中国物理B ›› 2018, Vol. 27 ›› Issue (2): 24208-024208.doi: 10.1088/1674-1056/27/2/024208

• ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS • 上一篇    下一篇

Fabrication of mixed perovskite organic cation thin films via controllable cation exchange

Yu-Long Zhao(赵宇龙), Jin-Feng Wang(王进峰), Ben-Guang Zhao(赵本广), Chen-Chen Jia(贾晨晨), Jun-Peng Mou(牟俊朋), Lei Zhu(朱磊), Jian Song(宋健), Xiu-Quan Gu(顾修全), Ying-Huai Qiang(强颖怀)   

  1. School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, China
  • 收稿日期:2017-07-08 修回日期:2017-11-03 出版日期:2018-02-05 发布日期:2018-02-05
  • 通讯作者: Ying-Huai Qiang E-mail:yhqiang@cumt.edu.cn
  • 基金资助:
    Project supported by the Fundamental Research Funds for the Central Universities, China (Grant No. 2015QNA09).

Fabrication of mixed perovskite organic cation thin films via controllable cation exchange

Yu-Long Zhao(赵宇龙), Jin-Feng Wang(王进峰), Ben-Guang Zhao(赵本广), Chen-Chen Jia(贾晨晨), Jun-Peng Mou(牟俊朋), Lei Zhu(朱磊), Jian Song(宋健), Xiu-Quan Gu(顾修全), Ying-Huai Qiang(强颖怀)   

  1. School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, China
  • Received:2017-07-08 Revised:2017-11-03 Online:2018-02-05 Published:2018-02-05
  • Contact: Ying-Huai Qiang E-mail:yhqiang@cumt.edu.cn
  • About author:42.82.Gw; 42.88.+h; 42.90.+m
  • Supported by:
    Project supported by the Fundamental Research Funds for the Central Universities, China (Grant No. 2015QNA09).

摘要: Here in this paper, we demonstrate a facile technique for creating the mixed formamidinium (HN=CHNH3+, FA+) and methylammonium (CH3NH3+, MA+) cations in the lead iodide perovskite. This technique entails a facile drop-casting of formamidinium iodide (FAI) solutions on as-prepared MAPbI3 perovskite thin films under the controlled conditions, which leads to controllable displacement of the MA+ cations by FA+ cations in the perovskite structure at room temperature. Uniform and controllable mixed organic cation perovskite thin films without a “bi-layered” or graded structure are achieved. By applying this approach to photovoltaic devices, we are able to improve the performances of devices through extending their optical-absorption onset further into the infrared region to enhance solar-light harvesting. Additionally, this work provides a simple and efficient technique to tune the structural, electrical, and optoelectronic properties of the light-harvesting materials for high-performance perovskite solar cells.

关键词: organic-inorganic perovskitesolar cell, morphology, cation exchange, drop-casting

Abstract: Here in this paper, we demonstrate a facile technique for creating the mixed formamidinium (HN=CHNH3+, FA+) and methylammonium (CH3NH3+, MA+) cations in the lead iodide perovskite. This technique entails a facile drop-casting of formamidinium iodide (FAI) solutions on as-prepared MAPbI3 perovskite thin films under the controlled conditions, which leads to controllable displacement of the MA+ cations by FA+ cations in the perovskite structure at room temperature. Uniform and controllable mixed organic cation perovskite thin films without a “bi-layered” or graded structure are achieved. By applying this approach to photovoltaic devices, we are able to improve the performances of devices through extending their optical-absorption onset further into the infrared region to enhance solar-light harvesting. Additionally, this work provides a simple and efficient technique to tune the structural, electrical, and optoelectronic properties of the light-harvesting materials for high-performance perovskite solar cells.

Key words: organic-inorganic perovskitesolar cell, morphology, cation exchange, drop-casting

中图分类号:  (Other integrated-optical elements and systems)

  • 42.82.Gw
42.88.+h (Environmental and radiation effects on optical elements, devices, and systems) 42.90.+m (Other topics in optics)