中国物理B ›› 2010, Vol. 19 ›› Issue (8): 84203-084203.doi: 10.1088/1674-1056/19/8/084203

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Study on UV-light-induced absorption in LiNbO3:Fe, Co crystal

陈洪建1, 阎文博1, 陈贵锋1, 沈俊1, 申绪男1, 李养贤1, 师丽红2   

  1. (1)School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China; (2)Tianjin Institute of Urban Construction, Tianjin 300384, China
  • 收稿日期:2009-08-05 修回日期:2009-10-12 出版日期:2010-08-15 发布日期:2010-08-15
  • 基金资助:
    Project supported by the Natural Science Foundation of Hebei Province, China (Grant Nos. F2007000119 and F2009000108), the Natural Science Foundation of Tianjin, China (Grant No. 09JCYBJC02400), and the Scientific Research Foundation of Education Bureau of Hebei Province, China (Grant No. 2008113).

Study on UV-light-induced absorption in LiNbO3:Fe, Co crystal

Chen Hong-Jian(陈洪建)a), Shi Li-Hong(师丽红)b), Yan Wen-Bo(阎文博)a)†, Chen Gui-Feng(陈贵锋)a), Shen Jun(沈俊)a), Shen Xu-Nan(申绪男)a), and Li Yang-Xian(李养贤)a)   

  1. a School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China; b Tianjin Institute of Urban Construction, Tianjin 300384, China
  • Received:2009-08-05 Revised:2009-10-12 Online:2010-08-15 Published:2010-08-15
  • Supported by:
    Project supported by the Natural Science Foundation of Hebei Province, China (Grant Nos. F2007000119 and F2009000108), the Natural Science Foundation of Tianjin, China (Grant No. 09JCYBJC02400), and the Scientific Research Foundation of Education Bureau of Hebei Province, China (Grant No. 2008113).

摘要: In this paper, the temporary UV-light-induced absorption in LiNbO3:Fe, Co crystal is investigated for different UV intensities. It is found that the sensitizing process in LiNbO3:Fe, Co can be considered as a combination of two sub-processes with different time constants. Based on the lattice structure and the photochromic mechanism of the material, the two sub-processes are suggested to arise from electron transfer from O2 - to Fe3 + through two paths with different distances. The two-colour recording experiment in LiNbO3:Fe, Co is also preformed by using UV and green light as gating and writing beams respectively. High sensitivity is obtained in the recording, which is considered as the consequence of direct charge transfer from O2 - to Fe3 + .

Abstract: In this paper, the temporary UV-light-induced absorption in LiNbO3:Fe, Co crystal is investigated for different UV intensities. It is found that the sensitizing process in LiNbO3:Fe, Co can be considered as a combination of two sub-processes with different time constants. Based on the lattice structure and the photochromic mechanism of the material, the two sub-processes are suggested to arise from electron transfer from O2 - to Fe3 + through two paths with different distances. The two-colour recording experiment in LiNbO3:Fe, Co is also preformed by using UV and green light as gating and writing beams respectively. High sensitivity is obtained in the recording, which is considered as the consequence of direct charge transfer from O2 - to Fe3 + .

Key words: lithium niobate, photochromic, charge transfer, photorefractive effect

中图分类号:  (Other nonmetallic inorganics)

  • 78.40.Ha
61.66.Fn (Inorganic compounds) 61.72.J- (Point defects and defect clusters) 61.72.S- (Impurities in crystals) 78.20.Jq (Electro-optical effects)