Ca2BO3Cl:Ce3+, Tb3+: A novel tunable emitting phosphor for white light-emitting diode

doi:10.1088/1674-1056/21/12/127804

Chin. Phys. B ›› 2012, Vol. 21 ›› Issue (12): 127804-127804.doi: 10.1088/1674-1056/21/12/127804

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Ca₂BO₃Cl:Ce³⁺, Tb³⁺: A novel tunable emitting phosphor for white light-emitting diode

李盼来^{a b c}, 王永生^{a b}, 赵谡玲^{a b}, 张福俊^{a b}, 徐征^{a b}

a Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, China;
b Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China;
c College of Physics Science & Technology, Hebei University, Baoding 071002, China

收稿日期:2012-04-17 修回日期:2012-05-08 出版日期:2012-11-01 发布日期:2012-11-01
基金资助:
Project supported by the National Basic Research Program of China (Grant No. 2010CB327704), the National Natural Science Foundation for Distinguished Young Scholars of China (Grant No. 60825407), the New Century Excellent Talents in University (Grant No. NCET-10-0220), the National Natural Science Foundation of China (Grant Nos. 10974013, 60978060, 10804006, and 50902042)

Ca₂BO₃Cl:Ce³⁺, Tb³⁺: A novel tunable emitting phosphor for white light-emitting diode

Li Pan-Lai (李盼来)^{a b c}, Wang Yong-Sheng (王永生)^{a b}, Zhao Su-Ling (赵谡玲)^{a b}, Zhang Fu-Jun (张福俊)^{a b}, Xu Zheng (徐征)^{a b}

a Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, China;
b Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China;
c College of Physics Science & Technology, Hebei University, Baoding 071002, China

Received:2012-04-17 Revised:2012-05-08 Online:2012-11-01 Published:2012-11-01
Contact: Wang Yong-Sheng, Xu Zheng E-mail:yshwang@bjtu.edu.cn;zhengxu@bjtu.edu.cn
Supported by:
Project supported by the National Basic Research Program of China (Grant No. 2010CB327704), the National Natural Science Foundation for Distinguished Young Scholars of China (Grant No. 60825407), the New Century Excellent Talents in University (Grant No. NCET-10-0220), the National Natural Science Foundation of China (Grant Nos. 10974013, 60978060, 10804006, and 50902042)

摘要/Abstract

摘要： Ca₂BO₃Cl:Ce³⁺, Ca₂BO₃Cl:Tb³⁺, and Ca₂BO₃Cl:Ce³⁺, Tb³⁺ phosphors are synthesized by a high temperature solid-state reaction. The emission intensity of Ce³⁺ or Tb³⁺ in Ca₂BO₃Cl is influenced by the Ce³⁺ or Tb³⁺ doping content, and the optimum concentrations of Ce³⁺ and Tb³⁺ are 0.03 mol and 0.05 mol, respectively. The concentration quenching effect of Ce³⁺ or Tb³⁺ in Ca₂BO₃Cl occurs, and the concentration quenching mechanism is d-d interaction for either Ce³⁺ or Tb³⁺. The Ca₂BO₃Cl:Ce³⁺, Tb³⁺ can produce colour emission from blue to green by properly tuning the relative ratio between Ce³⁺ and Tb³⁺, and the emission intensity of Tb³⁺ in Ca₂BO₃Cl can be enhanced by the energy transfer from Ce³⁺ to Tb³⁺. The results indicate that Ca₂BO₃Cl:Ce³⁺, Tb³⁺ may be a promising double emission phosphor for UV-based white light emitting diode.

关键词: luminescence, phosphor, Ca₂BO₃Cl：Ce³⁺, Tb³⁺, energy transfer

Abstract: Ca₂BO₃Cl:Ce³⁺, Ca₂BO₃Cl:Tb³⁺, and Ca₂BO₃Cl:Ce³⁺, Tb³⁺ phosphors are synthesized by a high temperature solid-state reaction. The emission intensity of Ce³⁺ or Tb³⁺ in Ca₂BO₃Cl is influenced by the Ce³⁺ or Tb³⁺ doping content, and the optimum concentrations of Ce³⁺ and Tb³⁺ are 0.03 mol and 0.05 mol, respectively. The concentration quenching effect of Ce³⁺ or Tb³⁺ in Ca₂BO₃Cl occurs, and the concentration quenching mechanism is d-d interaction for either Ce³⁺ or Tb³⁺. The Ca₂BO₃Cl:Ce³⁺, Tb³⁺ can produce colour emission from blue to green by properly tuning the relative ratio between Ce³⁺ and Tb³⁺, and the emission intensity of Tb³⁺ in Ca₂BO₃Cl can be enhanced by the energy transfer from Ce³⁺ to Tb³⁺. The results indicate that Ca₂BO₃Cl:Ce³⁺, Tb³⁺ may be a promising double emission phosphor for UV-based white light emitting diode.

Key words: luminescence, phosphor, Ca₂BO₃Cl：Ce³⁺, Tb³⁺, energy transfer

中图分类号: (Photoluminescence, properties and materials)

78.55.-m

33.50.Dq (Fluorescence and phosphorescence spectra) 33.20.Kf (Visible spectra)

李盼来, 王永生, 赵谡玲, 张福俊, 徐征. Ca₂BO₃Cl:Ce³⁺, Tb³⁺: A novel tunable emitting phosphor for white light-emitting diode[J]. Chin. Phys. B, 2012, 21(12): 127804-127804.

Li Pan-Lai (李盼来), Wang Yong-Sheng (王永生), Zhao Su-Ling (赵谡玲), Zhang Fu-Jun (张福俊), Xu Zheng (徐征). Ca₂BO₃Cl:Ce³⁺, Tb³⁺: A novel tunable emitting phosphor for white light-emitting diode[J]. Chin. Phys. B, 2012, 21(12): 127804-127804.

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Ca₂BO₃Cl:Ce³⁺, Tb³⁺: A novel tunable emitting phosphor for white light-emitting diode

Ca₂BO₃Cl:Ce³⁺, Tb³⁺: A novel tunable emitting phosphor for white light-emitting diode

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