Influences of Mg2+ ion on dopant occupancy and upconversion luminescence of Ho3+ ion in LiNbO3 crystal

doi:10.1088/1674-1056/22/9/094201

中国物理B ›› 2013, Vol. 22 ›› Issue (9): 94201-094201.doi: 10.1088/1674-1056/22/9/094201

• ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS • 上一篇下一篇

Influences of Mg²⁺ ion on dopant occupancy and upconversion luminescence of Ho³⁺ ion in LiNbO₃ crystal

代丽^{a b}, 徐超^c, 张颖^a, 李大勇^a, 徐玉恒^c

a School of Materials Science and Engineering, Harbin University of Science and Technology, Harbin 150080, China;
b Applied Science College, Harbin University of Science and Technology, Harbin 150080, China;
c Department of the Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China

收稿日期:2012-11-14 修回日期:2013-03-25 出版日期:2013-07-26 发布日期:2013-07-26
基金资助:
Project supported by the China Postdoctoral Science Foundation (Grant No. 2012M520759 ) and the Science and Technology Research Project of Education Bureau of Heilongjiang Province, China (Grant No. 12531098).

Influences of Mg²⁺ ion on dopant occupancy and upconversion luminescence of Ho³⁺ ion in LiNbO₃ crystal

Dai Li (代丽)^{a b}, Xu Chao (徐超)^c, Zhang Ying (张颖)^a, Li Da-Yong (李大勇)^a, Xu Yu-Heng (徐玉恒)^c

a School of Materials Science and Engineering, Harbin University of Science and Technology, Harbin 150080, China;
b Applied Science College, Harbin University of Science and Technology, Harbin 150080, China;
c Department of the Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China

Received:2012-11-14 Revised:2013-03-25 Online:2013-07-26 Published:2013-07-26
Contact: Dai Li E-mail:daili198108@126.com
Supported by:
Project supported by the China Postdoctoral Science Foundation (Grant No. 2012M520759 ) and the Science and Technology Research Project of Education Bureau of Heilongjiang Province, China (Grant No. 12531098).

摘要/Abstract

摘要： The effects of a Mg²⁺ ion on the dopant occupancy and upconversion luminescence of a Ho³⁺ ion in LiNbO₃ crystal are reported. The birefringence gradient of the crystal is measured to investigate the optical homogeneity. The X-ray powder diffraction spectrum and the upconversion luminescence are used to investigate defect structure and spectroscopic properties of Mg,Ho:LiNbO₃. Under 808-nm excitation, blue, red, and very intense yellow-green bands are observed. Based on the energy levels of Ho³⁺ in LiNbO₃, and the pump intensity dependence of the observed emission, an excitation scheme is presented. The upconversion emission spectra reveal an enhancement of upconversion intensity when the Mg²⁺ ions are introduced into Ho:LiNbO₃. The main upconversion mechanism is discussed in this work.

关键词: Mg, Ho：LiNbO₃, upconversion luminescence, optical homogeneity

Abstract: The effects of a Mg²⁺ ion on the dopant occupancy and upconversion luminescence of a Ho³⁺ ion in LiNbO₃ crystal are reported. The birefringence gradient of the crystal is measured to investigate the optical homogeneity. The X-ray powder diffraction spectrum and the upconversion luminescence are used to investigate defect structure and spectroscopic properties of Mg,Ho:LiNbO₃. Under 808-nm excitation, blue, red, and very intense yellow-green bands are observed. Based on the energy levels of Ho³⁺ in LiNbO₃, and the pump intensity dependence of the observed emission, an excitation scheme is presented. The upconversion emission spectra reveal an enhancement of upconversion intensity when the Mg²⁺ ions are introduced into Ho:LiNbO₃. The main upconversion mechanism is discussed in this work.

Key words: Mg, Ho：LiNbO₃, upconversion luminescence, optical homogeneity

中图分类号: (Diffraction and scattering)

42.25.Fx

42.65.-k (Nonlinear optics) 74.25.Gz (Optical properties)

代丽, 徐超, 张颖, 李大勇, 徐玉恒. Influences of Mg²⁺ ion on dopant occupancy and upconversion luminescence of Ho³⁺ ion in LiNbO₃ crystal[J]. 中国物理B, 2013, 22(9): 94201-094201.

Dai Li (代丽), Xu Chao (徐超), Zhang Ying (张颖), Li Da-Yong (李大勇), Xu Yu-Heng (徐玉恒). Influences of Mg²⁺ ion on dopant occupancy and upconversion luminescence of Ho³⁺ ion in LiNbO₃ crystal[J]. Chin. Phys. B, 2013, 22(9): 94201-094201.

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Influences of Mg²⁺ ion on dopant occupancy and upconversion luminescence of Ho³⁺ ion in LiNbO₃ crystal

Influences of Mg²⁺ ion on dopant occupancy and upconversion luminescence of Ho³⁺ ion in LiNbO₃ crystal

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