Holographic property of photopolymers with  different amine photoinitiators

doi:10.1088/1674-1056/19/2/024212

中国物理B ›› 2010, Vol. 19 ›› Issue (2): 24212-024212.doi: 10.1088/1674-1056/19/2/024212

Holographic property of photopolymers with different amine photoinitiators

路海, 李若平, 孙彩霞, 肖勇, 唐道广, 黄明举

Institute of Optics & Optoelectronics Technique and School of Physics and Electronics, Henan University, Kaifeng 475001, China

收稿日期:2007-07-28 修回日期:2009-07-22 出版日期:2010-02-15 发布日期:2010-02-15
基金资助:
Project supported by the Natural Science Foundation of Henan University, China (Grant No. 06ZDZR002).

Holographic property of photopolymers with different amine photoinitiators

Lu Hai(路海),Li Ruo-Ping(李若平), Sun Cai-Xia(孙彩霞), Xiao Yong(肖勇), Tang Dao-Guang(唐道广), and Huang Ming-Ju(黄明举)^†

Institute of Optics & Optoelectronics Technique and School of Physics and Electronics, Henan University, Kaifeng 475001, China

Received:2007-07-28 Revised:2009-07-22 Online:2010-02-15 Published:2010-02-15
Supported by:
Project supported by the Natural Science Foundation of Henan University, China (Grant No. 06ZDZR002).

摘要/Abstract

摘要： Holographic parameters and photobleaching kinetics of the photopolymers with five different amine photoinitiators are studied. The maximum values of diffraction efficiency, photobleaching coefficient and quantum yield follow the sequence: Triethanolamine (TEA)> Diethanolamine (DEA)> Ethanolamine (EA)> Triethylamine (TETN)> Diethylamine (DETN). The holographic capabilities of photopolymer performances are determined by the number of functional groups in the amine molecular structure. There is an optimum proportion of the photoinitiator, the photosensitizer and the monomer in the test of holographic parameters with different amine concentrations. The maximum diffraction efficiency is 59.26\%, sensitivity is 1.72\times 10^{ - 3}~cm^{2}/mJ, and the maximum refractive modulation index is 4.64\times 10^{ - 4}.

Abstract: Holographic parameters and photobleaching kinetics of the photopolymers with five different amine photoinitiators are studied. The maximum values of diffraction efficiency, photobleaching coefficient and quantum yield follow the sequence: Triethanolamine (TEA)> Diethanolamine (DEA)> Ethanolamine (EA)> Triethylamine (TETN)> Diethylamine (DETN). The holographic capabilities of photopolymer performances are determined by the number of functional groups in the amine molecular structure. There is an optimum proportion of the photoinitiator, the photosensitizer and the monomer in the test of holographic parameters with different amine concentrations. The maximum diffraction efficiency is 59.26\%, sensitivity is $1.72\times 10^{ - 3}$ cm$^{2}$/mJ, and the maximum refractive modulation index is $4.64\times 10^{ - 4}$.

Key words: photopolymer, amine, holographic recording, photoinitiator

中图分类号: (Polymers and organics)

42.70.Jk

42.50.Gy (Effects of atomic coherence on propagation, absorption, and Amplification of light; electromagnetically induced transparency and Absorption) 42.40.Lx (Diffraction efficiency, resolution, and other hologram characteristics) 42.70.Ln (Holographic recording materials; optical storage media) 42.40.Ht (Hologram recording and readout methods)

路海, 李若平, 孙彩霞, 肖勇, 唐道广, 黄明举. Holographic property of photopolymers with different amine photoinitiators[J]. 中国物理B, 2010, 19(2): 24212-024212.

Lu Hai(路海),Li Ruo-Ping(李若平), Sun Cai-Xia(孙彩霞), Xiao Yong(肖勇), Tang Dao-Guang(唐道广), and Huang Ming-Ju(黄明举). Holographic property of photopolymers with different amine photoinitiators[J]. Chin. Phys. B, 2010, 19(2): 24212-024212.

参考文献 15

[1]	Gan F X 1998 Digital Optical Disk Recording Technique (Beijing:Science Press) pp. 306--309
[2]	Tao S Q 1998 Optical Holographic Recording (Beijing: BeijingUniversity of Technology Press) pp. 31--37
[3]	Huang M J, Yao H W, Chen Z Y, Yu D W, Hou L S and Gan F X 2002 Acta. Phys. Sin. 51 2536 (in Chinese)
[4]	Gong Q X, Wang S L, Huang M J and Gan F X 2005 Chin. Phys. 142004
[5]	Allen N S, Edge M, Sethi S, Catalina F, Corrales T and Green A2000 Photochemistry and Photobiology A : Chemistry 137 169
[6]	Fernandez-Pousa C R, Mallavia R and Blaya S 2000 Appl. Phys. B 70 537
[7]	Ushamani M, Sreekumar K, Kartha C S and Joseph R 2004 Appl. Opt. 4 3 3697
[8]	Davidson R. S, Dias A A and Illsley D R 1995 Photochemistry andPhotobiology A : Chemistry 91 153
[9]	Lu H, Li R P, Sun C X and Huang M J 2008 J. Appl.Opt. 29 307
[10]	Herwig K 1969 The Bell System Technical Journal 48 2909
[11]	Costela A, Garcia-Moreno I, Garcia O and Sastre R 2000 Photochemical and Photobiology A : Chemistry 131133
[12]	Carretero L, Blaya S, Mallavia R, Madrigal R F and Fimia A 1998 J. Mod. Opt. 45 2345
[13]	Allen N S, Ryabov S V, Edge M, Kobylinskyy S N, Pokcholenko A Aand Voitenko Z V 2002 Polymer Degradation and Stability 75229
[14]	Allen N S, Salleh N G, Edge M, Shah M, Ley C, Morlet-SavaryF, Fouassier J P, Catalina F, Green A, Navaratnam S and Parsons B J1999 Polymer 40 4181
[15]	Li S J and Ji C G 2003 Theory and Application of MacromoleculePhotochemistry (Shanghai: Fudan University Press) pp. 108--113

Holographic property of photopolymers with different amine photoinitiators

Holographic property of photopolymers with different amine photoinitiators

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 15

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Yongqin Zhang(张永钦), Hua Yang(杨华), Yaguang Sun(孙亚光),Xiangrui Zheng(郑香蕊), and Yafang Guo(郭雅芳). Molecular dynamics simulations of mechanical properties of epoxy-amine: Cross-linker type and degree of conversion effects[J]. 中国物理B, 2022, 31(6): 64209-064209.
[2]	Zhen Xu (徐真), Hui Li (李慧), and Lidong Chen(陈立东). Recent progress in design of conductive polymers to improve the thermoelectric performance[J]. 中国物理B, 2022, 31(2): 28203-028203.
[3]	符越吾, 孙潼鹤, 张美玲, 张绪成, 王菲, 张大明. Polymer/silica hybrid waveguide Y-branch power splitter with loss compensation based on NaYF₄: Er³⁺, Yb³⁺ nanocrystals[J]. 中国物理B, 2019, 28(10): 104206-104206.
[4]	张波, 徐晨, 徐国跃, 刘初阳, 卜红寒, 张建超. Influences on oxidation voltage and holding time on poly(3-methylthiophene) film for electrochromic stability[J]. 中国物理B, 2018, 27(12): 127802-127802.
[5]	邢桂超, 张美玲, 孙潼鹤, 符越吾, 黄雅莉, 邵健, 刘静蓉, 王菲, 张大明. Polymer waveguide thermo-optical switch with loss compensation based on NaYF₄: 18% Yb³⁺, 2% Er³⁺ nanocrystals[J]. 中国物理B, 2018, 27(11): 114218-114218.
[6]	刘豫, 孙月, 衣云骥, 田亮, 曹悦, 陈长鸣, 孙小强, 张大明. All polymer asymmetric Mach-Zehnder interferometer waveguide sensor by imprinting bonding and laser polishing[J]. 中国物理B, 2017, 26(12): 124215-124215.
[7]	M D Zidan,A W Allaf,A Allahham,A AL-Zier. Optical nonlinearities of tetracarbonyl-chromium triphenyl phosphine complex[J]. 中国物理B, 2017, 26(4): 44205-044205.
[8]	高洪跃, 刘攀, 曾超, 姚秋香, 郑志强, 刘吉成, 郑华东, 于瀛洁, 曾震湘, 孙涛. Holographic storage of three-dimensional image and data using photopolymer and polymer dispersed liquid crystal films[J]. 中国物理B, 2016, 25(9): 94205-094205.
[9]	Zubair Ahmad, Kh S Karimov, Farid Touati. Flexible impedance and capacitive tensile load Sensor based on CNT composite[J]. 中国物理B, 2016, 25(2): 28801-028801.
[10]	李晓慧, 俞计成, 陆乃彦, 张卫东, 翁雨燕, 顾臻. Confinement-induced nanocrystal alignment of conjugated polymer by the soft-stamped nanoimprint lithography[J]. 中国物理B, 2015, 24(10): 104215-104215.
[11]	何小川, 杨建兵, 闫东航, 翁羽翔. New method for fast morphological characterization of organic polycrystalline films by polarized optical microscopy[J]. 中国物理B, 2015, 24(7): 76803-076803.
[12]	Kh. S. Karimov, Khaulah Sulaiman, Zubair Ahmad, Khakim M. Akhmedov, A. Mateen. Novel pressure and displacement sensors based on carbon nanotubes[J]. , 2015, 24(1): 18801-018801.
[13]	孙倩倩, 安桥石, 张福俊. A simple encapsulation method for organic optoelectronic devices[J]. , 2014, 23(8): 83302-083302.
[14]	吴珂, 朱凯, 吴昊, 韩君, 王金昌, 黄志义, 梁培. Influence of limestone fillers on combustion characteristics of asphalt mortar for pavements[J]. , 2014, 23(7): 74703-074703.
[15]	R. A. Rehman, 蔡亦良, 张寒洁, 吴珂, 窦卫东, 李海洋, 何丕模, 鲍世宁. A shortcut for determining growth mode[J]. 中国物理B, 2013, 22(10): 107202-107202.