A new sulfur-doped source and synergistic effect with nitrogen for carbon dots produced from glucose

doi:10.1088/1674-1056/ab5213

中国物理B ›› 2019, Vol. 28 ›› Issue (12): 128102-128102.doi: 10.1088/1674-1056/ab5213

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇下一篇

A new sulfur-doped source and synergistic effect with nitrogen for carbon dots produced from glucose

Lige Fu(付丽歌), Yuehong Yin(殷月红), Guohua Cao(曹国华), Pingping Wu(武苹苹), Jian Wang(汪舰), Lingling Yan(闫玲玲), Baoqing Zhang(张宝庆), Ming Li(李明)

1 School of Physics and Electronic Information, Henan Polytechnic University, Jiaozuo 454000, China;
2 School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China

收稿日期:2019-08-15 修回日期:2019-09-29 出版日期:2019-12-05 发布日期:2019-12-05
通讯作者: Yuehong Yin, Guohua Cao E-mail:yuehongyin@126.com;ghcao@hpu.edu.cn
基金资助:
Project by the National Natural Science Foundation of China (Grant Nos. 51571085, 11805052, and 61705062), the Research Project for Basic and Forefront Technology of Henan Province, China (Grant No. 162300410219), and the Doctor Foundation of Henan Polytechnic University, China (Grant No. B2014049).

A new sulfur-doped source and synergistic effect with nitrogen for carbon dots produced from glucose

Lige Fu(付丽歌)¹, Yuehong Yin(殷月红)¹, Guohua Cao(曹国华)¹, Pingping Wu(武苹苹)¹, Jian Wang(汪舰)¹, Lingling Yan(闫玲玲)¹, Baoqing Zhang(张宝庆)², Ming Li(李明)¹

1 School of Physics and Electronic Information, Henan Polytechnic University, Jiaozuo 454000, China;
2 School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China

Received:2019-08-15 Revised:2019-09-29 Online:2019-12-05 Published:2019-12-05
Contact: Yuehong Yin, Guohua Cao E-mail:yuehongyin@126.com;ghcao@hpu.edu.cn
Supported by:
Project by the National Natural Science Foundation of China (Grant Nos. 51571085, 11805052, and 61705062), the Research Project for Basic and Forefront Technology of Henan Province, China (Grant No. 162300410219), and the Doctor Foundation of Henan Polytechnic University, China (Grant No. B2014049).

摘要/Abstract

摘要： The nitrogen and sulfur co-doped carbon dots (N, S-CDs) with increased luminescence were synthesized by a hydrothermal process in one green pot by using glucose, and a new sulfur-doping source of sodium sulfite was developed. The synergistic effect of the N and S groups was well discussed through the structure analysis of Fourier transform infrared spectra and x-ray photoelectron spectra. The surface states of N, S-CDs embody more complicated functional groups, and S element exists as -SSO₃, -C-SO₃, and SO₄^2- groups due to the introduction of sodium sulfite. The sulfur-containing groups passivate the surface of the CDs, and the relatively high sulfur groups may reduce the non-radiation centers. The fluorescence is affected by the hydroxyl group of the solvent. The quenching of Fe³⁺ ion to fluorescence and the sensitivity of fluorescence to pH were also investigated.

关键词: carbon dots, glucose, sodium sulfite, nitrogen and sulfur codoping, synergistic effect

Abstract: The nitrogen and sulfur co-doped carbon dots (N, S-CDs) with increased luminescence were synthesized by a hydrothermal process in one green pot by using glucose, and a new sulfur-doping source of sodium sulfite was developed. The synergistic effect of the N and S groups was well discussed through the structure analysis of Fourier transform infrared spectra and x-ray photoelectron spectra. The surface states of N, S-CDs embody more complicated functional groups, and S element exists as -SSO₃, -C-SO₃, and SO₄^2- groups due to the introduction of sodium sulfite. The sulfur-containing groups passivate the surface of the CDs, and the relatively high sulfur groups may reduce the non-radiation centers. The fluorescence is affected by the hydroxyl group of the solvent. The quenching of Fe³⁺ ion to fluorescence and the sensitivity of fluorescence to pH were also investigated.

Key words: carbon dots, glucose, sodium sulfite, nitrogen and sulfur codoping, synergistic effect

中图分类号: (Carbon/carbon-based materials)

81.05.U-

81.07.-b (Nanoscale materials and structures: fabrication and characterization) 42.70.-a (Optical materials)

付丽歌, 殷月红, 曹国华, 武苹苹, 汪舰, 闫玲玲, 张宝庆, 李明. A new sulfur-doped source and synergistic effect with nitrogen for carbon dots produced from glucose[J]. 中国物理B, 2019, 28(12): 128102-128102.

Lige Fu(付丽歌), Yuehong Yin(殷月红), Guohua Cao(曹国华), Pingping Wu(武苹苹), Jian Wang(汪舰), Lingling Yan(闫玲玲), Baoqing Zhang(张宝庆), Ming Li(李明). A new sulfur-doped source and synergistic effect with nitrogen for carbon dots produced from glucose[J]. Chin. Phys. B, 2019, 28(12): 128102-128102.

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A new sulfur-doped source and synergistic effect with nitrogen for carbon dots produced from glucose

A new sulfur-doped source and synergistic effect with nitrogen for carbon dots produced from glucose

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