Mid-infrared luminescence of Dy3+-doped Ga2S3-Sb2S3-CsI chalcohalide glasses

doi:10.1088/1674-1056/27/7/077105

中国物理B ›› 2018, Vol. 27 ›› Issue (7): 77105-077105.doi: 10.1088/1674-1056/27/7/077105

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Mid-infrared luminescence of Dy³⁺-doped Ga₂S₃-Sb₂S₃-CsI chalcohalide glasses

Anping Yang(杨安平), Jiahua Qiu(邱嘉桦), Mingjie Zhang(张鸣杰), Mingyang Sun(孙明阳), Zhiyong Yang(杨志勇)

1 Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China;
2 State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China

收稿日期:2018-01-24 修回日期:2018-03-30 出版日期:2018-07-05 发布日期:2018-07-05
通讯作者: Zhiyong Yang E-mail:yangzhiyong@jsnu.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 61405080 and 61575086), Jiangsu Collaborative Innovation Centre of Advanced Laser Technology and Emerging Industry, China, and the Priority Academic Program Development of Jiangsu Higher Education Institutions, China.

Mid-infrared luminescence of Dy³⁺-doped Ga₂S₃-Sb₂S₃-CsI chalcohalide glasses

Anping Yang(杨安平)¹, Jiahua Qiu(邱嘉桦)¹, Mingjie Zhang(张鸣杰)^1,2, Mingyang Sun(孙明阳)¹, Zhiyong Yang(杨志勇)¹

1 Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China;
2 State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China

Received:2018-01-24 Revised:2018-03-30 Online:2018-07-05 Published:2018-07-05
Contact: Zhiyong Yang E-mail:yangzhiyong@jsnu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 61405080 and 61575086), Jiangsu Collaborative Innovation Centre of Advanced Laser Technology and Emerging Industry, China, and the Priority Academic Program Development of Jiangsu Higher Education Institutions, China.

摘要/Abstract

摘要： The mid-infrared (MIR) luminescent properties of Dy³⁺ ions in a new chalcohalide glass host, Ga₂S₃-Sb₂S₃-CsI, are investigated; and the suitability of the doped glass for MIR fiber lasers is evaluated. The Dy³⁺-doped chalcohalide glasses exhibit good thermal stability and intense MIR emissions around 2.96 μ and 4.41 μm. These emissions show quantum efficiencies (η) as high as ~60%, and have relatively large stimulated emission cross sections (σ_em). The low phonon energy (~307 cm^-1) of the host glass accounts for the intense MIR emissions, as well as the high η. These favorable thermal and emission properties make the Dy³⁺-doped Ga₂S₃-Sb₂S₃-CsI glasses promising materials for MIR fiber amplifiers or lasers.

关键词: chalcogenide glasses, rare earth, emission property, mid-infrared laser

Abstract: The mid-infrared (MIR) luminescent properties of Dy³⁺ ions in a new chalcohalide glass host, Ga₂S₃-Sb₂S₃-CsI, are investigated; and the suitability of the doped glass for MIR fiber lasers is evaluated. The Dy³⁺-doped chalcohalide glasses exhibit good thermal stability and intense MIR emissions around 2.96 μ and 4.41 μm. These emissions show quantum efficiencies (η) as high as ~60%, and have relatively large stimulated emission cross sections (σ_em). The low phonon energy (~307 cm^-1) of the host glass accounts for the intense MIR emissions, as well as the high η. These favorable thermal and emission properties make the Dy³⁺-doped Ga₂S₃-Sb₂S₃-CsI glasses promising materials for MIR fiber amplifiers or lasers.

Key words: chalcogenide glasses, rare earth, emission property, mid-infrared laser

中图分类号: (Amorphous semiconductors, metallic glasses, glasses)

71.23.Cq

76.30.Kg (Rare-earth ions and impurities) 78.45.+h (Stimulated emission) 95.85.Hp (Infrared (3-10 μm))

杨安平, 邱嘉桦, 张鸣杰, 孙明阳, 杨志勇. Mid-infrared luminescence of Dy³⁺-doped Ga₂S₃-Sb₂S₃-CsI chalcohalide glasses[J]. 中国物理B, 2018, 27(7): 77105-077105.

Anping Yang(杨安平), Jiahua Qiu(邱嘉桦), Mingjie Zhang(张鸣杰), Mingyang Sun(孙明阳), Zhiyong Yang(杨志勇). Mid-infrared luminescence of Dy³⁺-doped Ga₂S₃-Sb₂S₃-CsI chalcohalide glasses[J]. Chin. Phys. B, 2018, 27(7): 77105-077105.

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Mid-infrared luminescence of Dy³⁺-doped Ga₂S₃-Sb₂S₃-CsI chalcohalide glasses

Mid-infrared luminescence of Dy³⁺-doped Ga₂S₃-Sb₂S₃-CsI chalcohalide glasses

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