中国物理B ›› 2012, Vol. 21 ›› Issue (4): 47803-047803.doi: 10.1088/1674-1056/21/4/047803

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李盼来1 2 3,徐征1 2,赵谡玲1 2,王永生1 2,张福俊1 2   

  • 收稿日期:2011-08-25 修回日期:2011-10-09 出版日期:2012-02-29 发布日期:2012-02-29
  • 通讯作者: 徐征,zhengxu@bjtu.edu.cn E-mail:zhengxu@bjtu.edu.cn

The concentration quenching and crystallographic sites of Eu2+ in Ca2BO3Cl

Li Pan-Lai(李盼来)a)b)c), Xu Zheng(徐征)a)b)†, Zhao Su-Ling(赵谡玲)a)b), Wang Yong-Sheng(王永生)a)b), and Zhang Fu-Jun(张福俊)a)b)   

  1. a. Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, China;
    b. Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China;
    c. College of Physics Science & Technology, Hebei University, Baoding 071002, China
  • Received:2011-08-25 Revised:2011-10-09 Online:2012-02-29 Published:2012-02-29
  • Contact: Xu Zheng,zhengxu@bjtu.edu.cn E-mail:zhengxu@bjtu.edu.cn
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant Nos. 10974013, 60978060, and 10804006), the Research Fund for the Doctoral Program of Higher Education, China (Grant No. 20090009110027), the Beijing Municipal Natural Science Foundation, China (Grant No. 1102028), the National Basic Research Program of China (Grant No. 2010CB327704), the National Natural Science Foundation for Distinguished Young Scholars (Grant No. 60825407), the Beijing Municipal Science and Technology Commission, China (Grant No. Z090803044009001), the Science Fund of the Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Ministry of Education, China (Grant No. 2010LOI12), and the Excellent Doctor’s Science and Technology Innovation Foundation of Beijing Jiaotong University, China (Grant No. 2011YJS073).

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Abstract: A yellow phosphor, Ca2BO3Cl:Eu2+, is prepared by the high-temperature solid-state method. Under the condition of excitation sources ranging from ultraviolet to visible light, efficient yellow emission can be observed. The emission spectrum shows an asymmetrical single intensive band centred at 573 nm, which corresponds to the 4f,65d1→4f,7 transition of Eu2+. Eu2+ ions occupy two types of Ca2+ sites in the Ca2BO3Cl lattice and form two corresponding emission centres, respectively, which lead to the asymmetrical emission of Eu2+ in Ca2BO3Cl. The emission intensity of Eu2+ in Ca2BO3Cl is influenced by the Eu2+ doping concentration. Concentration quenching is discovered, and its mechanism is verified to be a dipole-dipole interaction. The value of the critical transfer distance is calculated to be 2.166 nm, which is in good agreement with the 2.120 nm value derived from the experimental data.

Key words: luminescence, Ca2BO3Cl:Eu2+, concentration quenching, crystallographic sites

中图分类号:  (Photoluminescence, properties and materials)

  • 78.55.-m
33.50.Dq (Fluorescence and phosphorescence spectra) 33.20.Kf (Visible spectra)