂, indicating that this ternary compound can be viewed as H₂Se-replaced partial H₂S of (H₂S)₂H₂.

关键词: hydride, high pressure, Raman spectroscopy

Abstract: The chemical reaction products of elemental sulfur (S), selenium (Se), and molecular hydrogen (H₂) at high pressures and room temperature are probed by Raman spectroscopy. Two known compounds H₂S and H₂Se can be synthesized after laser heating at pressures lower than 1 GPa. Under further compression at room temperature, an H₂S-H₂Se and an H₂S-H₂Se-H₂ van der Waals compounds are synthesized at 4 GPa and 6 GPa, respectively. The later is of guest-host structure and can be identified as (H₂S)_x(H₂Se)_(2-x)H₂. It can be maintained up to 37 GPa at least, and the stability of its H₂Se molecules is extended:the H-Se stretching mode can be detected at least to 36 GPa but disappears at 22 GPa in (H₂Se)₂H₂. The pressure dependence of S-H and Se-H stretching modes of this ternary compound is in line with that of (H₂S)₂H₂ and (H₂Se)₂H₂, respectively. However, its hydrogen subsystem only shows the relevance to (H₂S)₂H₂, indicating that this ternary compound can be viewed as H₂Se-replaced partial H₂S of (H₂S)₂H₂.

Key words: hydride, high pressure, Raman spectroscopy

中图分类号: (Infrared and Raman spectra)

78.30.-j

82.40.Fp (Shock wave initiated reactions, high-pressure chemistry) 74.70.-b (Superconducting materials other than cuprates)

Xiao Zhang(张晓). Synthesis of ternary compound in H-S-Se system at high pressures[J]. 中国物理B, 2021, 30(12): 127801-127801.

Xiao Zhang(张晓). Synthesis of ternary compound in H-S-Se system at high pressures[J]. Chin. Phys. B, 2021, 30(12): 127801-127801.

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Synthesis of ternary compound in H-S-Se system at high pressures

Synthesis of ternary compound in H-S-Se system at high pressures

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