Optical nonlinearities of tetracarbonyl-chromium triphenyl phosphine complex

doi:10.1088/1674-1056/26/4/044205

中国物理B ›› 2017, Vol. 26 ›› Issue (4): 44205-044205.doi: 10.1088/1674-1056/26/4/044205

• ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS • 上一篇下一篇

Optical nonlinearities of tetracarbonyl-chromium triphenyl phosphine complex

M D Zidan, A W Allaf, A Allahham, A AL-Zier

1 Department of Physics, Atomic Energy Commission, P. O. Box 6091, Damascus, Syria;
2 Department of Chemistry, Atomic Energy Commission, P. O. Box 6091, Damascus, Syria

收稿日期:2016-11-28 修回日期:2017-01-22 出版日期:2017-04-05 发布日期:2017-04-05
通讯作者: M D Zidan E-mail:pscientific2@aec.org.sy

Optical nonlinearities of tetracarbonyl-chromium triphenyl phosphine complex

M D Zidan¹, A W Allaf², A Allahham¹, A AL-Zier²

1 Department of Physics, Atomic Energy Commission, P. O. Box 6091, Damascus, Syria;
2 Department of Chemistry, Atomic Energy Commission, P. O. Box 6091, Damascus, Syria

Received:2016-11-28 Revised:2017-01-22 Online:2017-04-05 Published:2017-04-05
Contact: M D Zidan E-mail:pscientific2@aec.org.sy

摘要/Abstract

摘要： The new tetracarbonyl–chromium-triphenyl phosphine complex was synthesized and characterized using ultraviolet (UV)-visible, Fourier transform infrared (FTIR), and nuclear magnetic resonance (NMR) techniques. The characterization results confirm the molecular structure of the new complex. The z-scan measurements were done by diode laser [continuous wave (CW)] to estimate the nonlinear optical parameter (χ³). The results led to calculate three parameters: the ground-state cross sections (σ_g), the excited-state cross sections (σ_ex), and thermo-optic coefficient of the new complex. This study indicated that our complex is a suitable for photonic applications.

关键词: tetra carbonyl-chromium triphenyl phosphine, Z-scan technique, nonlinear optical materials

Abstract: The new tetracarbonyl–chromium-triphenyl phosphine complex was synthesized and characterized using ultraviolet (UV)-visible, Fourier transform infrared (FTIR), and nuclear magnetic resonance (NMR) techniques. The characterization results confirm the molecular structure of the new complex. The z-scan measurements were done by diode laser [continuous wave (CW)] to estimate the nonlinear optical parameter (χ³). The results led to calculate three parameters: the ground-state cross sections (σ_g), the excited-state cross sections (σ_ex), and thermo-optic coefficient of the new complex. This study indicated that our complex is a suitable for photonic applications.

Key words: tetra carbonyl-chromium triphenyl phosphine, Z-scan technique, nonlinear optical materials

中图分类号: (Nonlinear optics)

42.65.-k

42.70.Nq (Other nonlinear optical materials; photorefractive and semiconductor materials) 31.15.ap (Polarizabilities and other atomic and molecular properties) 42.70.Jk (Polymers and organics)

M D Zidan,A W Allaf,A Allahham,A AL-Zier. Optical nonlinearities of tetracarbonyl-chromium triphenyl phosphine complex[J]. 中国物理B, 2017, 26(4): 44205-044205.

M D Zidan, A W Allaf, A Allahham, A AL-Zier. Optical nonlinearities of tetracarbonyl-chromium triphenyl phosphine complex[J]. Chin. Phys. B, 2017, 26(4): 44205-044205.

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Optical nonlinearities of tetracarbonyl-chromium triphenyl phosphine complex

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