Adsorption behavior of triphenylene on Ru(0001) investigated by scanning tunneling microscopy

doi:10.1088/1674-1056/28/7/076801

中国物理B ›› 2019, Vol. 28 ›› Issue (7): 76801-076801.doi: 10.1088/1674-1056/28/7/076801

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

Adsorption behavior of triphenylene on Ru(0001) investigated by scanning tunneling microscopy

Li-Wei Jing(井立威), Jun-Jie Song(宋俊杰), Yu-Xi Zhang(张羽溪), Qiao-Yue Chen(陈乔悦), Kai-Kai Huang(黄凯凯), Han-Jie Zhang(张寒洁), Pi-Mo He(何丕模)

1 Zhejiang Province Key Laboratory of Quantum Technology and Device, Department of Physics, Zhejiang University, Hangzhou 310027, China;
2 Collaborative Innovation Center of Advanced Microstructure, Nanjing University, Nanjing 210093, China;
3 School of Information Science and Engineering, Ningbo Institute of Technology, Zhejiang University, Ningbo 315100, China;
4 Department of Fundamental and Social Science, Zhejiang University of Water Resources and Electric Power, Hangzhou 310018, China

收稿日期:2019-04-06 修回日期:2019-05-03 出版日期:2019-07-05 发布日期:2019-07-05
通讯作者: Han-Jie Zhang, Pi-Mo He E-mail:zhj_fox@zju.edu.cn;phypmhe@zju.edu.cn
基金资助:
Project supported by the National Key Research and Development Program of China (Grant No. 2017YFB0503100) and the National Natural Science Foundation of China (Grant No. 11790313).

Adsorption behavior of triphenylene on Ru(0001) investigated by scanning tunneling microscopy

Li-Wei Jing(井立威)¹, Jun-Jie Song(宋俊杰)³, Yu-Xi Zhang(张羽溪)⁴, Qiao-Yue Chen(陈乔悦)¹, Kai-Kai Huang(黄凯凯)¹, Han-Jie Zhang(张寒洁)¹, Pi-Mo He(何丕模)^1,2

1 Zhejiang Province Key Laboratory of Quantum Technology and Device, Department of Physics, Zhejiang University, Hangzhou 310027, China;
2 Collaborative Innovation Center of Advanced Microstructure, Nanjing University, Nanjing 210093, China;
3 School of Information Science and Engineering, Ningbo Institute of Technology, Zhejiang University, Ningbo 315100, China;
4 Department of Fundamental and Social Science, Zhejiang University of Water Resources and Electric Power, Hangzhou 310018, China

Received:2019-04-06 Revised:2019-05-03 Online:2019-07-05 Published:2019-07-05
Contact: Han-Jie Zhang, Pi-Mo He E-mail:zhj_fox@zju.edu.cn;phypmhe@zju.edu.cn
Supported by:
Project supported by the National Key Research and Development Program of China (Grant No. 2017YFB0503100) and the National Natural Science Foundation of China (Grant No. 11790313).

摘要/Abstract

摘要：

As a representative of small aromatic molecules, triphenylene (TP) has markedly high carrier mobility and is an ideal precursor for building graphene nanostructures. We mainly investigated the adsorption behavior of TP molecules on Ru(0001) by using scanning tunneling microscopy (STM). In submonolayer regime, TP molecules are randomly dispersed on Ru(0001) and the TP overlayer can be thoroughly dehydrogenated and converted into graphene islands at 700 K. Due to weak interaction between TP molecules and graphene, the grooves formed among graphene islands have confinement effect on TP molecules. TP adopts a flat-lying adsorption mode and has two adsorption configurations with the 3-fold molecular axis aligned almost parallel or antiparallel to the[1100] direction of the substrate. At TP coverages of 0.6 monolayer (ML) and 0.8 ML, the orientational distributions of the two adsorption configurations are equal. At about 1.0 ML, we find the coexistence of locally ordered and disordered phases. The ordered phase includes two sets of different superstructures with the symmetries of (√19×√19)R23.41° and p(4×4), respectively. The adsorption behavior of TP on Ru(0001) can be attributed to the delicate balance between molecule-substrate and molecule-molecule interactions.

关键词: self-assembly, ordered superstructure, scanning tunneling microscopy

Abstract:

Key words: self-assembly, ordered superstructure, scanning tunneling microscopy

中图分类号: (Adsorbate structure (binding sites, geometry))

68.43.Fg

68.37.Ef (Scanning tunneling microscopy (including chemistry induced with STM)) 68.43.-h (Chemisorption/physisorption: adsorbates on surfaces)

井立威, 宋俊杰, 张羽溪, 陈乔悦, 黄凯凯, 张寒洁, 何丕模. Adsorption behavior of triphenylene on Ru(0001) investigated by scanning tunneling microscopy[J]. 中国物理B, 2019, 28(7): 76801-076801.

Li-Wei Jing(井立威), Jun-Jie Song(宋俊杰), Yu-Xi Zhang(张羽溪), Qiao-Yue Chen(陈乔悦), Kai-Kai Huang(黄凯凯), Han-Jie Zhang(张寒洁), Pi-Mo He(何丕模). Adsorption behavior of triphenylene on Ru(0001) investigated by scanning tunneling microscopy[J]. Chin. Phys. B, 2019, 28(7): 76801-076801.

参考文献 55

[1]	Kaneko S, Murai D, Marques Gonzalez S, Nakamura H, Komoto Y, Fujii S, Nishino T, Ikeda K, Tsukagoshi K and Kiguchi M 2016 J. Am. Chem. Soc. 138 1294 doi: 10.1021/jacs.5b11559
[2]	Komoto Y, Fujii S, Iwane M and Kiguchi M 2016 J. Mater. Chem. C 4 8842 doi: 10.1039/C6TC03268K
[3]	Trasobares J, Vuillaume D, Theron D and Clement N 2016 Nat Commun. 7 12850 doi: 10.1038/ncomms12850
[4]	Yan S C, Xie N, Gong H Q, Sun Q, Guo Y, Shan X Y and Lu X H 2012 Chin. Phys. Lett. 29 046803 doi: 10.1088/0256-307X/29/4/046803
[5]	Li J, Gottardi S, Solianyk L, Moreno Lopez J C and Stohr M 2016 J. Phys. Chem. C 120 18093 doi: 10.1021/acs.jpcc.6b05541
[6]	DeLoach A S, Conrad B R, Einstein T L and Dougherty D B 2017 J. Chem. Phys. 147 184701 doi: 10.1063/1.4999623
[7]	Jeon S, Doak P W, Sumpter B G, Ganesh P and Maksymovych P 2016 ACS Nano 10 7821 doi: 10.1021/acsnano.6b03492
[8]	Parschau M, Fasel R, Ernst K H, Groning O, Brandenberger L, Schillinger R, Greber T, Seitsonen A P, Wu Y T and Siegel J S 2007 Angew. Chem. Int. Ed. Engl. 46 8258 doi: 10.1002/anie.200700610
[9]	Abb S, Harnau L, Gutzler R, Rauschenbach S and Kern K 2016 Nat Commun. 7 10335 doi: 10.1038/ncomms10335
[10]	Otero R, Gallego J M, de Parga A L, Martin N and Miranda R 2011 Adv. Mater. 23 5148 doi: 10.1002/adma.201102022
[11]	Kumar A, Banerjee K and Liljeroth P 2017 Nanotechnology 28 082001 doi: 10.1088/1361-6528/aa564f
[12]	Jarvinen P, Hamalainen S K, Banerjee K, Hakkinen P, Ijas M, Harju A and Liljeroth P 2013 Nano Lett. 13 3199 doi: 10.1021/nl401265f
[13]	Caputo M, Panighel M, Lisi S, et al. 2016 Nano Lett. 16 3409 doi: 10.1021/acs.nanolett.5b02635
[14]	Ashkenasy G, Cahen D, Cohen R, Shanzer A and Vilan A 2002 Acc. Chem. Res. 35 121 doi: 10.1021/ar990047t
[15]	Kim J H, Ribierre J C, Yang Y S, Adachi C, Kawai M, Jung J, Fukushima T and Kim Y 2016 Nat Commun. 7 10653 doi: 10.1038/ncomms10653
[16]	Peyrot D and Silly F 2016 ACS Nano 10 5490 doi: 10.1021/acsnano.6b01938
[17]	Han Z, Czap G, Chiang C L, Xu C, Wagner P J, Wei X, Zhang Y, Wu R and Ho W 2017 Science 358 206 doi: 10.1126/science.aai8625
[18]	Ren J, Bao D L, Dong L, Gao L, Wu R, Yan L, Wang A, Yan J, Wang Y, Du S X, Huan Q and Gao H J 2017 Chin. Phys. B 26 086801 doi: 10.1088/1674-1056/26/8/086801
[19]	Wang H, Sun X, Li D, Zhang X, Chen S, Shao W, Tian Y and Xie Y 2017 J. Am. Chem. Soc. 139 2468 doi: 10.1021/jacs.6b12878
[20]	Enache M, Maggini L, Llanes Pallas A, Jung T A, Bonifazi D and Stöhr M 2014 J. Phys. Chem. C 118 15286 doi: 10.1021/jp503188m
[21]	Dou R F, Ma X C, Xi L, Yip H L, Wong K Y, Lau W M, Jia J F, Xue Q K, Yang W S, Ma H and Jen A K 2006 Langmuir 22 3049 doi: 10.1021/la052987u
[22]	Xu L, Ding S Y, Liu J, Sun J, Wang W and Zheng Q Y 2016 Chem. Commun. (Camb) 52 4706
[23]	Heller L E, Whitleigh J, Roth D F, Oherlein E M, Lucci F R, Kolonko K J and Plass K E 2012 Langmuir 28 14855 doi: 10.1021/la3031733
[24]	Yokoyama T, Yokoyama S, Kamikado T, Okuno Y and Mashiko S 2001 Nature 413 619 doi: 10.1038/35098059
[25]	Gao H Y, Wagner H, Held P A, Du S, Gao H J, Studer A and Fuchs H 2015 Appl. Phys. Lett. 106 081606 doi: 10.1063/1.4907777
[26]	Lin N, Dmitriev A, Weckesser J, Barth J V and Kern K 2002 Angew. Chem. Int. Ed. Engl. 41 4779 doi: 10.1002/anie.200290046
[27]	Quiñonero D, Frontera A, Deyá P M, Alkorta I and Elguero J 2008 Chem. Phys. Lett. 460 406 doi: 10.1016/j.cplett.2008.06.028
[28]	Wen R, Yan C J, Yan H J, Pan G B and Wan L J 2011 Chem. Commun. (Camb) 47 6915
[29]	Zyss J, Ledoux Rak I, Weiss H C, Bläser D, Boese R, Thallapally P K, Thalladi V R and Desiraju G R 2003 Chem. Mater. 15 3063 doi: 10.1021/cm031018m
[30]	Gardner J W 2004 Electronic Noses & Sensors for the Detection of Explosives (1st edn.) (Dordrecht: Springer) pp. 29-37 doi: ronic Noses
[31]	Katsonis N, Marchenko A and Fichou D 2003 J. Am. Chem. Soc. 125 13682 doi: 10.1021/ja0375737
[32]	Xu J, Li T, Geng Y, Zhao D, Deng K, Zeng Q and Wang C 2015 J. Phys. Chem. C 119 9227 doi: 10.1021/jp512079z
[33]	Kumar S 2004 Liq. Cryst. 31 1037 doi: 10.1080/02678290410001724746
[34]	Turner R J 2015 Triphenylene as a Scaffold for New Molecular Materials (Ph.D. Thesis) (Norwich: University of East Anglia)
[35]	Gupta M and Pal S K 2016 Langmuir 32 1120 doi: 10.1021/acs.langmuir.5b03353
[36]	Wyrick J, Kim D H, Sun D, Cheng Z, Lu W, Zhu Y, Berl, K, Kim Y S, Rotenberg E, Luo M, Hyldgaard P, Einstein T L and Bartels L 2011 Nano Lett. 11 2944 doi: 10.1021/nl201441b
[37]	Lu B, Zhang H, Li H, Bao S, He P and Hao T 2003 Phys. Rev. B 68 125410 doi: 10.1103/PhysRevB.68.125410
[38]	Horcas I, Fernandez R, Gomez Rodriguez J M, Colchero J, Gomez Herrero J and Baro A M 2007 Rev. Sci. Instrum. 78 013705 doi: 10.1063/1.2432410
[39]	Cui Y, Fu Q, Zhang H and Bao X 2011 Chem. Commun. (Camb) 47 1470
[40]	Gao J F and Ding F 2015 J. Cluster Sci. 26 347 doi: 10.1007/s10876-014-0834-x
[41]	Moritz W, Wang B, Bocquet M L, Brugger T, Greber T, Wintterlin J and Gunther S 2010 Phys. Rev. Lett. 104 136102 doi: 10.1103/PhysRevLett.104.136102
[42]	Liao Q, Zhang H J, Wu K, Li H Y, Bao S N and He P 2010 Appl. Surf. Sci. 257 82 doi: 10.1016/j.apsusc.2010.06.037
[43]	Feng W, Lei S, Li Q and Zhao A 2011 J. Phys. Chem. C 115 24858 doi: 10.1021/jp2082962
[44]	Cai Y, Zhang H, Song J, Zhang Y, Rehman A U and He P 2015 Nanotechnology 26 295601 doi: 10.1088/0957-4484/26/29/295601
[45]	Song J, Zhang H, Zhang Y, Cai Y, Bao S and He P 2016 Appl. Surf. Sci. 367 424 doi: 10.1016/j.apsusc.2016.01.214
[46]	Wang C S, Bartelt N C, Ragan R and Thurmer K 2018 Carbon 129 537 doi: 10.1016/j.carbon.2017.12.005
[47]	Zint S, Ebeling D, Ahles S, Wegner H A and Schirmeisen A 2016 J. Phys. Chem. C 120 1615
[48]	Weiss K, Gebert S, Wühn M, Wadepohl H and Wöll C 1998 J. Vac. Sci. Technol. A 16 1017 doi: 10.1116/1.581225
[49]	Zhang X, Wang H, Wang S, Shen Y, Yang Y, Deng K, Zhao K, Zeng Q and Wang C 2012 J. Phys. Chem. C 117 307
[50]	Rui G, Jialin Z, Songtao Z, Xiaojiang Y, Shu Z, Shuo S, Zhenyu L and Wei C 2017 Acta Phys. -Chim. Sin. 33 627
[51]	Glöckler K, Seidel C, Soukopp A, Sokolowski M, Umbach E, Böhringer M, Berndt R and Schneider W D 1998 Surf. Sci. 405 1 doi: 10.1016/S0039-6028(97)00888-1
[52]	Nowakowski R, Seidel C and Fuchs H 2001 Phys. Rev. B 63 195418 doi: 10.1103/PhysRevB.63.195418
[53]	Hu F, Zhang H, Mao H, Liao Q and He P 2011 J. Chem. Phys. 134 194702 doi: 10.1063/1.3591968
[54]	Mantooth B A, Sykes E C H, Han P, Moore A M, Donhauser Z J, Crespi V H and Weiss P S 2007 J. Phys. Chem. C 111 6167
[55]	Witte G and Wöll C 2004 J. Mater. Res. 19 1889 doi: 10.1557/JMR.2004.0251

相关文章 15

[1]	Wangwei Xu(许望伟), Shijie Sun(孙诗杰), Muzi Yang(杨慕紫), Zhenliang Hao(郝振亮), Lei Gao(高蕾), Jianchen Lu(卢建臣), Jiasen Zhu(朱嘉森), Jian Chen(陈建), and Jinming Cai(蔡金明). Polarization Raman spectra of graphene nanoribbons[J]. 中国物理B, 2023, 32(4): 46803-046803.
[2]	Jing Wang(王静), Meysam Bagheri Tagani, Li Zhang(张力), Yu Xia(夏雨), Qilong Wu(吴奇龙), Bo Li(黎博), Qiwei Tian(田麒玮), Yuan Tian(田园), Long-Jing Yin(殷隆晶), Lijie Zhang(张利杰), and Zhihui Qin(秦志辉). Selective formation of ultrathin PbSe on Ag(111)[J]. 中国物理B, 2022, 31(9): 96801-096801.
[3]	Geng Li(李更), Shiyu Zhu(朱诗雨), Peng Fan(范朋), Lu Cao(曹路), and Hong-Jun Gao(高鸿钧). Exploring Majorana zero modes in iron-based superconductors[J]. 中国物理B, 2022, 31(8): 80301-080301.
[4]	Qi-Yuan Li(李启远), Yang-Yang Lv(吕洋洋), Yong-Jie Xu(徐永杰), Li Zhu(朱立), Wei-Min Zhao(赵伟民), Yanbin Chen(陈延彬), and Shao-Chun Li(李绍春). Surface electron doping induced double gap opening in T_d-WTe₂[J]. 中国物理B, 2022, 31(6): 66802-066802.
[5]	Bin Hu(胡彬), Yuhan Ye(耶郁晗), Zihao Huang(黄子豪), Xianghe Han(韩相和), Zhen Zhao(赵振),Haitao Yang(杨海涛), Hui Chen(陈辉), and Hong-Jun Gao(高鸿钧). Robustness of the unidirectional stripe order in the kagome superconductor CsV₃Sb₅[J]. 中国物理B, 2022, 31(5): 58102-058102.
[6]	Jing-Peng Song(宋靖鹏) and Ang Li(李昂). Electronic properties and interfacial coupling in Pb islands on single-crystalline graphene[J]. 中国物理B, 2022, 31(3): 37401-037401.
[7]	Wenze Gao(高文泽), Chi Zhang(张弛), Zheng Zhou(周正), and Wei Xu(许维). On-surface synthesis of one-dimensional carbyne-like nanostructures with sp-carbon[J]. 中国物理B, 2022, 31(12): 128101-128101.
[8]	Jian-Mei Li(李健梅), Dong Hao(郝东), Li-Huan Sun(孙丽欢), Xiang-Qian Tang(唐向前), Yang An(安旸), Xin-Yan Shan(单欣岩), and Xing-Hua Lu(陆兴华). Enhanced photon emission by field emission resonances and local surface plasmon in tunneling junction[J]. 中国物理B, 2022, 31(11): 116801-116801.
[9]	Qi Zheng(郑琦), Li Huang(黄立), Deliang Bao(包德亮), Rongting Wu(武荣庭), Yan Li(李彦), Xiao Lin(林晓), Shixuan Du(杜世萱), and Hong-Jun Gao(高鸿钧). Substrate tuned reconstructed polymerization of naphthalocyanine on Ag(110)[J]. 中国物理B, 2022, 31(1): 18202-018202.
[10]	Le Lei(雷乐), Feiyue Cao(曹飞跃), Shuya Xing(邢淑雅), Haoyu Dong(董皓宇), Jianfeng Guo(郭剑锋), Shangzhi Gu(顾尚志), Yanyan Geng(耿燕燕), Shuo Mi(米烁), Hanxiang Wu(吴翰翔), Fei Pang(庞斐), Rui Xu(许瑞), Wei Ji(季威), and Zhihai Cheng(程志海). Phase transition-induced superstructures of β-Sn films with atomic-scale thickness[J]. 中国物理B, 2021, 30(9): 96804-096804.
[11]	Xiaoshuai Fu(富晓帅), Li Liu(刘丽), Li Zhang(张力), Qilong Wu(吴奇龙), Yu Xia(夏雨), Lijie Zhang(张利杰), Yuan Tian(田园), Long-Jing Yin(殷隆晶), and Zhihui Qin(秦志辉). Signatures of strong interlayer coupling in γ-InSe revealed by local differential conductivity[J]. 中国物理B, 2021, 30(8): 87306-087306.
[12]	Huan Yang(杨欢), Yixuan Gao(高艺璇), Wenhui Niu(牛雯慧), Xiao Chang(常霄), Li Huang(黄立), Junzhi Liu(刘俊治), Yiyong Mai(麦亦勇), Xinliang Feng(冯新亮), Shixuan Du(杜世萱), and Hong-Jun Gao(高鸿钧). Fabrication of sulfur-doped cove-edged graphene nanoribbons on Au(111)[J]. 中国物理B, 2021, 30(7): 77306-077306.
[13]	Lijie Lei(雷李杰), Shuo Wang(王硕), Xinyuan Zhang(张昕源), Wenjie Lai(赖文杰), Jinyu Wu(吴晋宇), and Yongxiang Gao(高永祥). Phoretic self-assembly of active colloidal molecules[J]. 中国物理B, 2021, 30(5): 56112-056112.
[14]	Huan Yang(杨欢), Yun Cao(曹云), Yixuan Gao(高艺璇), Yubin Fu(付钰彬), Li Huang(黄立), Junzhi Liu(刘俊治), Xinliang Feng(冯新亮), Shixuan Du(杜世萱), and Hong-Jun Gao(高鸿钧). NBN-doped nanographene embedded with five- and seven-membered rings on Au(111) surface[J]. 中国物理B, 2021, 30(5): 56802-056802.
[15]	Han-Bin Deng(邓翰宾), Yuan Li(李渊), Zili Feng(冯子力), Jian-Yu Guan(关剑宇), Xin Yu(于鑫), Xiong Huang(黄雄), Rui-Zhe Liu(刘睿哲), Chang-Jiang Zhu(朱长江), Limin Liu(刘立民), Ying-Kai Sun(孙英开), Xi-Liang Peng(彭锡亮), Shuai-Shuai Li(李帅帅), Xin Du(杜鑫), Zheng Wang(王铮), Rui Wu(武睿), Jia-Xin Yin(殷嘉鑫), You-Guo Shi(石友国), and Han-Qing Mao(毛寒青). Moiré superlattice modulations in single-unit-cell FeTe films grown on NbSe₂ single crystals[J]. 中国物理B, 2021, 30(12): 126801-126801.

Adsorption behavior of triphenylene on Ru(0001) investigated by scanning tunneling microscopy

Adsorption behavior of triphenylene on Ru(0001) investigated by scanning tunneling microscopy

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 55

相关文章 15

Metrics

本文评价

推荐阅读 0