Influences on oxidation voltage and holding time on poly(3-methylthiophene) film for electrochromic stability

doi:10.1088/1674-1056/27/12/127802

中国物理B ›› 2018, Vol. 27 ›› Issue (12): 127802-127802.doi: 10.1088/1674-1056/27/12/127802

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Influences on oxidation voltage and holding time on poly(3-methylthiophene) film for electrochromic stability

Bo Zhang(张波), Chen Xu(徐晨), Guo-Yue Xu(徐国跃), Chu-Yang Liu(刘初阳), Hong-Han Bu(卜红寒), Jian-Chao Zhang(张建超)

College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China

收稿日期:2018-06-08 修回日期:2018-09-25 出版日期:2018-12-05 发布日期:2018-12-05
通讯作者: Bo Zhang E-mail:zhangbo8916@163.com
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 51403102) and the Natural Science Foundation of Jiangsu Province, China (Grant No. BK20140811).

Influences on oxidation voltage and holding time on poly(3-methylthiophene) film for electrochromic stability

Bo Zhang(张波), Chen Xu(徐晨), Guo-Yue Xu(徐国跃), Chu-Yang Liu(刘初阳), Hong-Han Bu(卜红寒), Jian-Chao Zhang(张建超)

College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China

Received:2018-06-08 Revised:2018-09-25 Online:2018-12-05 Published:2018-12-05
Contact: Bo Zhang E-mail:zhangbo8916@163.com
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 51403102) and the Natural Science Foundation of Jiangsu Province, China (Grant No. BK20140811).

摘要/Abstract

摘要：

In this study, we report the influences of oxidation potential and holding time on the electrochromic (EC) stability of poly(3-methylthiophene) (P3MT) film during the electrochemical reaction. The cycle stability and transmittance changes of the film were investigated by optimizing the oxidation potential, and its chemical compositions were measured by x-ray photoelectron spectra after multiple electrochemical cycles. High oxidation potentials can increase the P3MT film color contrast and decrease its cycle stability because of accelerating chemical decomposition. Moreover, the holding time with potential pulsing was analyzed by using the optical memory of P3MT at an optimized oxidation potential, which revealed the reduced voltage duration saved energy consumption by 11.6% and improved the EC cycle stability without changing in color contrast.

关键词: electrochromism, P3MT, oxidation potential, cycle stability

Abstract:

Key words: electrochromism, P3MT, oxidation potential, cycle stability

中图分类号: (Electro-optical effects)

78.20.Jq

42.70.Jk (Polymers and organics) 81.15.-z (Methods of deposition of films and coatings; film growth and epitaxy) 81.70.-q (Methods of materials testing and analysis)

张波, 徐晨, 徐国跃, 刘初阳, 卜红寒, 张建超. Influences on oxidation voltage and holding time on poly(3-methylthiophene) film for electrochromic stability[J]. 中国物理B, 2018, 27(12): 127802-127802.

Bo Zhang(张波), Chen Xu(徐晨), Guo-Yue Xu(徐国跃), Chu-Yang Liu(刘初阳), Hong-Han Bu(卜红寒), Jian-Chao Zhang(张建超). Influences on oxidation voltage and holding time on poly(3-methylthiophene) film for electrochromic stability[J]. Chin. Phys. B, 2018, 27(12): 127802-127802.

参考文献 47

[1]	Zhang C, Deng M S and Cai S H 2017 Acta Phys. Sin. 66 124302 (in Chinese)
[2]	Fang C, Wang H and Shi S Q 2016 Acta Phys. Sin. 65 168201 (in Chinese)
[3]	Guo N, Yam K M and Zhang C 2018 Nanotechnology 29 245705 doi: 10.1088/1361-6528/aabac3
[4]	Wang X J, Guo Z F, Qu J Y, Pan K, Qi Z and Li H 2016 Chin. Phys. B 25 028201 doi: 10.1088/1674-1056/25/2/028201
[5]	Xu F, Cao X, Zhu J T, Sun G Y, Li R, Long S W, Luo H J and Jin P 2018 Mater. Lett. 222 62 doi: 10.1016/j.matlet.2018.03.176
[6]	Guan Y, Zhang L P, Wang D, West J L and Fu S H 2018 Mater. Design 147 28 doi: 10.1016/j.matdes.2018.03.030
[7]	Liang Y, Wang P, Lu H, Wang F, Huang L and Wang Q S 2018 J. Lumin. 195 126 doi: 10.1016/j.jlumin.2017.11.021
[8]	Hu J Y, Wang J, Liu R, Li Y, Lu J P and Zhu H J 2018 Dyes. Pigments. 153 84 doi: 10.1016/j.dyepig.2018.02.007
[9]	Liu W S, Zhang X Y, Liu J Q, Ma X D, Zeng J M, Liu P and Xu T G 2017 J. Alloys Compd. 718 379 doi: 10.1016/j.jallcom.2017.05.222
[10]	Xiao P B, Zhang W, Qu T L, Huang Y and Hu S M 2015 Chin. Phys. Lett. 32 074204 doi: 10.1088/0256-307X/32/7/074204
[11]	Chiang A C and Lin Y Y 2013 Chin. Phys. Lett. 30 094201 doi: 10.1088/0256-307X/30/9/094201
[12]	Wang Z, Zhang H, Zhang J, Su H and Wang Y A 2010 Chin. Phys. Lett. 27 127803 doi: 10.1088/0256-307X/27/12/127803
[13]	Ren C, Chen Z, Jia G, Liu X, Zhao J and Wang S 2009 Chin. Phys. Lett. 26 067804 doi: 10.1088/0256-307X/26/6/067804
[14]	Zhang Y, Liao Z, Pan J, Zhou F, Zhu H, Zhao L and Wang W 2009 Chin. Phys. Lett. 26 104208 doi: 10.1088/0256-307X/26/10/104208
[15]	Lee C, Oh Y, Yoon I S, Kim S H, Ju B K and Hong J M 2018 Sci. Rep. 8 2763 doi: 10.1038/s41598-018-20368-3
[16]	Dulgerbaki C, Komur A I, Maslakci N N, Kuralay F and Oksuz A U 2017 Opt. Mater. 70 171 doi: 10.1016/j.optmat.2017.05.024
[17]	Yang X S, Wang Y, Dong L, Zhang F and Qi L Z 2004 Acta Phys. Sin. 53 2724 (in Chinese)
[18]	Yu S N, Wu H H, Chen G Y, Yuan X and Li Y 2011 Acta Phys. Sin. 60 028104 (in Chinese)
[19]	Rai V, Tiwari N, Rajput M, Joshi S M, Nguyen A C and Mathews N 2017 Electrochim. Acta 255 63 doi: 10.1016/j.electacta.2017.09.088
[20]	Pellitero M A, Guimera A, Kitsara M, Villa R, Rubio C, Lakard B, Doche M L, Hihn J Y and Campo F J 2017 Chem. Sci. 8 1995 doi: 10.1039/C6SC04469G
[21]	Kumar C and Pamu D 2016 J. Electron. Mater. 45 3101 doi: 10.1007/s11664-016-4406-8
[22]	Dai F P, Lu S Y, Feng B X, Jiang S R and Chen C 2003 Acta Phys. Sin. 52 1003 (in Chinese)
[23]	Han X, Du W M, Chen M X, Wang X D, Zhang X J, Li X Y, Li J, Peng Z C, Pan C F and Wang Z L 2017 Adv. Mater. 29 26
[24]	Chu J, Lu D Y, Wu B H, Wang X Q, Gong M, Zhang R L and Xiong S X 2018 Sol. Energy Mater. Sol. Cells 177 70 doi: 10.1016/j.solmat.2017.05.049
[25]	Hu B, Lv X J, Sun J W, Bian G F, Ouyang M, Fu Z Y, Wang P J and Zhang C 2013 Org. Electron. 14 6
[26]	Hu Y J, Liu X F, Jiang F X, Zhou W G, Liu C C, Duan X M and Xu J K 2017 J. Phys. Chem. B 121 9281 doi: 10.1021/acs.jpcb.7b05217
[27]	Lai C Y, Foot P J S and Brown J W 2017 Polym. Polym. Compos. 25 119
[28]	Tavoli F and Alizadeh N 2015 J. Electroanal. Chem. 746 39 doi: 10.1016/j.jelechem.2015.03.020
[29]	Tao Y J, Zhang K, Zhang Z Y, Cheng H F, Jiao C L, Zhao Y L and Xu W F 2016 Polymer 91 98 doi: 10.1016/j.polymer.2016.03.060
[30]	Nie G, Wang Y, Tang Y, Zhao D and Guo Q 2018 Biosens. Bioelectron. 101 123 doi: 10.1016/j.bios.2017.10.021
[31]	Niu L and Wang L X 2018 Acta Phys. Sin. 67 027304 (in Chinese)
[32]	Zhu Z, Zhang Y, An Z and Zheng F 2012 Acta Phys. Sin. 61 067701 (in Chinese)
[33]	Wang L and Li J 2011 Acta Phys. Sin. 60 117310 (in Chinese)
[34]	Wang L and Zhang Y 2011 Acta Phys. Sin. 60 047304 (in Chinese)
[35]	Nemani S K, Chen D Y, Mohamed M H and Sojoudi H 2018 J. Nanomater. 2018 3230293
[36]	Tavares F C, Dorr D, Pawlicka A and Avellaneda C O 2018 J. Appl. Polym. Sci. 135 46229 doi: 10.1002/app.46229
[37]	Wang G H and Zhang J K 2018 Chin. Phys. B 27 027801 doi: 10.1088/1674-1056/27/2/027801
[38]	Jabar M A, Aziz H and Nzar R A 2016 Chin. Phys. B 25 114206 doi: 10.1088/1674-1056/25/11/114206
[39]	Wang X J, Guo Z F, Qu J Y, Pan K, Qi Z and Li H 2016 Chin. Phys. B 25 028201 doi: 10.1088/1674-1056/25/2/028201
[40]	Zhou J, He Z H, Ma Y and Dong S K 2015 Chin. Phys. B 24 094203 doi: 10.1088/1674-1056/24/9/094203
[41]	Liu Q R, Chen Q Q, Zhang Q Q, Xiao Y, Zhong X L, Dong G B, Delplancke-Ogletree M P, H Terryn, Baert K and Reniers F 2018 J. Mater. Chem. C 6 646 doi: 10.1039/C7TC04696K
[42]	D Sydorov, Duboriz I and Pud A 2013 Electrochim. Acta 106 114 doi: 10.1016/j.electacta.2013.05.071
[43]	Kim Y, Kim Y, Kim S and Kim E 2010 ACS Nano 4 5277 doi: 10.1021/nn1016378
[44]	Galal A 2006 J. Appl. Polym. Sci. 102 2416 doi: 10.1002/app.24513
[45]	Malitesta C, Guascito M R, Mazzotta E, Siciliano T and Tepore A 2013 Sensor. Actuat. B. Chem. 184 70 doi: 10.1016/j.snb.2013.04.001
[46]	Park S K, Hong Y K, Lee Y B and Joo J 2009 Synth. Metals 159 1191 doi: 10.1016/j.synthmet.2009.02.012
[47]	Dams R, Vangeneagden D and Vanderzande D 2006 Chem. Vapor. Depos. 12 719 doi: 10.1002/cvde.200606483

Influences on oxidation voltage and holding time on poly(3-methylthiophene) film for electrochromic stability

Influences on oxidation voltage and holding time on poly(3-methylthiophene) film for electrochromic stability

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