中国物理B ›› 2012, Vol. 21 ›› Issue (10): 106101-106101.doi: 10.1088/1674-1056/21/10/106101

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇    下一篇

Synthesis and thermoelectric properties of Mn-doped AgSbTe2 compounds

张贺a b, 骆军b, 朱航天b, 刘泉林a, 梁敬魁b, 李静波b, 刘广耀b   

  1. a State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;
    b Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
  • 收稿日期:2012-04-05 修回日期:2012-06-19 出版日期:2012-09-01 发布日期:2012-09-01
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant Nos. 11144002 and 51172276).

Synthesis and thermoelectric properties of Mn-doped AgSbTe2 compounds

Zhang He (张贺)a b, Luo Jun (骆军)b, Zhu Hang-Tian (朱航天)b, Liu Quan-Lin (刘泉林)a, Liang Jing-Kui (梁敬魁)b, Li Jing-Bo (李静波)b, Liu Guang-Yao (刘广耀)b   

  1. a State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;
    b Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
  • Received:2012-04-05 Revised:2012-06-19 Online:2012-09-01 Published:2012-09-01
  • Contact: Luo Jun E-mail:jluo@aphy.iphy.ac.cn
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant Nos. 11144002 and 51172276).

摘要: Polycrystalline p-type Ag0.9Sb1.1-xMnxTe2.05(x=0.05, 0.10, and 0.20) compounds have been prepared by a combined process of melt-quenching and spark plasma sintering. The sample composition of Ag0.9Sb1.1-xMnxTe2.05 has been specially designed in order to achieve the doping effect by replacing part of Sb with Mn and to present the uniformly dispersed Ag2Te phase in the matrix by adding insufficient Te, which is beneficial for optimizing the electrical transport properties and enhancing the phonon scattering effect. All the samples have the NaCl-type structure according to our X-ray powder diffraction analysis. After the treatment of spark plasma sintering, only the sample with x = 0.20 has a small amount of MnTe2 impurities. The thermal analysis indicates that a tiny amount of Ag2Te phase exists in all these samples. The presence of the MnTe2 impurity with high resistance and high thermal conductivity leads to the deteriorative thermoelectric performance of the sample with x=0.20 due to the decreased electrical transport properties and the increased thermal conductivity. In contrast, the sample with x=0.10 exhibits enhanced thermoeletric properties due to the Mn-doping effect. A dimensionless thermoelectric figure of merit of 1.2 is attained for the sample with x=0.10 at 573 K, showing promising thermoelectric properties in the medium temperature range.

关键词: AgSbTe2, phase stability, crystal structure, thermoelectric properties

Abstract: Polycrystalline p-type Ag0.9Sb1.1-xMnxTe2.05(x=0.05, 0.10, and 0.20) compounds have been prepared by a combined process of melt-quenching and spark plasma sintering. The sample composition of Ag0.9Sb1.1-xMnxTe2.05 has been specially designed in order to achieve the doping effect by replacing part of Sb with Mn and to present the uniformly dispersed Ag2Te phase in the matrix by adding insufficient Te, which is beneficial for optimizing the electrical transport properties and enhancing the phonon scattering effect. All the samples have the NaCl-type structure according to our X-ray powder diffraction analysis. After the treatment of spark plasma sintering, only the sample with x = 0.20 has a small amount of MnTe2 impurities. The thermal analysis indicates that a tiny amount of Ag2Te phase exists in all these samples. The presence of the MnTe2 impurity with high resistance and high thermal conductivity leads to the deteriorative thermoelectric performance of the sample with x=0.20 due to the decreased electrical transport properties and the increased thermal conductivity. In contrast, the sample with x=0.10 exhibits enhanced thermoeletric properties due to the Mn-doping effect. A dimensionless thermoelectric figure of merit of 1.2 is attained for the sample with x=0.10 at 573 K, showing promising thermoelectric properties in the medium temperature range.

Key words: AgSbTe2, phase stability, crystal structure, thermoelectric properties

中图分类号:  (X-ray diffraction)

  • 61.05.cp
64.60.My (Metastable phases) 73.50.Lw (Thermoelectric effects)